Carrier Dynamics and Surface Reaction Boosted by Polymer-based Single-atom Photocatalysts

doi:10.1007/s40242-022-2215-6

高等学校化学研究 ›› 2022, Vol. 38 ›› Issue (5): 1207-1218.doi: 10.1007/s40242-022-2215-6

Carrier Dynamics and Surface Reaction Boosted by Polymer-based Single-atom Photocatalysts

TENG Zhenyuan¹, YANG Hongbin², ZHANG Qitao³, OHNO Teruhisa¹

1. Department of Applied Chemistry, Faculty of Engineering, Kyushu Institute of Technology, Kitakyushu 804-8550, Japan;
2. School of Materials Science and Engineering, Suzhou University of Science and Technology, Suzhou 215009, P. R. China;
3. International Collaborative Laboratory of 2D Materials for Optoelectronics Science and Technology of Ministry of Education, Institute of Microscale Optoelectronics, Shenzhen University, Shenzhen 518060, P. R. China

收稿日期:2022-06-28 出版日期:2022-10-01 发布日期:2022-10-08
通讯作者: TENG Zhenyuan E-mail:zy.teng@foxmail.com
基金资助:
This work was supported by the Mitsubishi Chemical Corporation, JSPS Grant-in-Aid for Scientific Research(B, No.20H02847), the Grant-in-Aid for JSPS Fellows(DC2, No.20J13064), the National Natural Science Foundation of China(No.21805191), the Guangdong Basic and Applied Basic Research Foundation, China(No.2020A1515010982), and the Shenzhen Stable Support Project, China(No.20200812122947002).

Carrier Dynamics and Surface Reaction Boosted by Polymer-based Single-atom Photocatalysts

TENG Zhenyuan¹, YANG Hongbin², ZHANG Qitao³, OHNO Teruhisa¹

1. Department of Applied Chemistry, Faculty of Engineering, Kyushu Institute of Technology, Kitakyushu 804-8550, Japan;
2. School of Materials Science and Engineering, Suzhou University of Science and Technology, Suzhou 215009, P. R. China;
3. International Collaborative Laboratory of 2D Materials for Optoelectronics Science and Technology of Ministry of Education, Institute of Microscale Optoelectronics, Shenzhen University, Shenzhen 518060, P. R. China

Received:2022-06-28 Online:2022-10-01 Published:2022-10-08
Contact: TENG Zhenyuan E-mail:zy.teng@foxmail.com
Supported by:
This work was supported by the Mitsubishi Chemical Corporation, JSPS Grant-in-Aid for Scientific Research(B, No.20H02847), the Grant-in-Aid for JSPS Fellows(DC2, No.20J13064), the National Natural Science Foundation of China(No.21805191), the Guangdong Basic and Applied Basic Research Foundation, China(No.2020A1515010982), and the Shenzhen Stable Support Project, China(No.20200812122947002).

摘要/Abstract

摘要： Carrier dynamics and surface reaction are two critical processes for determining the performance of photocatalytic reaction. Highly designable polymer-based photocatalysts have shown promising protectives in energetic and environmental applications. In this prospective, we first distinguished the differences of physiochemical properties between polymer-based semiconductors and traditional inorganic semiconductors. Then, the effects of single-atom sites on the charge dynamics and reaction kinetics of polymer-based photocatalysts are further elaborated. Time(excitation)-space(wavefunction) population analysis, which can provide relevant information to clarify the structure-excitation relationships after introducing the single atom sites was also reviewed. In the future, with the further development of artificial intelligence, the establishment of an energy function with a regression accuracy close to or reaching the level of density functional theory is highly desired to infer the energetic diagram of the photocatalytic systems at the excited states. Furthermore, coordination structures, interaction with inorganic semiconductors, photocatalytic stability and solvent effects should also be carefully considered in the future studies of polymer-based photocatalyst.

关键词: Carrier dynamics, Surface reaction, Polymer, Single-atom catalyst, Dielectric property

Abstract: Carrier dynamics and surface reaction are two critical processes for determining the performance of photocatalytic reaction. Highly designable polymer-based photocatalysts have shown promising protectives in energetic and environmental applications. In this prospective, we first distinguished the differences of physiochemical properties between polymer-based semiconductors and traditional inorganic semiconductors. Then, the effects of single-atom sites on the charge dynamics and reaction kinetics of polymer-based photocatalysts are further elaborated. Time(excitation)-space(wavefunction) population analysis, which can provide relevant information to clarify the structure-excitation relationships after introducing the single atom sites was also reviewed. In the future, with the further development of artificial intelligence, the establishment of an energy function with a regression accuracy close to or reaching the level of density functional theory is highly desired to infer the energetic diagram of the photocatalytic systems at the excited states. Furthermore, coordination structures, interaction with inorganic semiconductors, photocatalytic stability and solvent effects should also be carefully considered in the future studies of polymer-based photocatalyst.

Key words: Carrier dynamics, Surface reaction, Polymer, Single-atom catalyst, Dielectric property

TENG Zhenyuan, YANG Hongbin, ZHANG Qitao, OHNO Teruhisa. Carrier Dynamics and Surface Reaction Boosted by Polymer-based Single-atom Photocatalysts[J]. 高等学校化学研究, 2022, 38(5): 1207-1218.

TENG Zhenyuan, YANG Hongbin, ZHANG Qitao, OHNO Teruhisa. Carrier Dynamics and Surface Reaction Boosted by Polymer-based Single-atom Photocatalysts[J]. Chemical Research in Chinese Universities, 2022, 38(5): 1207-1218.

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Carrier Dynamics and Surface Reaction Boosted by Polymer-based Single-atom Photocatalysts

Carrier Dynamics and Surface Reaction Boosted by Polymer-based Single-atom Photocatalysts

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