Synthesis, Structures and Properties of Two Complexes Based on Benzimidazole or Benzothiazole Ligand

doi:10.1007/s40242-014-3434-2

高等学校化学研究 ›› 2014, Vol. 30 ›› Issue (2): 185-189.doi: 10.1007/s40242-014-3434-2

Synthesis, Structures and Properties of Two Complexes Based on Benzimidazole or Benzothiazole Ligand

ZHANG Zhongqiang^1,2, DI Di¹, ZHAI Jingshuo², WU Lili², ZHU Qinlei¹, XU Yanqing¹, HUANG Rudan¹

1. Key Laboratory of Cluster Science, Ministry of Education, School of Chemistry, Beijing Institute of Technology, Beijing 100081, P. R. China;
2. Department of Applied Chemistry, Hengshui University, Hengshui 053000, P. R. China

收稿日期:2013-10-14 修回日期:2013-11-08 出版日期:2014-04-01 发布日期:2013-12-04
通讯作者: HUANG Rudan E-mail:huangrd@bit.edu.cn
基金资助:
Supported by the National Natural Science Foundation of China(Nos.20971014, 21271024), the Natural Science Foundation of Beijing City, China(No.2112037) and the Science and Technology Supported Planning Project of Hebei Province, China(No. 12215117D).

Synthesis, Structures and Properties of Two Complexes Based on Benzimidazole or Benzothiazole Ligand

ZHANG Zhongqiang^1,2, DI Di¹, ZHAI Jingshuo², WU Lili², ZHU Qinlei¹, XU Yanqing¹, HUANG Rudan¹

1. Key Laboratory of Cluster Science, Ministry of Education, School of Chemistry, Beijing Institute of Technology, Beijing 100081, P. R. China;
2. Department of Applied Chemistry, Hengshui University, Hengshui 053000, P. R. China

Received:2013-10-14 Revised:2013-11-08 Online:2014-04-01 Published:2013-12-04
Contact: HUANG Rudan E-mail:huangrd@bit.edu.cn
Supported by:
Supported by the National Natural Science Foundation of China(Nos.20971014, 21271024), the Natural Science Foundation of Beijing City, China(No.2112037) and the Science and Technology Supported Planning Project of Hebei Province, China(No. 12215117D).

摘要/Abstract

摘要：

Two complexes, Co(Hbim)₂(NCS)₂(Hbim=benzimidazole)(1) and [Cu(Hbzt)SCN]_n(Hbzt=benzothiazole) (2) were synthesized by the same synthesis method and characterized by elemental analysis, infrared spectroscopy(IR), thermogravimetric analysis(TGA), X-ray powder diffraction(XRPD) and single-crystal X-ray diffraction. The results from the single-crystal X-ray diffraction indicate that complex 1 is zero-dimensional(0D) framework and complex 2 is 2-dimensional(2D) framework. In complex 2, the 3-dimensional(3D) supermolecular architecture was built up by means of π-π stacking interaction, and two helical chains existed in its structure. The luminescence properties and the magnetic properties of the two complexes were investigated.

关键词: Chemical synthesis, Crystal structure, Luminescence property, Magnetic property

Abstract:

Key words: Chemical synthesis, Crystal structure, Luminescence property, Magnetic property

ZHANG Zhongqiang, DI Di, ZHAI Jingshuo, WU Lili, ZHU Qinlei, XU Yanqing, HUANG Rudan. Synthesis, Structures and Properties of Two Complexes Based on Benzimidazole or Benzothiazole Ligand[J]. 高等学校化学研究, 2014, 30(2): 185-189.

