Solvothermal Synthesis and Crystal Structure of Zn(en)3 B5 O7 (OH)3

高等学校化学研究 ›› 2006, Vol. 22 ›› Issue (3): 271-273.

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Solvothermal Synthesis and Crystal Structure of Zn(en)₃ B₅ O₇ (OH)₃

HE Yi, CHEN Wei, YANG Jin, XI Chun-yu, CHEN Jie-sheng

State Key Laboratory of Inorganic Synthesis and Preparative Chemistry, College of Chemistry, Jilin University, Changchun 130012, P.R. China

收稿日期:2005-09-19 出版日期:2006-06-24 发布日期:2011-08-06
基金资助:
Supported by the National Natural Science Foundation of China (No. 20128001).

Solvothermal Synthesis and Crystal Structure of Zn(en)₃ B₅ O₇ (OH)₃

HE Yi, CHEN Wei, YANG Jin, XI Chun-yu, CHEN Jie-sheng

State Key Laboratory of Inorganic Synthesis and Preparative Chemistry, College of Chemistry, Jilin University, Changchun 130012, P.R. China

Received:2005-09-19 Online:2006-06-24 Published:2011-08-06
Supported by:
Supported by the National Natural Science Foundation of China (No. 20128001).

摘要/Abstract

摘要： A new polyborate containing chiral metal-complex Zn (en)₃ B₅ O₇ (OH)₃, where en = ethylenediamine, was synthesizedunder solvothermal conditions and structurally characterized by means of X-ray diffraction analysis. Crystal data: Zn (en)₃ B₅ O₇ (OH)₃, monoclinic, space group P2₁/c, a = 0. 8532 (72) nm, b = 2. 3340 (5) nm, c =0.9526(92) nm, β=107.04(3)°, Z=4, V=1.8140(6) nm³, D_c =1.694 g/cm³,μ=1.416 mm^-1, F(000)960, GOF= 1.020, R = 0.0276, R_w = 0. 0828. There is a chira l Zn(en)₃²⁺ com plex cation and an iso lated B₅O₇· =(OH)₃^2- group in a Zn(en)₃B₅O₇ (OH)₃ molecule. The enantiomer of the chiral complex cation is separated orderly as Δ and Λ configurations in the compound and the borate group consists of two B₃O₃ cycles linked through a bridging boron atom.

关键词: Solvothermal synthesis, Crystal structure, Chiral metal-complex, Borate compound

Abstract: A new polyborate containing chiral metal-complex Zn (en)₃ B₅ O₇ (OH)₃, where en = ethylenediamine, was synthesizedunder solvothermal conditions and structurally characterized by means of X-ray diffraction analysis. Crystal data: Zn (en)₃ B₅ O₇ (OH)₃, monoclinic, space group P2₁/c, a = 0. 8532 (72) nm, b = 2. 3340 (5) nm, c =0.9526(92) nm, β=107.04(3)°, Z=4, V=1.8140(6) nm³, D_c =1.694 g/cm³,μ=1.416 mm^-1, F(000)960, GOF= 1.020, R = 0.0276, R_w = 0. 0828. There is a chira l Zn(en)₃²⁺ com plex cation and an iso lated B₅O₇· =(OH)₃^2- group in a Zn(en)₃B₅O₇ (OH)₃ molecule. The enantiomer of the chiral complex cation is separated orderly as Δ and Λ configurations in the compound and the borate group consists of two B₃O₃ cycles linked through a bridging boron atom.

Key words: Solvothermal synthesis, Crystal structure, Chiral metal-complex, Borate compound

HE Yi, CHEN Wei, YANG Jin, XI Chun-yu, CHEN Jie-sheng. Solvothermal Synthesis and Crystal Structure of Zn(en)₃ B₅ O₇ (OH)₃[J]. 高等学校化学研究, 2006, 22(3): 271-273.

HE Yi, CHEN Wei, YANG Jin, XI Chun-yu, CHEN Jie-sheng. Solvothermal Synthesis and Crystal Structure of Zn(en)₃ B₅ O₇ (OH)₃[J]. Chemical Research in Chinese Universities, 2006, 22(3): 271-273.

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Solvothermal Synthesis and Crystal Structure of Zn(en)₃ B₅ O₇ (OH)₃

Solvothermal Synthesis and Crystal Structure of Zn(en)₃ B₅ O₇ (OH)₃

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