Photolysis and Cycloaddition Reactivity of Diferrocenyl Substituted Cyclopentadienone

doi:10.1007/s40242-016-6158-7

高等学校化学研究 ›› 2016, Vol. 32 ›› Issue (5): 775-780.doi: 10.1007/s40242-016-6158-7

Photolysis and Cycloaddition Reactivity of Diferrocenyl Substituted Cyclopentadienone

ZHANG Xiaoyong^1,2, HAN Limin¹, GAO Yuanyuan¹, SHI Jiale¹, SUO Quanling¹

1. Chemical Engineering College, Inner Mongolia University of Technology, Hohhot 010051, P. R. China;
2. Department of Chemistry, Baotou Teacher's College, Baotou 014030, P. R. China

收稿日期:2016-04-22 修回日期:2016-06-20 出版日期:2016-10-01 发布日期:2016-08-01
通讯作者: SUO Quanling E-mail:szj010062@163.com
基金资助:
Supported by the National Natural Science Foundation of China(Nos.21266019, 21062011).

Photolysis and Cycloaddition Reactivity of Diferrocenyl Substituted Cyclopentadienone

ZHANG Xiaoyong^1,2, HAN Limin¹, GAO Yuanyuan¹, SHI Jiale¹, SUO Quanling¹

1. Chemical Engineering College, Inner Mongolia University of Technology, Hohhot 010051, P. R. China;
2. Department of Chemistry, Baotou Teacher's College, Baotou 014030, P. R. China

Received:2016-04-22 Revised:2016-06-20 Online:2016-10-01 Published:2016-08-01
Contact: SUO Quanling E-mail:szj010062@163.com
Supported by:
Supported by the National Natural Science Foundation of China(Nos.21266019, 21062011).

摘要/Abstract

摘要：

The photolysis results of new diferrocenyl substituted cyclopentadienone(3) show that sunlight and air play an important role in the decomposition of compound 3, and two new compounds, 2-cyclopentenone(4) and α-pyrone(5), were obtained via photolysis of compound 3. The photolysis process was investigated by ¹H NMR, and a plausible mechanism for the formation of compound 5 was deduced. The cycloaddition reactions of substituted cyclopentadienones(3, 7, 9) with maleimide gave substituted imides 8, 10, 11, 12 and an unprecedented diferrocenyl substituted 1H-pyrrol-3(2H)-one derivative 13, respectively. The structures of compounds 4, 5, 8, 10, 11, 12 and 13 were confirmed by X-ray single crystal diffraction analysis technique.

关键词: Cyclopentadienone, Reactivity, Photolysis, Cycloaddition, Crystal structure

Abstract:

Key words: Cyclopentadienone, Reactivity, Photolysis, Cycloaddition, Crystal structure

ZHANG Xiaoyong, HAN Limin, GAO Yuanyuan, SHI Jiale, SUO Quanling. Photolysis and Cycloaddition Reactivity of Diferrocenyl Substituted Cyclopentadienone[J]. 高等学校化学研究, 2016, 32(5): 775-780.

ZHANG Xiaoyong, HAN Limin, GAO Yuanyuan, SHI Jiale, SUO Quanling. Photolysis and Cycloaddition Reactivity of Diferrocenyl Substituted Cyclopentadienone[J]. Chemical Research in Chinese Universities, 2016, 32(5): 775-780.

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Photolysis and Cycloaddition Reactivity of Diferrocenyl Substituted Cyclopentadienone

Photolysis and Cycloaddition Reactivity of Diferrocenyl Substituted Cyclopentadienone

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