Energy Storage in Covalent Organic Frameworks: From Design Principles to Device Integration

doi:10.1007/s40242-022-1494-2

摘要/Abstract

摘要： Covalent organic frameworks(COFs) have received profound attention in recent years owing to their tailor-made porosity, large surface area and robust stability. More specifically, 2D COFs with redox-active and π electron-rich units allow efficient charge carriers hopping and ion migration, thus offering great potentials in energy storage. Herein, we present a systematic and concise overview of the recent advances in 2D COFs related to the electrochemical energy field, including supercapacitors, fuel cells, rechargeable lithium batteries, lithium-sulfur batteries, and other metal-ion batteries. In addition, a brief outlook is proposed on the challenges and prospects of COFs as electrode materials for energy storage.

关键词: Covalent organic framework, Battery, Capacitor, Electrochemical energy storage, Electrode

Abstract: Covalent organic frameworks(COFs) have received profound attention in recent years owing to their tailor-made porosity, large surface area and robust stability. More specifically, 2D COFs with redox-active and π electron-rich units allow efficient charge carriers hopping and ion migration, thus offering great potentials in energy storage. Herein, we present a systematic and concise overview of the recent advances in 2D COFs related to the electrochemical energy field, including supercapacitors, fuel cells, rechargeable lithium batteries, lithium-sulfur batteries, and other metal-ion batteries. In addition, a brief outlook is proposed on the challenges and prospects of COFs as electrode materials for energy storage.

Key words: Covalent organic framework, Battery, Capacitor, Electrochemical energy storage, Electrode

DING Huimin, MAL Arindam, WANG Cheng. Energy Storage in Covalent Organic Frameworks: From Design Principles to Device Integration[J]. 高等学校化学研究, 2022, 38(2): 356-363.

DING Huimin, MAL Arindam, WANG Cheng. Energy Storage in Covalent Organic Frameworks: From Design Principles to Device Integration[J]. Chemical Research in Chinese Universities, 2022, 38(2): 356-363.

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