Syntheses, Structures and Magnetic Properties of Two Coordination Polymers Based on 2, 2-Biphenyldicarboxylate Ligand

doi:10.1007/s40242-016-5365-6

高等学校化学研究 ›› 2016, Vol. 32 ›› Issue (2): 165-171.doi: 10.1007/s40242-016-5365-6

Syntheses, Structures and Magnetic Properties of Two Coordination Polymers Based on 2, 2-Biphenyldicarboxylate Ligand

ZHANG Qingfen, ZHOU Zhongyuan, WANG Xuan, LU Jing

Shandong Provincial Key Laboratory of Chemical Energy Storage and Novel Cell Technology, School of Chemistry and Chemical Engineering, Liaocheng University, Liaocheng 252059, P. R. China

收稿日期:2015-09-18 修回日期:2015-12-03 出版日期:2016-04-01 发布日期:2016-01-04
通讯作者: LU Jing E-mail:lujing@lcu.edu.cn
基金资助:
Supported by the National Natural Science Foundation of China(No.21101086).

Syntheses, Structures and Magnetic Properties of Two Coordination Polymers Based on 2, 2-Biphenyldicarboxylate Ligand

ZHANG Qingfen, ZHOU Zhongyuan, WANG Xuan, LU Jing

Shandong Provincial Key Laboratory of Chemical Energy Storage and Novel Cell Technology, School of Chemistry and Chemical Engineering, Liaocheng University, Liaocheng 252059, P. R. China

Received:2015-09-18 Revised:2015-12-03 Online:2016-04-01 Published:2016-01-04
Contact: LU Jing E-mail:lujing@lcu.edu.cn
Supported by:
Supported by the National Natural Science Foundation of China(No.21101086).

摘要/Abstract

摘要：

Two coordination polymers {[Co₃L₃(Me₂NH)₂]·(Me₂NH)}_n(1) and [CuL(bpy)]_n(2)(L=2,2'-biphenyl dicarboxylate ion, bpy=4,4'-bipyridine) were obtained and characterized. Compound 1 was synthesised via solvothermal method, with the L ligands adopting syn-syn-μ₂-η¹:η¹- and μ₂-η²-coordination modes and Co(II) centers being linked to form a 1D coordination chain with trinuclear Co₃ cluster as sub-units. Compound 2 was synthesized at room temperature, with the L ligand chelating the Cu(II) centers to form a 1D chain, which was further linked by the auxiliary 4,4'-bpy ligand to form a 3D coordination network. The results of variable temperature susceptibility studies reveal that there were ferromagnetic and antiferromagnetic interactions between the paramagnetic metal centers in compounds 1 and 2, respectively.

关键词: Coordination polymer, Crystal structure, Magnetic property

Abstract:

Key words: Coordination polymer, Crystal structure, Magnetic property

ZHANG Qingfen, ZHOU Zhongyuan, WANG Xuan, LU Jing. Syntheses, Structures and Magnetic Properties of Two Coordination Polymers Based on 2, 2-Biphenyldicarboxylate Ligand[J]. 高等学校化学研究, 2016, 32(2): 165-171.

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Syntheses, Structures and Magnetic Properties of Two Coordination Polymers Based on 2, 2-Biphenyldicarboxylate Ligand

Syntheses, Structures and Magnetic Properties of Two Coordination Polymers Based on 2, 2-Biphenyldicarboxylate Ligand

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