Coordination Polymers with Bipyridyl Diene and Triene Ligands: Synthesis, Structures and Luminescent Properties

doi:10.1007/s40242-021-1352-7

高等学校化学研究 ›› 2022, Vol. 38 ›› Issue (1): 209-216.doi: 10.1007/s40242-021-1352-7

Coordination Polymers with Bipyridyl Diene and Triene Ligands: Synthesis, Structures and Luminescent Properties

HUA Chen, YI Pin, LIU Wencong, WANG Mengfan, NIU Zheng, LANG Jianping

College of Chemistry, Chemical Engineering and Materials Science, Soochow University, Suzhou 215123, P. R. China

收稿日期:2021-09-02 修回日期:2021-09-26 出版日期:2022-02-01 发布日期:2021-10-08
通讯作者: LANG Jianping, NIU Zheng, WANG Mengfan E-mail:jplang@suda.edu.cn；zhengniu@suda.edu.cn；Wangmf2020@163.com
基金资助:
This work was supported by the National Natural Science Foundation of China (Nos. 21531006, 21773163), the Priority Academic Program Development of Jiangsu Higher Education Institutions, China, the Project of Scientific and Technologic Infrastructure of Suzhou, China(No.SZS201905), and the Undergraduate Training Program for Innovation and Entrepreneurship, Soochow University, China(No.202010285022Z).

Coordination Polymers with Bipyridyl Diene and Triene Ligands: Synthesis, Structures and Luminescent Properties

HUA Chen, YI Pin, LIU Wencong, WANG Mengfan, NIU Zheng, LANG Jianping

College of Chemistry, Chemical Engineering and Materials Science, Soochow University, Suzhou 215123, P. R. China

Received:2021-09-02 Revised:2021-09-26 Online:2022-02-01 Published:2021-10-08
Contact: LANG Jianping, NIU Zheng, WANG Mengfan E-mail:jplang@suda.edu.cn；zhengniu@suda.edu.cn；Wangmf2020@163.com
Supported by:
This work was supported by the National Natural Science Foundation of China (Nos. 21531006, 21773163), the Priority Academic Program Development of Jiangsu Higher Education Institutions, China, the Project of Scientific and Technologic Infrastructure of Suzhou, China(No.SZS201905), and the Undergraduate Training Program for Innovation and Entrepreneurship, Soochow University, China(No.202010285022Z).

摘要/Abstract

摘要： Solvothermal reactions of cadmium salts with bipyridyl diene and triene ligands[1,3-bis((E)-2-(pyridin-4-yl)vinyl)benzene-(1,3-bpeb) and 1,6-bis(4-pyridyl)-1,3,5-hexatriene(bphte)] and one bipyridyl triene ligand[1,6-bis(4-pyridyl)-1,3,5-hexatriene-(bphte)] in the presence of auxiliary carboxylic acids including 2,6-dichlorobenzoic acid(2,6-HDCBA) and 2-naphthal-enecarboxylic acid(2-HNCA) gave rise to four coordination polymers[Cd(bphte)(2,6-DCBA)₂]_n(1), {[Cd(bphte)(2-NCA)₂]·5.8H₂O}_n(2),[Cd₂(1,3-bpeb)₂(2,6-DCBA)₄]_n(3) and {[Cd₄(1,3-bpeb)₄(2-NCA)₇(HCOO)]·

2-HNCA·H₂O}_n(4), respectively. Compounds 1-4 were structurally characterized by elemental analysis, IR, ¹H NMR, powder X-ray diffraction, thermogravimetric analysis and single-crystal X-ray diffraction. They possess one-dimensional linear(1, 2) and zigzag(3, 4) chain structures. Their luminescent properties were explored while the representative sample 4 exhibited good luminescent performance in sensing Fe(III) in water.

关键词: Coordination polymer, Bipyridyl olefinic ligand, Crystal structure, Luminescent property

Abstract: Solvothermal reactions of cadmium salts with bipyridyl diene and triene ligands[1,3-bis((E)-2-(pyridin-4-yl)vinyl)benzene-(1,3-bpeb) and 1,6-bis(4-pyridyl)-1,3,5-hexatriene(bphte)] and one bipyridyl triene ligand[1,6-bis(4-pyridyl)-1,3,5-hexatriene-(bphte)] in the presence of auxiliary carboxylic acids including 2,6-dichlorobenzoic acid(2,6-HDCBA) and 2-naphthal-enecarboxylic acid(2-HNCA) gave rise to four coordination polymers[Cd(bphte)(2,6-DCBA)₂]_n(1), {[Cd(bphte)(2-NCA)₂]·5.8H₂O}_n(2),[Cd₂(1,3-bpeb)₂(2,6-DCBA)₄]_n(3) and {[Cd₄(1,3-bpeb)₄(2-NCA)₇(HCOO)]·

Key words: Coordination polymer, Bipyridyl olefinic ligand, Crystal structure, Luminescent property

HUA Chen, YI Pin, LIU Wencong, WANG Mengfan, NIU Zheng, LANG Jianping. Coordination Polymers with Bipyridyl Diene and Triene Ligands: Synthesis, Structures and Luminescent Properties[J]. 高等学校化学研究, 2022, 38(1): 209-216.