参考文献

[1] Cheng J. W., Zheng S. T., Yang G. Y., Inorg. Chem., 2007, 46, 10261
[2] Gong Y., Tang W., Hou W. B., Zha Z. Y., Hu C. W., Inorg. Chem., 2006, 45, 4987
[3] Park K. S., Ni Z., Coté A. P., Choi J. Y., Huang R. D., Uribe-Romo F. J., Chae H. K., Keeffe M. O'., Yaghi O. M., PANS, 2006, 103, 10186
[4] Tu T., Assenmacher W., Peterlik H., Weisbarth R., Nieger M., Dötz K. H., Angew. Chem. Int. Ed., 2007, 46, 6368
[5] Chuprakov S., Hwang F. W., Gevorgyan V., Angew. Chem., 2007, 119, 4841
[6] Lu H. J., Li X. G., Wang S. R., Gao W. Z., Wang S. S., Chem. Res. Chinese Universities, 2012, 28(2), 313
[7] Li C. J., Feng Z. J., Zhao X. J., Wang S. N., Dou J. M., Chem. Res. Chinese Universities, 2013, 29(2), 414
[8] Su C. Y., Goforth A. M., Smith M. D., Loye H. C., Inorg. Chem., 2003, 42, 5685
[9] Matthews C. J., Clegg W., Heath S. L., Martin N. C., Stuart H. M. N., Lockhart J. C., Inorg. Chem., 1998, 37, 199
[10] Rajesh, Mathur P., Polyhedron, 1998, 17, 2607
[11] Quintal S., Matos J., Fonseca I., Félix V., Drew M. G. B., Trindade N., Meireles M., Calhorda M. J., Inorg. Chem. Acta, 2008, 361, 1584
[12] Yang X. P., Jones R. A., Lai R. J., Waheed A., Oye M. M., Holmes A. L., Polyhedron, 2006, 25, 881
[13] González-Álvarez M., Alzuet G., Borrás J., Agudo L. C., García-Granda S., Montejo-Bernardo J. M., Inorg. Chem., 2005, 44, 9424
[14] TzanopoulouS., Pirmettis I. C., Patsis G., Raptopoulou C., Terzis A., Papadopoulos M., Pelecanou M., Inorg. Chem., 2006, 45, 902
[15] Toth A., Floriani C., Chiesi-Villa A., Guastinil C., Inorg. Chem., 1987, 26, 3897
[16] Yen S. K., Koh L. L., Hahn F. E., Huynh H. V., Andy H. T. S., Organometallics, 2006, 25, 5105
[17] Huynh H. V., Meier N., Pape T., Ekkehardt H. F., Organometallics, 2006, 25, 3012
[18] Huang X. Y., Meng X. G., Zhang Y., Wang L., Liu C. L., Chem. J. Chinese Universities, 2012, 33(6), 1151
[19] Chen Q., Chang Z., Song W. C., Song H., Song H. B., Hu T. L., Bu X. H., Angew. Chem. Int. Ed., 2013, 52, 11550
[20] Sielisch T., Cowie M., Organometallics, 1988, 7, 707
[21] Raper E. S., Coord. Chem. Rev., 1997, 165, 475
[22] Ballester L., Coronado E., Gutierrez A., Mange A., Perpifitin M. F., Pinilla E., Rico T., Inorg. Chem., 1992, 31, 2053
[23] Colacio E., Kivekãs R., Lloret F., Sunberg M., Inorg. Chem., 2002, 41, 5141
[24] Chesnut D. J., Kusnetzow A., Birge R., Zubieta J., Inorg. Chem., 1999, 38, 5484
[25] Li C. X., Zhang G. H., Shih H. H., Jiang X. Q., Sun P., Pan Y., Cheng C. H., J. Organomet. Chem., 2009, 694, 2415
[26] Weaver J. A., Hxmbright P., Talbeizt P. T., Kaiyg E., Thorpe A. N., Inorg. Chem., 1970, 9, 268
[27] Tong Y. P., Zheng S. L., Chen X. M., Inorg. Chem., 2005, 44, 4270
[28] Shavaleev N. M., Scopelliti R., Gumy F., Bunzli J. C. G., Inorg. Chem., 2009, 48, 6178
[29] Payra P., Hung S. C., Kwok W. H., Johnston D., Gallucci J., Chan M. K., Inorg. Chem., 2001, 40, 4036
[30] Lescop C., Belorizky E., Luneau D., Rey P., Inorg. Chem., 2002, 41, 3375
[31] Casella L., Carugo O., Gullotti M., Garofani S., Zanello P., Inorg. Chem., 1993, 32, 2056
[32] Arjmand F., Mohani B., Ahmad S., Eur. J. Med. Chem., 2005, 40, 1103
[33] Mohapatra S. C., Tehlan S., Hundal M. S., Mathur P., Inorg. Chem. Acta, 2008, 361, 1897
[34] Tarte N. H., Woo S. I., Cui L. Q., Gong Y. D., Hwang Y. H., J. Organomet. Chem., 2008, 693, 729
[35] Li Y. W., Li J. R., Wang L. F., Zhou B. Y., Chen Q., Bu X. H., J. Mater. Chem. A, 2013, 1, 495
[36] Zhong C. F., Guo R. F., Wu Q., Zhang H. L., React. Funct. Polym., 2007, 67, 408
[37] Sheldrick G. M., SMART and SAINT Software Package, Siemens Analytical X-Ray Instruments Inc., Madison, WI, 1996
[38] Sheldrick G. M., SHELXS-97, Program for Crystal Structure Solution, University of Göttingen, Göttingen, 1997
[39] Wang X. L., Hu H. L., Tian A. X., Lin H. Y., Li J., Inorg. Chem., 2010, 49, 10299
[40] Mandal T. N., Roy S., Barik A. K., Gupta S., Butcher R. J., Kar S. K., Inorg. Chem. Acta, 2009, 362, 1315
[41] Gao H. L., Yi L., Zhao B., Zhao X. Q., Cheng P., Liao D. Z., Yan S. P., Inorg. Chem., 2006, 45, 5980
[42] Wang X. W., Chen F. P., Chen L., Chen J. Z., Jiang W. J., Cai T. J., Deng Q., J. Mol. Struct., 2007, 842, 75
[43] Xia C. K., Lu C. Z., Zhang Q. Z., He X., Zhang J. J., Wu D. M., Cryst. Growth Des., 2005, 5, 1569

Synthesis, Structures and Properties of Two Complexes Based on Benzimidazole or Benzothiazole Ligand

Synthesis, Structures and Properties of Two Complexes Based on Benzimidazole or Benzothiazole Ligand

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