Synthesis and Crystal Structure of 10-Phenyl-1,7-dithia-4-oxa-10-aza-12-crown-4

高等学校化学研究 ›› 1998, Vol. 14 ›› Issue (4): 375-378.

Synthesis and Crystal Structure of 10-Phenyl-1,7-dithia-4-oxa-10-aza-12-crown-4

NIU Chang-rong¹, JIANG Hua¹, WU Cheng-tai¹, LUO Bao-sheng²

1. Department of Chemistry, Wuhan University 430072;
2. Center of Instrumental Analysis, Wuhan University, Wuhan 430072

收稿日期:1997-12-26 出版日期:1998-12-24 发布日期:2011-08-17
通讯作者: NIU Chang-rong
基金资助:
Supported by the National Natural Science Foundation of China.

Synthesis and Crystal Structure of 10-Phenyl-1,7-dithia-4-oxa-10-aza-12-crown-4

NIU Chang-rong¹, JIANG Hua¹, WU Cheng-tai¹, LUO Bao-sheng²

1. Department of Chemistry, Wuhan University 430072;
2. Center of Instrumental Analysis, Wuhan University, Wuhan 430072

Received:1997-12-26 Online:1998-12-24 Published:2011-08-17

摘要/Abstract

摘要： The crystal structure of the title compound C₁₄H₂₁ONS₂ was determined by means of X-ray diffraction method.Its crystallog raphic data are as follows:M_r=283.46,it is a monoclinic crystal system,the space group P2₁/n,a=1.273 7(3)nm,b=1.510 9(5)nm,c=0.798 0(6)nm,=107.17(3)°,V=1.467 4 nm³,Z=4,D_c=1.283 g·cm^-3,(MoK)=3.370 cm^-1,F(000)=608,R₁=0.079,R_w=0.076 for 1.689 observed reflections with I≥6(I).Both the phenyl and hetero cyclic rings in the title compound are distorted to form a conjugate system.

关键词: Crystal structure, Free ligand, Mixed-donor macromolecular ligand

Abstract: The crystal structure of the title compound C₁₄H₂₁ONS₂ was determined by means of X-ray diffraction method.Its crystallog raphic data are as follows:M_r=283.46,it is a monoclinic crystal system,the space group P2₁/n,a=1.273 7(3)nm,b=1.510 9(5)nm,c=0.798 0(6)nm,=107.17(3)°,V=1.467 4 nm³,Z=4,D_c=1.283 g·cm^-3,(MoK)=3.370 cm^-1,F(000)=608,R₁=0.079,R_w=0.076 for 1.689 observed reflections with I≥6(I).Both the phenyl and hetero cyclic rings in the title compound are distorted to form a conjugate system.

Key words: Crystal structure, Free ligand, Mixed-donor macromolecular ligand

NIU Chang-rong, JIANG Hua, WU Cheng-tai, LUO Bao-sheng . Synthesis and Crystal Structure of 10-Phenyl-1,7-dithia-4-oxa-10-aza-12-crown-4[J]. 高等学校化学研究, 1998, 14(4): 375-378.

NIU Chang-rong, JIANG Hua, WU Cheng-tai, LUO Bao-sheng . Synthesis and Crystal Structure of 10-Phenyl-1,7-dithia-4-oxa-10-aza-12-crown-4[J]. Chemical Research in Chinese Universities, 1998, 14(4): 375-378.