参考文献

[1] Foo M. L., Matsuda R., Hijikata Y., Krishna R., Sato H., Horike S., Hori A., Duan J., Sato Y., Kubota Y., Takata M., Kitagawa S., J. Am. Chem. Soc., 2016, 138, 3022
[2] Niu Z., Cui X., Pham T., Lan P. C., Xing H., Forrest K. A., Wojtas L., Space B., Ma S., Angew. Chem. Int. Ed., 2019, 58, 10138
[3] Savage M., Cheng Y., Easun T. L., Eyley J. E., Argent S. P., Warren M. R., Lewis W., Murray C., Tang C. C., Frogley M. D., Cinque G., Sun J., Rudic S., Murden R. T., Benham M. J., Fitch A. N., Blake A. J., Ramirez-Cuesta A. J., Yang S., Schroder M., Adv. Mater., 2016, 28, 8705
[4] Lin R. B., Li L., Zhou H. L., Wu H., He C., Li S., Krishna R., Li J., Zhou W., Chen B., Nat. Mater., 2018, 17, 1128
[5] Silva P., Vilela S. M., Tome J. P., Almeida Paz F. A., Chem. Soc. Rev., 2015, 44, 6774
[6] Lin R. B., Liu S. Y., Ye J. W., Li X. Y., Zhang J. P., Adv. Sci., 2016, 3, 1500434
[7] Stassen I., Burtch N., Talin A., Falcaro P., Allendorf M., Ameloot R., Chem. Soc. Rev., 2017, 46, 3185
[8] Yu M. H., Space B., Franz D., Zhou W., He C. H., Li L. B., Krishna R., Chang Z., Li W., Hu T. L., Bu X. H., J. Am. Chem. Soc., 2019, 141, 17703
[9] Wang H. Y., Su J., Ma J. P., Yu F., Leong C. F., D'Alessandro D. M., Kurmoo M., Zuo J. L., Inorg. Chem., 2019, 58, 8657
[10] Huang N., Wang K., Drake H., Cai P., PangJ., Li J., Che S., Huang L., Wang Q., Zhou H. C., J. Am. Chem. Soc., 2018, 140, 6383
[11] Niu Z., Bhagya Gunatilleke W. D. C., Sun Q., Lan P. C., Perman J., Ma J. G., Cheng Y., Aguila B., Ma S., Chem, 2018, 4, 2587
[12] Hu F. L., Wang H. F., Guo D., Zhang H., Lang J. P., Beves J. E., Chem. Commun., 2016, 52, 7990
[13] Claassens I. E., Barbour L. J., Haynes D. A., J. Am. Chem. Soc., 2019, 141, 11425
[14] Yu J. G., Gan M. M., Bai S., Han Y. F., CrystEngComm., 2019, 21, 4673
[15] Kole G. K., Kojima T., Kawano M., Vittal J. J., Angew. Chem. Int. Ed., 2014, 53, 2143
[16] Claassens I. E., Nikolayenko V. I., Haynes D. A., Barbour L. J., Angew. Chem. Int. Ed., 2018, 57, 15563
[17] Yadava K., Vittal J. J., Cryst. Growth Des., 2019, 19, 2542
[18] He J., Xu J. L., Yin J. C., Li N., Bu X. H., Sci. China Mater., 2019, 62, 1655
[19] Gong W. J., Ren Z. G., Li H. X., Zhang J. G., Lang J. P., Cryst. Growth Des., 2017, 17, 870
[20] Liu D., Ren Z. G., Li H. X., Lang J. P., Li N. Y., Abrahams B. F., Angew. Chem. Int. Ed., 2010, 49, 4767
[21] Hu F. L., Wang S. L., Lang J. P., Abrahams B. F., Sci. Rep., 2014, 4, 6815
