Kinetics and Mechanism of Oxidation of 1,2-Butanediol or Mephenesin by Ditelluratocuprate(III) in Alkaline Media

高等学校化学研究 ›› 2011, Vol. 27 ›› Issue (6): 1041-1044.

Kinetics and Mechanism of Oxidation of 1,2-Butanediol or Mephenesin by Ditelluratocuprate(III) in Alkaline Media

SHAN Jin-huan*, LIU Yan-ping and FENG Shu-xia

College of Chemistry and Environmental Science, Hebei University, Baoding 071002, P. R. China

收稿日期:2011-01-06 修回日期:2011-03-22 出版日期:2011-11-25 发布日期:2011-11-07
通讯作者: SHAN Jin-huan E-mail:shanjinhuaner@yahoo.com.cn
基金资助:
Supported by the Natural Science Foundation of Hebei Province, China(No.295066).

Kinetics and Mechanism of Oxidation of 1,2-Butanediol or Mephenesin by Ditelluratocuprate(III) in Alkaline Media

SHAN Jin-huan*, LIU Yan-ping and FENG Shu-xia

College of Chemistry and Environmental Science, Hebei University, Baoding 071002, P. R. China

Received:2011-01-06 Revised:2011-03-22 Online:2011-11-25 Published:2011-11-07
Contact: SHAN Jin-huan E-mail:shanjinhuaner@yahoo.com.cn
Supported by:
Supported by the Natural Science Foundation of Hebei Province, China(No.295066).

摘要/Abstract

摘要： The kinetics of the oxidation of 1,2-butanediol or mephenesin by ditelluratocuprate(III)(DTC) was investigated spectrophotometrically at temperatures between 283.2―303.2 K in alkaline media. The reaction rate showed first order dependence in DTC and fractional order in 1,2-butanediol or mephenesin. It was shown that the pseudo- first-order rate constant kobs increased with an increase in concentration of OH– and a decrease in concentration of TeO42–. The reaction has a negative salt effect. A plausible mechanism of reaction involving a pre-equilibrium of adduct formation between the complex and 1,2-butanediol or mephenesin was proposed. The rate equations derived from the mechanism can explain all the experimental phenomena. The activation parameters for the rate-determining step were also calculated.

关键词: Ditelluratocuprate(III)(DTC), 1,2-Butanediol, Mephenesin, Kinetics, Mechanism

Abstract: The kinetics of the oxidation of 1,2-butanediol or mephenesin by ditelluratocuprate(III)(DTC) was investigated spectrophotometrically at temperatures between 283.2―303.2 K in alkaline media. The reaction rate showed first order dependence in DTC and fractional order in 1,2-butanediol or mephenesin. It was shown that the pseudo- first-order rate constant kobs increased with an increase in concentration of OH– and a decrease in concentration of TeO42–. The reaction has a negative salt effect. A plausible mechanism of reaction involving a pre-equilibrium of adduct formation between the complex and 1,2-butanediol or mephenesin was proposed. The rate equations derived from the mechanism can explain all the experimental phenomena. The activation parameters for the rate-determining step were also calculated.

Key words: Ditelluratocuprate(III)(DTC), 1,2-Butanediol, Mephenesin, Kinetics, Mechanism

SHAN Jin-huan*, LIU Yan-ping and FENG Shu-xia. Kinetics and Mechanism of Oxidation of 1,2-Butanediol or Mephenesin by Ditelluratocuprate(III) in Alkaline Media[J]. 高等学校化学研究, 2011, 27(6): 1041-1044.

SHAN Jin-huan*, LIU Yan-ping and FENG Shu-xia. Kinetics and Mechanism of Oxidation of 1,2-Butanediol or Mephenesin by Ditelluratocuprate(III) in Alkaline Media[J]. Chemical Research in Chinese Universities, 2011, 27(6): 1041-1044.

