Photoactive Poly(aryl ether)s Containing Azobenzene Moieties on Pendants for Fabrication of Thermal Stable Surface Relief Gratings

doi:10.1007/s40242-013-2234-4

Chemical Research in Chinese Universities ›› 2013, Vol. 29 ›› Issue (2): 384-388.doi: 10.1007/s40242-013-2234-4

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Photoactive Poly(aryl ether)s Containing Azobenzene Moieties on Pendants for Fabrication of Thermal Stable Surface Relief Gratings

XU Da, ZHANG Yu-xuan, REN Dian-fu, CHEN Xing-bo, ZHANG Hai-bo, JIANG Zhen-hua

College of Chemistry, Jilin University, Changchun 130012, P. R. China

Received:2012-06-16 Revised:2012-07-15 Online:2013-04-01 Published:2013-03-20
Supported by:
Supported by the National Natural Science Foundation of China(No.51103060).

Abstract

Abstract:

A series of azobenzene functionalized poly(aryl ether) copolymers(azo-PAEs) containing azo moieties on pendants was prepared by direct copolymerization. The amount of azobenzene chromophores could be controlled by the feed ratio of azo-monomer. Their chemical structures and properties were characterized by means of infrared(IR) spectrometry, UV-Vis, hydrogen nuclear magnetic resonance(¹H NMR), difference scanning calorimetry(DSC), and thermogravimetric analysis(TGA). The results suggest that azo-PAEs had high glass transition temperatures(T_gs) and good thermal stability. By exposing their spin-coated films to an interference pattern laser beam, azo-PAEs could be used for the fabrication of thermal stable surface relief gratings(SRGs).

Key words: Azo polymer, Poly(aryl ether), Surface relief grating, Photoactive

XU Da, ZHANG Yu-xuan, REN Dian-fu, CHEN Xing-bo, ZHANG Hai-bo, JIANG Zhen-hua. Photoactive Poly(aryl ether)s Containing Azobenzene Moieties on Pendants for Fabrication of Thermal Stable Surface Relief Gratings[J]. Chemical Research in Chinese Universities, 2013, 29(2): 384-388.

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Photoactive Poly(aryl ether)s Containing Azobenzene Moieties on Pendants for Fabrication of Thermal Stable Surface Relief Gratings

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