[22] Hu F. L., Mi Y., Zhu C., Abrahams B. F., Braunstein P., Lang J. P., Angew. Chem. Int. Ed., 2018, 57, 12696
[23] Shi Y. X., Zhang W. H., Abrahams B. F., Braunstein P., Lang J. P., Angew. Chem. Int. Ed., 2019, 58, 9453
[24] Wang M. F., Mi Y., Hu F. L., Niu Z., Yin X. H., Huang Q., Wang H. F., Lang J. P., J. Am. Chem. Soc., 2020, 142, 700
[25] Hu F. L., Shi Y. X., Chen H. H., Lang J. P., Dalton Trans, 2015, 44, 18795
[26] Li N. Y., Liu D., Ren Z. G., Lollar C., Lang J. P., Zhou H. C., Inorg. Chem., 2018, 57, 849
[27] Petrcarsky S. H., Stemmler I., Scheutzow D., Liebigs Ann. Chem., 1980, 2, 291
[28] Sheldrick G. M., Acta Crystallogr., Sect. C:Struct. Chem., 2015, 71, 3
[29] Dolomanov O. V., Bourhis L. J., Gildea R. J., Howard J. A. K., Puschmann H., J. Appl. Crystallogr., 2009, 42, 339
[30] Spek A. L., J. Appl. Crystallogr., 2003, 36, 7
[31] Burrow A. D., Cassar K., Duren T., Friend R. M. W., Mahon M. F., Gigby S. P., Savarese T. L., Dalton Trans., 2008, 2465
[32] Hu F. L., Wu W., Liang P., Gu Y. Q., Zhu L. G., Wei H., Lang J. P., Cryst. Growth Des., 2013, 13, 5050
[33] Jadhav T., Fang Y., Liu C. H., Dadvand A., Hamzehpoor E., Patterson W., Jonderian A., Stein R. S., Perepichka D. F., J. Am. Chem. Soc., 2020, 142, 8862
[34] Schmidt G. M. J., Pure Appl. Chem.,1971, 27, 647
[35] Kuai H. W., Xu X. Y., Cheng X. C., Feng L. D., Zhu X. H., J. Coord. Chem., 2013, 66, 4304
[36] Lv R., Wang J., Zhang Y., Li H., Yang L., Liao S., Gu W., Liu X., J. Mater. Chem. A, 2016, 4, 15494
[37] Wen L., Zheng X., Lv K., Wang C., Xu X., Inorg. Chem., 2015, 54, 7133
[38] Chen B., Wang L., Xiao Y., Fronczek F. R., Xue M., Cui Y., Qian G., Angew. Chem. Int. Ed., 2009, 48, 500
[39] Liu S., Xiang Z., Hu Z., Zheng X., Cao D., J. Mater. Chem., 2011, 21, 6649
[40] Wen R. M., Han S. D., Ren G. J., Chang Z., Li Y. W., Bu X. H., Dalton. Trans., 2015, 44, 10914
[41] Donges D., Nagle J. K., Yersin H., Inorg. Chem., 1997, 36, 3040
[42] Vogler A., Kunkely H., Coord. Chem. Rev., 2001, 219, 489
[43] Vogler A., Kunkely H., Coord. Chem. Rev., 2007, 251, 577
[44] Allendorf M. D., Bauer C. A., Bhakta R. K., Houk R. J., Chem. Soc. Rev., 2009, 38, 1330
[45] Champness N. R., Dalton. Trans., 2011, 40, 10311
[46] Li W. X., Gu J. H., Li H. X., Dai M., Young D. J., Li H. Y., Lang J. P., Inorg. Chem., 2018, 57, 13453
[47] Das D., Biradha K., Cryst. Growth Des., 2018, 18, 3683

