Synthesis, Structure and Characterization of Three Metal Molybdate Hydrates: Fe(H2O)2(MoO4)2·H3O, NaCo2(MoO4)2(H3O2) and Mn2(MoO4)3·2H3O

高等学校化学研究 ›› 2012, Vol. 28 ›› Issue (2): 186-190 .

Synthesis, Structure and Characterization of Three Metal Molybdate Hydrates: Fe(H₂O)₂(MoO₄)₂·H₃O, NaCo₂(MoO₄)₂(H₃O₂) and Mn₂(MoO₄)₃·₂H₃O

YU Yang, LIU Dan, HU Wei-wei, LI Jia, PENG Yu, ZHOU Qi, YANG Fen, LI Guang-hua, SHI Zhan, FENG Shou-hua

State Key Laboratory of Inorganic Synthesis & Preparative Chemistry, College of Chemistry, Jilin University, Changchun 130012, P. R. China

收稿日期:2011-03-01 修回日期:2011-04-30 出版日期:2012-03-25 发布日期:2012-03-08
通讯作者: LI Guang-hua, SHI Zhan E-mail:zshi@jlu.edu.cn; leegh@jlu.edu.cn
基金资助:
Supported by the National Natural Science Foundation of China(Nos.20971054, 90922034) and the Key Project of the Mi- nistry of Education of China(No.2009-49).

Synthesis, Structure and Characterization of Three Metal Molybdate Hydrates: Fe(H₂O)₂(MoO₄)₂·H₃O, NaCo₂(MoO₄)₂(H₃O₂) and Mn₂(MoO₄)₃·₂H₃O

YU Yang, LIU Dan, HU Wei-wei, LI Jia, PENG Yu, ZHOU Qi, YANG Fen, LI Guang-hua, SHI Zhan, FENG Shou-hua

State Key Laboratory of Inorganic Synthesis & Preparative Chemistry, College of Chemistry, Jilin University, Changchun 130012, P. R. China

Received:2011-03-01 Revised:2011-04-30 Online:2012-03-25 Published:2012-03-08
Supported by:
Supported by the National Natural Science Foundation of China(Nos.20971054, 90922034) and the Key Project of the Mi- nistry of Education of China(No.2009-49).

摘要/Abstract

摘要： Three metal molybdate hydrates, Fe(H₂O)₂(MoO₄)₂·H₃O(FeMo), NaCo₂(MoO₄)₂(H₃O₂)(CoMo) and Mn₂(MoO₄)₃·2H₃O(MnMo), were synthesized by the mixed-solvent-thermal methods and characterized by single- crystal X-ray diffraction. X-Ray photoelectron spectroscopy and bond-valence sums were applied to confirming the valance of Fe, Co, Mn and Mo. Thermo-gravimetric analysis and X-ray powder diffraction measurements indicate that the samples were converted to different structural compounds upon heating in air at 600 °C for 1 h. The magnetic properties of these compounds were studied. The dominant magnetic interactions are antiferromagnetic in nature. However, different synthesis conditions led to the diversity of magnetic properties of compound CoMo.

关键词: Mixed-solvent-thermal synthesis, Crystal structure, Transition metal molybdate, Magnetic property

Abstract: Three metal molybdate hydrates, Fe(H₂O)₂(MoO₄)₂·H₃O(FeMo), NaCo₂(MoO₄)₂(H₃O₂)(CoMo) and Mn₂(MoO₄)₃·2H₃O(MnMo), were synthesized by the mixed-solvent-thermal methods and characterized by single- crystal X-ray diffraction. X-Ray photoelectron spectroscopy and bond-valence sums were applied to confirming the valance of Fe, Co, Mn and Mo. Thermo-gravimetric analysis and X-ray powder diffraction measurements indicate that the samples were converted to different structural compounds upon heating in air at 600 °C for 1 h. The magnetic properties of these compounds were studied. The dominant magnetic interactions are antiferromagnetic in nature. However, different synthesis conditions led to the diversity of magnetic properties of compound CoMo.

Key words: Mixed-solvent-thermal synthesis, Crystal structure, Transition metal molybdate, Magnetic property

YU Yang, LIU Dan, HU Wei-wei, LI Jia, PENG Yu, ZHOU Qi, YANG Fen, LI Guang-hua, SHI Zhan, FENG Shou-hua. Synthesis, Structure and Characterization of Three Metal Molybdate Hydrates: Fe(H₂O)₂(MoO₄)₂·H₃O, NaCo₂(MoO₄)₂(H₃O₂) and Mn₂(MoO₄)₃·₂H₃O[J]. 高等学校化学研究, 2012, 28(2): 186-190 .

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Synthesis, Structure and Characterization of Three Metal Molybdate Hydrates: Fe(H₂O)₂(MoO₄)₂·H₃O, NaCo₂(MoO₄)₂(H₃O₂) and Mn₂(MoO₄)₃·₂H₃O

Synthesis, Structure and Characterization of Three Metal Molybdate Hydrates: Fe(H₂O)₂(MoO₄)₂·H₃O, NaCo₂(MoO₄)₂(H₃O₂) and Mn₂(MoO₄)₃·₂H₃O

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