Propargylic Dialkyl Effect Oriented Mechanistic Dichotomy in Gold(I)-catalyzed Cycloisomerization of 1,6-Enynes

doi:10.1007/s40242-025-5107-8

Chemical Research in Chinese Universities ›› 2026, Vol. 42 ›› Issue (1): 381-386.doi: 10.1007/s40242-025-5107-8

• Letter • Previous Articles

Propargylic Dialkyl Effect Oriented Mechanistic Dichotomy in Gold(I)-catalyzed Cycloisomerization of 1,6-Enynes

GAO Qiangqiang¹, LI Yi¹, ZHOU Qinghai¹, LI Jin¹, HUA Yuhui¹, LIU Guohua¹, LIU Rui¹, ZHAN Xiaotong²

1. Joint Laboratory of International Cooperation of Resource Chemistry of Ministry of Education, Shanghai Frontiers Science Center of Biomimetic Catalysis, Key Laboratory of Resource Chemistry of Ministry of Education, Shanghai Key Laboratory of Rare Earth Functional Materials, Shanghai Normal University, Shanghai 200234, P. R. China;
2. Sinochem Dongda (Zibo) Co., Ltd., Zibo 256408, P. R. China

Received:2025-05-24 Online:2026-02-01 Published:2026-01-28
Contact: ZHAN Xiaotong,E-mail:zhanxiaotong@sinochem.com;LIU Rui,E-mail:rliu@shnu.edu.cn E-mail:zhanxiaotong@sinochem.com;rliu@shnu.edu.cn
Supported by:
This work was supported by the National Natural Science Foundation of China (Nos. 22001170 and 22071154), and the Shanghai Sciences and Technologies Development Fund, China (No. 20070502600).

Abstract

GAO Qiangqiang, LI Yi, ZHOU Qinghai, LI Jin, HUA Yuhui, LIU Guohua, LIU Rui, ZHAN Xiaotong. Propargylic Dialkyl Effect Oriented Mechanistic Dichotomy in Gold(I)-catalyzed Cycloisomerization of 1,6-Enynes[J]. Chemical Research in Chinese Universities, 2026, 42(1): 381-386.

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Propargylic Dialkyl Effect Oriented Mechanistic Dichotomy in Gold(I)-catalyzed Cycloisomerization of 1,6-Enynes

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