Progress and Outlook of Carbon-supported Single-atom Electrocatalyst for Oxygen Reduction Reaction

doi:10.1007/s40242-024-4072-y

高等学校化学研究 ›› 2024, Vol. 40 ›› Issue (3): 462-474.doi: 10.1007/s40242-024-4072-y

Progress and Outlook of Carbon-supported Single-atom Electrocatalyst for Oxygen Reduction Reaction

WANG Chengbin¹, LI Ping¹, CHEN Dehong², ZHANG Ruiyong³, WANG Lei¹, ZONG Lingbo¹

1. College of Chemistry and Molecular Engineering, Qingdao University of Science and Technology, Qingdao 266042, P. R. China;
2. College of Materials Science and Engineering, Qingdao University of Science and Technology, Qingdao 266042, P. R. China;
3. Key Laboratory of Marine Environmental Corrosion and Bio-fouling, Institute of Oceanology, Chinese Academy of Sciences, Qingdao 266071, P. R. China

收稿日期:2024-03-23 出版日期:2024-06-01 发布日期:2024-06-01
通讯作者: ZONG Lingbo,E-mail:lingbozong@qust.edu.cn E-mail:lingbozong@qust.edu.cn
基金资助:
This work was supported by the National Natural Science Foundation of China (No. 52172208), the Taishan Scholar Young Talent Program, China (No. tsqn202306216), and the Taishan Scholar Talent Program, China (No. ts20190402).

Progress and Outlook of Carbon-supported Single-atom Electrocatalyst for Oxygen Reduction Reaction

WANG Chengbin¹, LI Ping¹, CHEN Dehong², ZHANG Ruiyong³, WANG Lei¹, ZONG Lingbo¹

1. College of Chemistry and Molecular Engineering, Qingdao University of Science and Technology, Qingdao 266042, P. R. China;
2. College of Materials Science and Engineering, Qingdao University of Science and Technology, Qingdao 266042, P. R. China;
3. Key Laboratory of Marine Environmental Corrosion and Bio-fouling, Institute of Oceanology, Chinese Academy of Sciences, Qingdao 266071, P. R. China

Received:2024-03-23 Online:2024-06-01 Published:2024-06-01
Contact: ZONG Lingbo,E-mail:lingbozong@qust.edu.cn E-mail:lingbozong@qust.edu.cn
Supported by:
This work was supported by the National Natural Science Foundation of China (No. 52172208), the Taishan Scholar Young Talent Program, China (No. tsqn202306216), and the Taishan Scholar Talent Program, China (No. ts20190402).

摘要/Abstract

摘要： Single-atom catalysts (SACs) have garnered extensive attention in the field of catalysis due to their exceptional inherent reaction activity, optimal utilization of metal atoms, etc. Controlled synthesis plays a crucial role in elucidating the structure-activity relationship of SACs. This paper reviews various synthetic strategies for SACs, encompassing defect engineering, metal-organic frameworks (MOFs) pyrolysis, and ion exchange. With specific examples, the significance of constructing catalysts at the atomic level is discussed, aiming to comprehensively understand the synthetic strategies of SACs. Finally, it addresses the challenges and prospects associated with controlled synthesis techniques for SACs as well as their future applications.

关键词: Single-atom catalyst, Synthetic strategy, Carbon support, Oxygen reduction reaction

Abstract: Single-atom catalysts (SACs) have garnered extensive attention in the field of catalysis due to their exceptional inherent reaction activity, optimal utilization of metal atoms, etc. Controlled synthesis plays a crucial role in elucidating the structure-activity relationship of SACs. This paper reviews various synthetic strategies for SACs, encompassing defect engineering, metal-organic frameworks (MOFs) pyrolysis, and ion exchange. With specific examples, the significance of constructing catalysts at the atomic level is discussed, aiming to comprehensively understand the synthetic strategies of SACs. Finally, it addresses the challenges and prospects associated with controlled synthesis techniques for SACs as well as their future applications.

Key words: Single-atom catalyst, Synthetic strategy, Carbon support, Oxygen reduction reaction

WANG Chengbin, LI Ping, CHEN Dehong, ZHANG Ruiyong, WANG Lei, ZONG Lingbo. Progress and Outlook of Carbon-supported Single-atom Electrocatalyst for Oxygen Reduction Reaction[J]. 高等学校化学研究, 2024, 40(3): 462-474.

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Progress and Outlook of Carbon-supported Single-atom Electrocatalyst for Oxygen Reduction Reaction

Progress and Outlook of Carbon-supported Single-atom Electrocatalyst for Oxygen Reduction Reaction

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