A New Organo-templated Layered Zincophosphate Synthesized from a Solvothermal System Containing Racemic1,2-Diaminopropane

高等学校化学研究 ›› 2002, Vol. 18 ›› Issue (4): 375-379.

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A New Organo-templated Layered Zincophosphate Synthesized from a Solvothermal System Containing Racemic1,2-Diaminopropane

CHEN Wei, YUAN Hong-ming, JIANG Yu-sheng, HUO Hua, CHEN Jie-sheng

State Key Laboratory of Inorganic Synthesis and Preparative Chemistry, Jilin University, Changchun 130023, P. R. China

收稿日期:2001-07-04 出版日期:2002-12-24 发布日期:2011-08-04
基金资助:
Supported by the National Natural Science Foundation of China(No.29931010).

A New Organo-templated Layered Zincophosphate Synthesized from a Solvothermal System Containing Racemic1,2-Diaminopropane

CHEN Wei, YUAN Hong-ming, JIANG Yu-sheng, HUO Hua, CHEN Jie-sheng

State Key Laboratory of Inorganic Synthesis and Preparative Chemistry, Jilin University, Changchun 130023, P. R. China

Received:2001-07-04 Online:2002-12-24 Published:2011-08-04
Supported by:
Supported by the National Natural Science Foundation of China(No.29931010).

摘要/Abstract

摘要： A new layered zincophosphate was synthesized under solvothermal conditions by employing racemic 1,2-diaminopropane as the structure-directing agent. The structure of the compound was solved by means of single-crystal X-ray diffraction analysis. It crystallized in the monoclinic space group P2₁/c (No. 14) with a=1.047 0(3) nm, b=0.787 31(18) nm, c=0.662 68(16) nm, β=103.120(5)°, V=0.532 0(2) nm³ and Z=4. The structure is made up of anionic zincophosphate sheets stacked in an AAAA sequence. The individual sheet contains three- and four-membered rings and the infinite Zn-O-Zn chains can also be envisaged in the sheet. The charge-balancing diprotonated racemic 1,2-diaminopropane cations are sandwiched between the layers, whereas the inorganic layers are stabilized by strong H-bonds formed between the N atoms of the amine and the O atoms in the inorganic sheets.

关键词: Layered zincophosphate, X-ray diffraction, Crystal structure, Racemic system

Abstract: A new layered zincophosphate was synthesized under solvothermal conditions by employing racemic 1,2-diaminopropane as the structure-directing agent. The structure of the compound was solved by means of single-crystal X-ray diffraction analysis. It crystallized in the monoclinic space group P2₁/c (No. 14) with a=1.047 0(3) nm, b=0.787 31(18) nm, c=0.662 68(16) nm, β=103.120(5)°, V=0.532 0(2) nm³ and Z=4. The structure is made up of anionic zincophosphate sheets stacked in an AAAA sequence. The individual sheet contains three- and four-membered rings and the infinite Zn-O-Zn chains can also be envisaged in the sheet. The charge-balancing diprotonated racemic 1,2-diaminopropane cations are sandwiched between the layers, whereas the inorganic layers are stabilized by strong H-bonds formed between the N atoms of the amine and the O atoms in the inorganic sheets.

Key words: Layered zincophosphate, X-ray diffraction, Crystal structure, Racemic system

CHEN Wei, YUAN Hong-ming, JIANG Yu-sheng, HUO Hua, CHEN Jie-sheng. A New Organo-templated Layered Zincophosphate Synthesized from a Solvothermal System Containing Racemic1,2-Diaminopropane[J]. 高等学校化学研究, 2002, 18(4): 375-379.

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A New Organo-templated Layered Zincophosphate Synthesized from a Solvothermal System Containing Racemic1,2-Diaminopropane

A New Organo-templated Layered Zincophosphate Synthesized from a Solvothermal System Containing Racemic1,2-Diaminopropane

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