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高等学校化学研究 ›› 2002, Vol. 18 ›› Issue (2): 211-215.

• Articles • 上一篇    下一篇

Crystal Structure and Characterization of a Dye with Two-photon Pumoed Frequency-upconverted Lasing Properties

TIAN Yu-peng1,2, YU Wen-tao3, FANG Qi3, WU Jie-ying1,2, JIANG Min-hua3, WANG He-zhou4, ZHENG Xi-guang4   

  1. 1. Department of Chemistry, Anhui University, Hefei 230039, P. R. China;
    2. State Key Laboratory of Coordination Chemistry, Nanjing University, Nanjing 210093, P. R. China;
    3. Institute of Crystal Materials, State Key Laboratory of Crystal Materials, Shandong University, Jinan 250100, P.R. China;
    4. Institute for Laser and Spectroscopy, Zhongshan University, Guangzhou 510275, P. R. China
  • 收稿日期:2000-04-04 出版日期:2002-04-24 发布日期:2011-08-04
  • 基金资助:

    Supported by Grant for State Key Program of China and the National Natural Science Foundation of China (No.29871001).

Crystal Structure and Characterization of a Dye with Two-photon Pumoed Frequency-upconverted Lasing Properties

TIAN Yu-peng1,2, YU Wen-tao3, FANG Qi3, WU Jie-ying1,2, JIANG Min-hua3, WANG He-zhou4, ZHENG Xi-guang4   

  1. 1. Department of Chemistry, Anhui University, Hefei 230039, P. R. China;
    2. State Key Laboratory of Coordination Chemistry, Nanjing University, Nanjing 210093, P. R. China;
    3. Institute of Crystal Materials, State Key Laboratory of Crystal Materials, Shandong University, Jinan 250100, P.R. China;
    4. Institute for Laser and Spectroscopy, Zhongshan University, Guangzhou 510275, P. R. China
  • Received:2000-04-04 Online:2002-04-24 Published:2011-08-04
  • Supported by:

    Supported by Grant for State Key Program of China and the National Natural Science Foundation of China (No.29871001).

PDF (PC)

摘要： The title compound, trans-4-[ p-( N-ethyl-N-(hydroxyethyl ) amino) styryl ]-N-methylpyridiniumtetraphenylborate (abbreviated as ESMT, C46H49N4O) crystallizes in a space group P1 with a= 0.983 23 (15)nm, b=1.410 73(16) nm, c=1.54 21(12) nm, a=95.252(13)°, β=91.959(17)°, γ= 107.421(12)°, Z=2, F(000)=712, μ= 0.1 mm-1 Mo Ka radiation, R=0. 093 8. The result shows that the cation of themolecule almost lies in one plane, the hydroxyethyl group is perpendicular to the plane, the anion takes a slightdistorted tetrahedral geometry. Also the thermal stability, two-photon fluorescence, two-photon pumped lasingproperty for the title compound were studied.

关键词: Crystal structure, Methylpyridinium salt, Two-photon pumped lasing property

Abstract: The title compound, trans-4-[ p-( N-ethyl-N-(hydroxyethyl ) amino) styryl ]-N-methylpyridiniumtetraphenylborate (abbreviated as ESMT, C46H49N4O) crystallizes in a space group P1 with a= 0.983 23 (15)nm, b=1.410 73(16) nm, c=1.54 21(12) nm, a=95.252(13)°, β=91.959(17)°, γ= 107.421(12)°, Z=2, F(000)=712, μ= 0.1 mm-1 Mo Ka radiation, R=0. 093 8. The result shows that the cation of themolecule almost lies in one plane, the hydroxyethyl group is perpendicular to the plane, the anion takes a slightdistorted tetrahedral geometry. Also the thermal stability, two-photon fluorescence, two-photon pumped lasingproperty for the title compound were studied.

Key words: Crystal structure, Methylpyridinium salt, Two-photon pumped lasing property