A Three-dimensional Covalent Organic Framework for CO2 Uptake and Dyes Adsorption

doi:10.1007/s40242-022-2060-7

高等学校化学研究 ›› 2022, Vol. 38 ›› Issue (3): 834-837.doi: 10.1007/s40242-022-2060-7

A Three-dimensional Covalent Organic Framework for CO₂ Uptake and Dyes Adsorption

SONG Jialong¹, WANG Zitao¹, LIU Yaozu¹, TUO Chao², WANG Yujie¹, FANG Qianrong¹, and QIU Shilun¹

1. State Key Laboratory of Inorganic Synthesis &
Preparative Chemistry, Jilin University, Changchun 130012, P. R. China;
2. School of Chemical Engineering and New Energy Materials, Zhuhai College of Science and Technology, Zhuhai 519041, P. R. China

收稿日期:2022-02-24 修回日期:2022-04-08 出版日期:2022-06-01 发布日期:2022-05-26
通讯作者: FANG qianrong, WANG Yujie E-mail:qrfang@jlu.edu.cn;wyujie@jlu.edu.cn
基金资助:
This work was supported by the National Natural Science Foundation of China (Nos.22025504, 21621001, 21390394), the ″111″ Project of China (Nos.BP0719036, B17020), the China Postdoctoral Science Foundation (Nos.2020TQ0118, 2020M681034), and the Program for JLU Science and Technology Innovative Research Team, China.

A Three-dimensional Covalent Organic Framework for CO₂ Uptake and Dyes Adsorption

SONG Jialong¹, WANG Zitao¹, LIU Yaozu¹, TUO Chao², WANG Yujie¹, FANG Qianrong¹, and QIU Shilun¹

1. State Key Laboratory of Inorganic Synthesis &
Preparative Chemistry, Jilin University, Changchun 130012, P. R. China;
2. School of Chemical Engineering and New Energy Materials, Zhuhai College of Science and Technology, Zhuhai 519041, P. R. China

Received:2022-02-24 Revised:2022-04-08 Online:2022-06-01 Published:2022-05-26
Contact: FANG qianrong, WANG Yujie E-mail:qrfang@jlu.edu.cn;wyujie@jlu.edu.cn
Supported by:
This work was supported by the National Natural Science Foundation of China (Nos.22025504, 21621001, 21390394), the ″111″ Project of China (Nos.BP0719036, B17020), the China Postdoctoral Science Foundation (Nos.2020TQ0118, 2020M681034), and the Program for JLU Science and Technology Innovative Research Team, China.

摘要/Abstract

摘要： Environmental pollution is one of the most severe problems facing today, including water pollution and the greenhouse effect. Therefore, developing materials with high-efficiency dyes adsorption and CO₂ uptake is significant. Covalent organic frameworks(COFs), as a burgeoning class of crystalline porous polymers, present a promising application potential in areas related to pollution regulation due to their exciting surface properties. Herein, we report a 3D COF with a high specific surface area(BET about 2072 m²/g) by utilizing tetrahedral and rectangle building blocks connected through[4+4] imine condensation reactions to synthesize. The obtained COF not only can separate dyes from water effectively but also shows a remarkable CO₂ uptake capacity. This research thus provides a promising material to remove dyes and adsorb CO₂ in environmental remediation.

关键词: Covalent organic framework, Dye adsorption, CO₂ uptake

Abstract: Environmental pollution is one of the most severe problems facing today, including water pollution and the greenhouse effect. Therefore, developing materials with high-efficiency dyes adsorption and CO₂ uptake is significant. Covalent organic frameworks(COFs), as a burgeoning class of crystalline porous polymers, present a promising application potential in areas related to pollution regulation due to their exciting surface properties. Herein, we report a 3D COF with a high specific surface area(BET about 2072 m²/g) by utilizing tetrahedral and rectangle building blocks connected through[4+4] imine condensation reactions to synthesize. The obtained COF not only can separate dyes from water effectively but also shows a remarkable CO₂ uptake capacity. This research thus provides a promising material to remove dyes and adsorb CO₂ in environmental remediation.

Key words: Covalent organic framework, Dye adsorption, CO₂ uptake

SONG Jialong, WANG Zitao, LIU Yaozu, TUO Chao, WANG Yujie, FANG Qianrong, and QIU Shilun. A Three-dimensional Covalent Organic Framework for CO₂ Uptake and Dyes Adsorption[J]. 高等学校化学研究, 2022, 38(3): 834-837.

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A Three-dimensional Covalent Organic Framework for CO₂ Uptake and Dyes Adsorption

A Three-dimensional Covalent Organic Framework for CO₂ Uptake and Dyes Adsorption

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