Synthesis and Crystal Structure of Novel Dimer of Bismuth( Ⅲ ) Complex with Dithiotetrahydropyrrolocarbamate: [Bi(S2CNC4H8)2 (NO3)]2

高等学校化学研究 ›› 2004, Vol. 20 ›› Issue (5): 565-567.

Synthesis and Crystal Structure of Novel Dimer of Bismuth( Ⅲ ) Complex with Dithiotetrahydropyrrolocarbamate: [Bi(S₂CNC₄H₈)₂ (NO₃)]₂

YIN Han-dong, WANG Chuan-hua, MA Chun-lin

Department of Chemistry, Liaocheng University, Liaocheng 252059, P. R. China

收稿日期:2003-04-24 出版日期:2004-10-24 发布日期:2011-08-06
基金资助:
Supported by the Natural Science Foundation of Shandong Province(No.L2003B01) and the State Key Laboratory of Crystal Materials, Shandong University.

Synthesis and Crystal Structure of Novel Dimer of Bismuth( Ⅲ ) Complex with Dithiotetrahydropyrrolocarbamate: [Bi(S₂CNC₄H₈)₂ (NO₃)]₂

YIN Han-dong, WANG Chuan-hua, MA Chun-lin

Department of Chemistry, Liaocheng University, Liaocheng 252059, P. R. China

Received:2003-04-24 Online:2004-10-24 Published:2011-08-06
Supported by:
Supported by the Natural Science Foundation of Shandong Province(No.L2003B01) and the State Key Laboratory of Crystal Materials, Shandong University.

摘要/Abstract

摘要： A novel dimer of the bismuth ( Ⅲ ) complex with dithiotetrahydropyrroloearbamate, [Bi(S₂CNC₄H₈)₂ ·(NO₃)]₂, was synthesized and the crystal structure was determined by X-ray single crystal diffraction.The crystal belongs to a monoclinic system with space group P2₁/n, a=0.64718(13) nm, b=2.6738(6) nm, c=1.0423(2) nm, β=106.384(3)°, Z=4, V=1.730(3) nm³, D_c=2.163 g/cm³, μ=10.682 mm^-1, F(000)=1072, R= 0.0329, wR=0.0659.The structure shows a distorted pentagonal bipyramidal configuration with the seven-coordinated central Bi atom.In the crystal, the molecular packing in the unit cell reveals that the two adjacent molecules are symmetrically linked each other in the dimer by virtue of a couple of Bi-S interaction.

关键词: Bismuth( Ⅲ ) complex, Dithiotetrahydropyrrolocarbamate, Dimmer, Crystal structure

Abstract: A novel dimer of the bismuth ( Ⅲ ) complex with dithiotetrahydropyrroloearbamate, [Bi(S₂CNC₄H₈)₂ ·(NO₃)]₂, was synthesized and the crystal structure was determined by X-ray single crystal diffraction.The crystal belongs to a monoclinic system with space group P2₁/n, a=0.64718(13) nm, b=2.6738(6) nm, c=1.0423(2) nm, β=106.384(3)°, Z=4, V=1.730(3) nm³, D_c=2.163 g/cm³, μ=10.682 mm^-1, F(000)=1072, R= 0.0329, wR=0.0659.The structure shows a distorted pentagonal bipyramidal configuration with the seven-coordinated central Bi atom.In the crystal, the molecular packing in the unit cell reveals that the two adjacent molecules are symmetrically linked each other in the dimer by virtue of a couple of Bi-S interaction.

Key words: Bismuth( Ⅲ ) complex, Dithiotetrahydropyrrolocarbamate, Dimmer, Crystal structure

YIN Han-dong, WANG Chuan-hua, MA Chun-lin. Synthesis and Crystal Structure of Novel Dimer of Bismuth( Ⅲ ) Complex with Dithiotetrahydropyrrolocarbamate: [Bi(S₂CNC₄H₈)₂ (NO₃)]₂[J]. 高等学校化学研究, 2004, 20(5): 565-567.

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Synthesis and Crystal Structure of Novel Dimer of Bismuth( Ⅲ ) Complex with Dithiotetrahydropyrrolocarbamate: [Bi(S₂CNC₄H₈)₂ (NO₃)]₂

Synthesis and Crystal Structure of Novel Dimer of Bismuth( Ⅲ ) Complex with Dithiotetrahydropyrrolocarbamate: [Bi(S₂CNC₄H₈)₂ (NO₃)]₂

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