Novel Receptor for the Rapid Reaction and Colorimetric Detection of HSO3- in Aqueous Solutions

doi:10.1007/s40242-013-2395-1

Chemical Research in Chinese Universities ›› 2013, Vol. 29 ›› Issue (2): 236-238.doi: 10.1007/s40242-013-2395-1

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Novel Receptor for the Rapid Reaction and Colorimetric Detection of HSO₃^- in Aqueous Solutions

YANG Wen-long, LI Qiao, WEI Tai-bao, ZHANG You-ming, LIN Qi, SHI Bing-bing, ZHANG Peng

Key Laboratory of Eco-Environment-Related Polymer Materials, Ministry of Education of China; Key Laboratory of Polymer Materials of Gansu Province, College of Chemistry and Chemical Engineering, Northwest Normal University, Lanzhou 730070, P. R. China

Received:2012-10-15 Revised:2013-01-16 Online:2013-04-01 Published:2013-03-20
Supported by:
Supported by the National Natural Science Foundation of China(Nos.21064006, 21161018), the Natural Science Foundation of Gansu Province, Chain(No.1010RJZA018) and the Program for Changjian Scholars and Innovative Research Team in University of Minisry of Education of China(No.IRT1177).

Abstract

Abstract:

A novel high-yield Schiff base was designed and synthesized as an anion receptor that specifically select HSO₃^- anions in aqueous solutions of H₂O/DMSO(15:85, volume ratio), which can be detected via colorimetry under direct visualization. The sensor exhibited different results for other anions, such as F^-, Cl^-, Br^-, I^-, H₂PO₄^-, AcO^-, HSO₄^- and ClO₄^-. The changes in the UV-Vis spectra also show the specific recognition of HSO₃^-, rather than similar anions H₂PO₄^- and HSO₄^- in the same aqueous solution. The detection limit of HSO₃^- was 1×10^-6 mol/L.

Key words: Bisulfite anion sensor, 2-Aminobenzimidazole, Aqueous solution, Single recognition, Colorimetry

YANG Wen-long, LI Qiao, WEI Tai-bao, ZHANG You-ming, LIN Qi, SHI Bing-bing, ZHANG Peng. Novel Receptor for the Rapid Reaction and Colorimetric Detection of HSO₃^- in Aqueous Solutions[J]. Chemical Research in Chinese Universities, 2013, 29(2): 236-238.

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Novel Receptor for the Rapid Reaction and Colorimetric Detection of HSO₃^- in Aqueous Solutions

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