Coordination Polymers with Bipyridyl Diene and Triene Ligands: Synthesis, Structures and Luminescent Properties

Coordination Polymers with Bipyridyl Diene and Triene Ligands: Synthesis, Structures and Luminescent Properties

可视化

摘要/Abstract

引用本文

使用本文

参考文献

相关文章 15

编辑推荐

Metrics

本文评价

[1]	WANG Yue, WANG Jinling, MA Jianxin, ZHANG Yue, XU Na, WANG Xiuli. Multi-functional Photoelectric Sensor Based on a Three-fold Interpenetrated Cd(II) Coordination Polymer for Sensitively Detecting Different Ions[J]. 高等学校化学研究, 2022, 38(4): 1105-1110.
[2]	ZHANG Wenqi, LIN Zhengguo, CHI Yingnan, HONG Jie, YAN Li, HU Changwen. Assembly of Three Scandium-containing Heteropolytungstates Based on a Building-block Synthetic Strategy[J]. 高等学校化学研究, 2020, 36(6): 1161-1167.
[3]	FU Pengyan, MO Junting, SUN Sisi, YIN Shaoyun, WANG Haiping, PAN Mei. Acid-base Vapor Sensing Enabled by ESIPT-attributed Cd(II) Coordination Polymer with Switchable Luminescence[J]. 高等学校化学研究, 2020, 36(5): 755-759.
[4]	QIAN Binbin, CHANG Ze, BU Xian-He. Zinc-coordination Polymers Based on a Donor-acceptor Mix-ligand System: Syntheses, Crystal Structures and Photophysical Properties[J]. 高等学校化学研究, 2020, 36(1): 74-80.
[5]	ZANG Jiahe, ZHANG Qing'an, SUN Dalin. Crystal Structures and Electrochemical Properties of R_1.5Ca_1.5MgNi₁₄(R=Nd, Gd and Er) Hydrogen Storage Alloys[J]. 高等学校化学研究, 2019, 35(6): 1040-1045.
[6]	WANG Dongmei, LOU Shengjun, YING Yiting, GUO Zhiqi, WANG Lijun. Assembly of Two Isostructural Metal-organic Frameworks Based on Hetero-N,O Donor Ligand for Detecting Nitro Explosives[J]. 高等学校化学研究, 2019, 35(5): 762-766.
[7]	MA Xiao, WANG Xiaohong, SHANG Fan, DING Zimei, HANG Xiaojing, HUANG Jie. Studies on 3-Amino-4-(1H-tetrazol-5-yl)-furazan: Crystal Structure, Thermal Behavior and Energetic Performance[J]. 高等学校化学研究, 2019, 35(5): 848-853.
[8]	LU Xue, LIU Guocheng, WANG Xiang, LIN Hongyan, WANG Xiuli. Carboxylate-induced Various Structures of Ni(Ⅱ) Complexes with Fluorescence Sensing and Bifunctional Electrochemical Properties[J]. 高等学校化学研究, 2019, 35(4): 549-555.
[9]	ZHONG Liangxuan, LIU Mingyue, ZHANG Bowei, SUN Yaqiu, XU Yanyan. Syntheses, Crystal Structures, Magnetic and Near-infrared Luminescence Properties of 3d-4f Coordination Polymers Cu₂Pr₂, Cu₂Eu₂ and Cu₄Tb₂[J]. 高等学校化学研究, 2019, 35(4): 693-699.
[10]	YU Yanzhao, CAO Jiapeng, XU Yan. Two Pentavanadate-based Organic-inorganic Materials with Third-order NLO Properties[J]. 高等学校化学研究, 2019, 35(1): 1-4.
[11]	DING Zimei, CAO Wenli, ZHENG Hui, HUANG Jie, XU Kangzhen, SONG Jirong. Synthesis, Structure Characteristic and Thermal Behavior of Two New Metal-organic Azo-triazole Compounds: [Zn(phen)₃]·ZTO·6H₂O and[Cu(phen)₃]·ZTO·6H₂O[J]. 高等学校化学研究, 2018, 34(6): 1009-1013.
[12]	CHEN Xiang, ZENG Tian, ZHANG Cong, GUO Zhaoqi, LI Shuailei, MAI Tao, GAO Rong, MA Haixia. Crystal Structures, Thermal Behavior Analysis and Thermal Safety of Two Energetic Salts of Hydrazinyl-1,2,4,5-tetrazine with 3,5-Dinitrosalicylic Acid[J]. 高等学校化学研究, 2018, 34(6): 959-964.
[13]	KANG Dawei, XIE Jingjing, LIU Yingying, MA Jianfang. Four Coordination Polymers Assembled with a New Biscarboxyl-functionalized Schiff Base Ligand[J]. 高等学校化学研究, 2018, 34(5): 839-843.
[14]	LIU Chao, LIU Yijie, ZHANG Lili, JIANG Kun, ZHANG Li. Two Coordination Compounds Bearing Bis(2-dimethylaminoethyl) Ether: Syntheses, Crystal Structures and Catalytic Application to the Henry Reaction[J]. 高等学校化学研究, 2018, 34(3): 358-362.
[15]	WANG Jingyang, ZHANG Meng, XU Xiaodong, FENG Jing, WANG Yanli, ZHANG Milin, HAN Wei, CHEN Yitung, TIAN Guoxin. Synthesis and Characterization of [Cu(N-MeIm)₄(BF₄)₂] in Ionic Liquid[J]. 高等学校化学研究, 2018, 34(1): 8-12.