The Study of Oxygen Transfer Kinetics for MoO2(S2CENt2)2 in Various Solvents

高等学校化学研究 ›› 1988, Vol. 4 ›› Issue (2): 85-90.

The Study of Oxygen Transfer Kinetics for MoO₂(S₂CENt₂)₂ in Various Solvents

Yang Huixing, Chen Yu, He Hong

Department of Chemistry, Peking University, Beijing

收稿日期:1987-09-27 出版日期:1988-04-24 发布日期:2011-09-09

The Study of Oxygen Transfer Kinetics for MoO₂(S₂CENt₂)₂ in Various Solvents

Yang Huixing, Chen Yu, He Hong

Department of Chemistry, Peking University, Beijing

Received:1987-09-27 Online:1988-04-24 Published:2011-09-09

摘要/Abstract

摘要： The reaction kinetics between MoO₂(S₂CNEt₂)₂ and triphenylphos-phine (PPh₃) were studied in various organic solvents with the aid of the stopped-flow technique. The linear correlations were found for rate constants or activation energy versus the function of refractive index (n²- 1)/(2n² + 1). It was also found that pre-factor increases with the descent of ( n² - l)/(2n² - 1) slightly.One step mechanism which supposes the lone pair of electrons on P atom of triphenylphosphine enters directly into the Ⅱ^* antibonding orbital, which makes the Mo= O bond broken, is suggested.

关键词: Rate constant, Activation energy, Pre-factor, Refractive index, Mechanism, Anti bond orbital

Abstract: The reaction kinetics between MoO₂(S₂CNEt₂)₂ and triphenylphos-phine (PPh₃) were studied in various organic solvents with the aid of the stopped-flow technique. The linear correlations were found for rate constants or activation energy versus the function of refractive index (n²- 1)/(2n² + 1). It was also found that pre-factor increases with the descent of ( n² - l)/(2n² - 1) slightly.One step mechanism which supposes the lone pair of electrons on P atom of triphenylphosphine enters directly into the Ⅱ^* antibonding orbital, which makes the Mo= O bond broken, is suggested.

Key words: Rate constant, Activation energy, Pre-factor, Refractive index, Mechanism, Anti bond orbital

Yang Huixing, Chen Yu, He Hong. The Study of Oxygen Transfer Kinetics for MoO₂(S₂CENt₂)₂ in Various Solvents[J]. 高等学校化学研究, 1988, 4(2): 85-90.

Yang Huixing, Chen Yu, He Hong. The Study of Oxygen Transfer Kinetics for MoO₂(S₂CENt₂)₂ in Various Solvents[J]. Chemical Research in Chinese Universities, 1988, 4(2): 85-90.

[1]	HU Shifan, WANG Yafeng and SU Bin. Effect of Ionic Strength on the Electrochemiluminescence Generation by Tris(2,2'-bipyridyl)ruthenium(II)/Tri-n-propylamine[J]. 高等学校化学研究, 2022, 38(3): 816-822.
[2]	LI Siying, PAN Yangang, TENG Honggang, SHAN Yuping, YANG Guocheng, and WANG Hongda. Revealing the Cell Entry Dynamic Mechanism of Single Rabies Virus Particle[J]. 高等学校化学研究, 2022, 38(3): 838-842.
[3]	ZHANG Xiaosi, YANG Miao, TIAN Peng, LIU Zhongmin. Progress in Seed-assisted Synthesis of (Silico) Aluminophosphate Molecular Sieves[J]. 高等学校化学研究, 2022, 38(1): 1-8.
[4]	ZHOU Xue, WANG Chao, CHU Yueying, WANG Qiang, XU Jun, DENG Feng. Mechanistic Insight into Ethanol Dehydration over SAPO-34 Zeolite by Solid-state NMR Spectroscopy[J]. 高等学校化学研究, 2022, 38(1): 155-160.
[5]	XU Haijiao, WANG Hongda. Conventional Molecular and Novel Structural Mechanistic Insights into Orderly Organelle Interactions[J]. 高等学校化学研究, 2021, 37(4): 829-839.
[6]	ZHANG Jianyu, ZHANG Haoke, LAM Jacky W. Y., TANG Ben Zhong. Restriction of Intramolecular Motion(RIM): Investigating AIE Mechanism from Experimental and Theoretical Studies[J]. 高等学校化学研究, 2021, 37(1): 1-15.
[7]	WANG Lipeng, LIU Leijing, XU Bin, TIAN Wenjing. Recent Advances in Mechanism of AIE Mechanochromic Materials[J]. 高等学校化学研究, 2021, 37(1): 100-109.
[8]	YU Bowen, LOU Caiyi, ZHANG Wenna, XU Shutao, HAN Jingfeng, YU Zhengxi, WEI Yingxu, LIU Zhongmin. Insight into the Dual Cycle Mechanism of Methanol-to-Olefins Reaction over SAPO-34 Molecular Sieve by Isotopic Tracer Studies[J]. 高等学校化学研究, 2020, 36(6): 1203-1208.
[9]	ZHAO Yangyang, LI Huangong, SUN Pengwei, GAO Li, ZHOU Sha, XIONG Lixia, YANG Na, LI Yuxin, LI Zhengming. Design, Synthesis, Biological Evaluation and SARs of Anthranilic Diamide Derivatives Containing Pyrrole Moieties[J]. 高等学校化学研究, 2020, 36(6): 1168-1173.
[10]	LIU Yuanyuan, LI Yi, ZONG Linghui, ZHANG Jingyi. Comparison of Two Rhodamine-Polyamine Polystyrene Solid-phase Fluorescence Sensors for Hg(II) Detection Based on Theoretical Calculation[J]. 高等学校化学研究, 2020, 36(5): 781-786.
[11]	PAN Lu, DONG Jinyang, YI Ding, YANG Yijun, WANG Xi. Recent Advances in Atomic-scale Storage Mechanism Studies of Two-dimensional Nanomaterials for Rechargeable Batteries Beyond Li-ion[J]. 高等学校化学研究, 2020, 36(4): 560-583.
[12]	WANG Haitao, TANG Yongbing. Artificial Solid Electrolyte Interphase Acting as “Armor” to Protect the Anode Materials for High-performance Lithium-ion Battery[J]. 高等学校化学研究, 2020, 36(3): 402-409.
[13]	CHEN Jianyu, XU Xin, HE Qian, MA Yanwen. Advanced Current Collectors for Alkali Metal Anodes[J]. 高等学校化学研究, 2020, 36(3): 386-401.
[14]	YANG Peihua, FAN Hongjin. Electrochemical Impedance Analysis of Thermogalvanic Cells[J]. 高等学校化学研究, 2020, 36(3): 420-424.
[15]	WANG Shuxin, CAO Jian, CHENG Yuxiao, LU Chenhong. A Sensitive Fluorescent Turn-on Probe NapP-deap Based on Naphthalimide Derivative to Detect Hg(II) Ions in HEPES Buffer Solution and Living Cells[J]. 高等学校化学研究, 2019, 35(6): 967-971.

The Study of Oxygen Transfer Kinetics for MoO₂(S₂CENt₂)₂ in Various Solvents

The Study of Oxygen Transfer Kinetics for MoO₂(S₂CENt₂)₂ in Various Solvents

PDF (PC)

可视化

摘要/Abstract

引用本文

使用本文

参考文献

相关文章 15

编辑推荐

Metrics

本文评价