[1]	HU Shifan, WANG Yafeng and SU Bin. Effect of Ionic Strength on the Electrochemiluminescence Generation by Tris(2,2'-bipyridyl)ruthenium(II)/Tri-n-propylamine[J]. 高等学校化学研究, 2022, 38(3): 816-822.
[2]	LI Siying, PAN Yangang, TENG Honggang, SHAN Yuping, YANG Guocheng, and WANG Hongda. Revealing the Cell Entry Dynamic Mechanism of Single Rabies Virus Particle[J]. 高等学校化学研究, 2022, 38(3): 838-842.
[3]	ZHANG Xiaosi, YANG Miao, TIAN Peng, LIU Zhongmin. Progress in Seed-assisted Synthesis of (Silico) Aluminophosphate Molecular Sieves[J]. 高等学校化学研究, 2022, 38(1): 1-8.
[4]	ZHOU Xue, WANG Chao, CHU Yueying, WANG Qiang, XU Jun, DENG Feng. Mechanistic Insight into Ethanol Dehydration over SAPO-34 Zeolite by Solid-state NMR Spectroscopy[J]. 高等学校化学研究, 2022, 38(1): 155-160.
[5]	ZHANG Luwei, LIU Jingyi, BAI Ling, WANG Ning. Diffusion Kinetics Study of Lithium Ion in the Graphdiyne Based Electrode[J]. 高等学校化学研究, 2021, 37(6): 1289-1295.
[6]	XU Haijiao, WANG Hongda. Conventional Molecular and Novel Structural Mechanistic Insights into Orderly Organelle Interactions[J]. 高等学校化学研究, 2021, 37(4): 829-839.
[7]	ZHANG Jianyu, ZHANG Haoke, LAM Jacky W. Y., TANG Ben Zhong. Restriction of Intramolecular Motion(RIM): Investigating AIE Mechanism from Experimental and Theoretical Studies[J]. 高等学校化学研究, 2021, 37(1): 1-15.
[8]	WANG Lipeng, LIU Leijing, XU Bin, TIAN Wenjing. Recent Advances in Mechanism of AIE Mechanochromic Materials[J]. 高等学校化学研究, 2021, 37(1): 100-109.
[9]	ZHAO Yangyang, LI Huangong, SUN Pengwei, GAO Li, ZHOU Sha, XIONG Lixia, YANG Na, LI Yuxin, LI Zhengming. Design, Synthesis, Biological Evaluation and SARs of Anthranilic Diamide Derivatives Containing Pyrrole Moieties[J]. 高等学校化学研究, 2020, 36(6): 1168-1173.
[10]	YU Bowen, LOU Caiyi, ZHANG Wenna, XU Shutao, HAN Jingfeng, YU Zhengxi, WEI Yingxu, LIU Zhongmin. Insight into the Dual Cycle Mechanism of Methanol-to-Olefins Reaction over SAPO-34 Molecular Sieve by Isotopic Tracer Studies[J]. 高等学校化学研究, 2020, 36(6): 1203-1208.
[11]	LI Ying, PAN Bo, MIAO Hongyan, XU Humin, LIU Xuefeng, SHI Gang. Single and Binary Dye Adsorption of Methylene Blue and Methyl Orange in Alcohol Aqueous Solution via Rice Husk Based Activated Carbon: Kinetics and Equilibrium Studies[J]. 高等学校化学研究, 2020, 36(6): 1272-1278.
[12]	LIU Yuanyuan, LI Yi, ZONG Linghui, ZHANG Jingyi. Comparison of Two Rhodamine-Polyamine Polystyrene Solid-phase Fluorescence Sensors for Hg(II) Detection Based on Theoretical Calculation[J]. 高等学校化学研究, 2020, 36(5): 781-786.
[13]	PEI Zhibin, LIU Yun, SUN Da, ZHU Zixuan, WANG Gongming. Phosphorene: a Potential 2D Material for Highly Efficient Polysulfide Trapping and Conversion[J]. 高等学校化学研究, 2020, 36(4): 631-639.
[14]	PAN Lu, DONG Jinyang, YI Ding, YANG Yijun, WANG Xi. Recent Advances in Atomic-scale Storage Mechanism Studies of Two-dimensional Nanomaterials for Rechargeable Batteries Beyond Li-ion[J]. 高等学校化学研究, 2020, 36(4): 560-583.
[15]	WANG Haitao, TANG Yongbing. Artificial Solid Electrolyte Interphase Acting as “Armor” to Protect the Anode Materials for High-performance Lithium-ion Battery[J]. 高等学校化学研究, 2020, 36(3): 402-409.

Kinetics and Mechanism of Oxidation of 1,2-Butanediol or Mephenesin by Ditelluratocuprate(III) in Alkaline Media

Kinetics and Mechanism of Oxidation of 1,2-Butanediol or Mephenesin by Ditelluratocuprate(III) in Alkaline Media

PDF (PC)

可视化

摘要/Abstract

引用本文

使用本文

参考文献

相关文章 15

编辑推荐

Metrics

本文评价