Two-dimensional Covalent Organic Frameworks: Intrinsic Synergy Promoting Photocatalytic Hydrogen Evolution

doi:10.1007/s40242-022-2007-z

高等学校化学研究 ›› 2022, Vol. 38 ›› Issue (2): 373-381.doi: 10.1007/s40242-022-2007-z

Two-dimensional Covalent Organic Frameworks: Intrinsic Synergy Promoting Photocatalytic Hydrogen Evolution

LIU Shujing¹, GUO Jia^1,2

1. State Key Laboratory of Molecular Engineering of Polymers, Department of Macromolecular Science, Laboratory of Advanced Materials, Fudan University, Shanghai 200438, P. R. China;
2. Jiangsu Key Laboratory of Advanced Functional Polymers Design and Application, Soochow University, Suzhou 215123, P. R. China

收稿日期:2022-01-03 修回日期:2022-02-08 出版日期:2022-04-01 发布日期:2022-02-17
通讯作者: GUO Jia E-mail:guojia@fudan.edu.cn
基金资助:
This work was supported by the National Natural Science Foundation of China(No. 51973039).

Two-dimensional Covalent Organic Frameworks: Intrinsic Synergy Promoting Photocatalytic Hydrogen Evolution

LIU Shujing¹, GUO Jia^1,2

1. State Key Laboratory of Molecular Engineering of Polymers, Department of Macromolecular Science, Laboratory of Advanced Materials, Fudan University, Shanghai 200438, P. R. China;
2. Jiangsu Key Laboratory of Advanced Functional Polymers Design and Application, Soochow University, Suzhou 215123, P. R. China

Received:2022-01-03 Revised:2022-02-08 Online:2022-04-01 Published:2022-02-17
Contact: GUO Jia E-mail:guojia@fudan.edu.cn
Supported by:
This work was supported by the National Natural Science Foundation of China(No. 51973039).

摘要/Abstract

摘要： Covalent organic frameworks(COFs) are emerging photocatalysts for hydrogen evolution in water splitting in recent years. They offer a pre-designable platform to design tailor-made structures and chemically adjustable functionality in terms of photocatalysis. In this review, we summarize the recent striking progress of COF-based photocatalysts in design and synthesis. Firstly, different approaches to functionalizing building blocks, diversifying linkages, extending π-conjugation and establishing D-A conjugation are illustrated for enhancing photocatalytic activity. Next, post-modification of backbones and pores is detailed for emphasizing the synergistic catalytic uniqueness of COFs. Besides, the strategy of preparing COF-related composites with various semiconductors is outlined for optimizing the electronic properties. Finally, we conclude with the current challenges and promising opportunities for the exploration of new COF-based photocatalysts.

关键词: Covalent organic framework, Photocatalysis, Hydrogen evolution, Charge separation

Abstract: Covalent organic frameworks(COFs) are emerging photocatalysts for hydrogen evolution in water splitting in recent years. They offer a pre-designable platform to design tailor-made structures and chemically adjustable functionality in terms of photocatalysis. In this review, we summarize the recent striking progress of COF-based photocatalysts in design and synthesis. Firstly, different approaches to functionalizing building blocks, diversifying linkages, extending π-conjugation and establishing D-A conjugation are illustrated for enhancing photocatalytic activity. Next, post-modification of backbones and pores is detailed for emphasizing the synergistic catalytic uniqueness of COFs. Besides, the strategy of preparing COF-related composites with various semiconductors is outlined for optimizing the electronic properties. Finally, we conclude with the current challenges and promising opportunities for the exploration of new COF-based photocatalysts.

Key words: Covalent organic framework, Photocatalysis, Hydrogen evolution, Charge separation

LIU Shujing, GUO Jia. Two-dimensional Covalent Organic Frameworks: Intrinsic Synergy Promoting Photocatalytic Hydrogen Evolution[J]. 高等学校化学研究, 2022, 38(2): 373-381.

LIU Shujing, GUO Jia. Two-dimensional Covalent Organic Frameworks: Intrinsic Synergy Promoting Photocatalytic Hydrogen Evolution[J]. Chemical Research in Chinese Universities, 2022, 38(2): 373-381.

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Two-dimensional Covalent Organic Frameworks: Intrinsic Synergy Promoting Photocatalytic Hydrogen Evolution

Two-dimensional Covalent Organic Frameworks: Intrinsic Synergy Promoting Photocatalytic Hydrogen Evolution

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