[1]	HUA Chen, YI Pin, LIU Wencong, WANG Mengfan, NIU Zheng, LANG Jianping. Coordination Polymers with Bipyridyl Diene and Triene Ligands: Synthesis, Structures and Luminescent Properties[J]. 高等学校化学研究, 2022, 38(1): 209-216.
[2]	ZHANG Wenqi, LIN Zhengguo, CHI Yingnan, HONG Jie, YAN Li, HU Changwen. Assembly of Three Scandium-containing Heteropolytungstates Based on a Building-block Synthetic Strategy[J]. 高等学校化学研究, 2020, 36(6): 1161-1167.
[3]	ZANG Jiahe, ZHANG Qing'an, SUN Dalin. Crystal Structures and Electrochemical Properties of R_1.5Ca_1.5MgNi₁₄(R=Nd, Gd and Er) Hydrogen Storage Alloys[J]. 高等学校化学研究, 2019, 35(6): 1040-1045.
[4]	WANG Dongmei, LOU Shengjun, YING Yiting, GUO Zhiqi, WANG Lijun. Assembly of Two Isostructural Metal-organic Frameworks Based on Hetero-N,O Donor Ligand for Detecting Nitro Explosives[J]. 高等学校化学研究, 2019, 35(5): 762-766.
[5]	MA Xiao, WANG Xiaohong, SHANG Fan, DING Zimei, HANG Xiaojing, HUANG Jie. Studies on 3-Amino-4-(1H-tetrazol-5-yl)-furazan: Crystal Structure, Thermal Behavior and Energetic Performance[J]. 高等学校化学研究, 2019, 35(5): 848-853.
[6]	ZHONG Liangxuan, LIU Mingyue, ZHANG Bowei, SUN Yaqiu, XU Yanyan. Syntheses, Crystal Structures, Magnetic and Near-infrared Luminescence Properties of 3d-4f Coordination Polymers Cu₂Pr₂, Cu₂Eu₂ and Cu₄Tb₂[J]. 高等学校化学研究, 2019, 35(4): 693-699.
[7]	YU Yanzhao, CAO Jiapeng, XU Yan. Two Pentavanadate-based Organic-inorganic Materials with Third-order NLO Properties[J]. 高等学校化学研究, 2019, 35(1): 1-4.
[8]	DING Zimei, CAO Wenli, ZHENG Hui, HUANG Jie, XU Kangzhen, SONG Jirong. Synthesis, Structure Characteristic and Thermal Behavior of Two New Metal-organic Azo-triazole Compounds: [Zn(phen)₃]·ZTO·6H₂O and[Cu(phen)₃]·ZTO·6H₂O[J]. 高等学校化学研究, 2018, 34(6): 1009-1013.
[9]	CHEN Xiang, ZENG Tian, ZHANG Cong, GUO Zhaoqi, LI Shuailei, MAI Tao, GAO Rong, MA Haixia. Crystal Structures, Thermal Behavior Analysis and Thermal Safety of Two Energetic Salts of Hydrazinyl-1,2,4,5-tetrazine with 3,5-Dinitrosalicylic Acid[J]. 高等学校化学研究, 2018, 34(6): 959-964.
[10]	LIU Chao, LIU Yijie, ZHANG Lili, JIANG Kun, ZHANG Li. Two Coordination Compounds Bearing Bis(2-dimethylaminoethyl) Ether: Syntheses, Crystal Structures and Catalytic Application to the Henry Reaction[J]. 高等学校化学研究, 2018, 34(3): 358-362.
[11]	WANG Jingyang, ZHANG Meng, XU Xiaodong, FENG Jing, WANG Yanli, ZHANG Milin, HAN Wei, CHEN Yitung, TIAN Guoxin. Synthesis and Characterization of [Cu(N-MeIm)₄(BF₄)₂] in Ionic Liquid[J]. 高等学校化学研究, 2018, 34(1): 8-12.
[12]	ZHOU Jinhua, LI Jingjing, LI Jie, REN Guoyu, REN Yinghui, MA Haixia. Structure and Enhanced Antifungal Activity of a Divalent Cobalt(II) Complex with Hexaconazole[J]. 高等学校化学研究, 2017, 33(6): 864-868.
[13]	WANG Xiang, LIN Lin, LIN Hongyan, LIU Guocheng. Syntheses, Structure and Properties of a 3d-4d/2-ptz Heterometallic Organic Chain-modified POM-based Framework[J]. 高等学校化学研究, 2017, 33(1): 7-11.
[14]	HE Yuanchun, GUO Jiao, XU Na, YU Yang. Assembly of Five Coordination Polymers Based on 5,11,17,23-Tetra-tert-butyl-25-(carboxymethoxy)-calix[4]arene Ligand[J]. 高等学校化学研究, 2017, 33(1): 44-48.
[15]	YAN Xia, ZHANG Jianxin. Copper(II) Complexes Based on 4'-R-Terpyridine: Synthesis, Structures, and Photocatalytic Properties[J]. 高等学校化学研究, 2017, 33(1): 1-6.

Synthesis and Crystal Structure of 10-Phenyl-1,7-dithia-4-oxa-10-aza-12-crown-4

Synthesis and Crystal Structure of 10-Phenyl-1,7-dithia-4-oxa-10-aza-12-crown-4

PDF (PC)

可视化

摘要/Abstract

引用本文

使用本文

参考文献

相关文章 15

编辑推荐

Metrics

本文评价