Photocatalytic Stille Cross-coupling on Gold/g-C3N4 Nano-heterojunction

doi:10.1007/s40242-020-0229-5

高等学校化学研究 ›› 2020, Vol. 36 ›› Issue (6): 1013-1016.doi: 10.1007/s40242-020-0229-5

Photocatalytic Stille Cross-coupling on Gold/g-C₃N₄Nano-heterojunction

YU Qiuying, LIN Xiu, LI Xinhao, CHEN Jiesheng

School of Chemistry and Chemical Engineering, Shanghai Jiao Tong University, Shanghai 200240, P. R. China

收稿日期:2020-07-08 修回日期:2020-08-13 出版日期:2020-12-01 发布日期:2020-12-03
通讯作者: LI Xinhao E-mail:xinhaoli@sjtu.edu.cn
基金资助:
Supported by the National Natural Science Foundation of China(Nos.21722103, 21931005, 21720102002, and 21673140), the Project of the Shanghai Science and Technology Committee, China(No.19JC1412600) and the Fund of the SJTU-MPI Partner Group.

Photocatalytic Stille Cross-coupling on Gold/g-C₃N₄Nano-heterojunction

YU Qiuying, LIN Xiu, LI Xinhao, CHEN Jiesheng

School of Chemistry and Chemical Engineering, Shanghai Jiao Tong University, Shanghai 200240, P. R. China

Received:2020-07-08 Revised:2020-08-13 Online:2020-12-01 Published:2020-12-03
Contact: LI Xinhao E-mail:xinhaoli@sjtu.edu.cn
Supported by:
Supported by the National Natural Science Foundation of China(Nos.21722103, 21931005, 21720102002, and 21673140), the Project of the Shanghai Science and Technology Committee, China(No.19JC1412600) and the Fund of the SJTU-MPI Partner Group.

摘要/Abstract

摘要： Heterogeneous catalysts have been developed for C-C coupling reactions, but stand low activity and always proceed under harsh conditions. Photocatalytic Stille cross-coupling reaction as a green catalytic method for C-C bond formation is of great interest for a wide range of scientists but still lacks stable and highly efficient catalysts. Herein, we have designed an Au nanoparticle-graphitic carbon nitride heterojunction as an outstanding photocatalyst for artificial photosynthesis in Stille cross-coupling reaction. The interface effect between metal and semiconductor makes electron rectify and prevents the recombination of electron-hole pairs. Moreover, the efficiency of Au nanoparticle catalysts could be adjusted by gold contents. Thus the turnover frequency(TOF) value reached the highest level of 788 h^-1 over the optimal heterojunction catalyst. Most importantly, the C-C bond formation reaction has been proved to be carried out well under visible light irradiation, indicating the low-cost organic synthesis process. Further analysis confirmed the stability and general application of our heterogeneous Au nano-heterojunction catalyst.

关键词: Photocatalysis, Stille coupling reaction, Green chemistry, Interface effect

Abstract: Heterogeneous catalysts have been developed for C-C coupling reactions, but stand low activity and always proceed under harsh conditions. Photocatalytic Stille cross-coupling reaction as a green catalytic method for C-C bond formation is of great interest for a wide range of scientists but still lacks stable and highly efficient catalysts. Herein, we have designed an Au nanoparticle-graphitic carbon nitride heterojunction as an outstanding photocatalyst for artificial photosynthesis in Stille cross-coupling reaction. The interface effect between metal and semiconductor makes electron rectify and prevents the recombination of electron-hole pairs. Moreover, the efficiency of Au nanoparticle catalysts could be adjusted by gold contents. Thus the turnover frequency(TOF) value reached the highest level of 788 h^-1 over the optimal heterojunction catalyst. Most importantly, the C-C bond formation reaction has been proved to be carried out well under visible light irradiation, indicating the low-cost organic synthesis process. Further analysis confirmed the stability and general application of our heterogeneous Au nano-heterojunction catalyst.

Key words: Photocatalysis, Stille coupling reaction, Green chemistry, Interface effect

YU Qiuying, LIN Xiu, LI Xinhao, CHEN Jiesheng. Photocatalytic Stille Cross-coupling on Gold/g-C₃N₄Nano-heterojunction[J]. 高等学校化学研究, 2020, 36(6): 1013-1016.

YU Qiuying, LIN Xiu, LI Xinhao, CHEN Jiesheng. Photocatalytic Stille Cross-coupling on Gold/g-C₃N₄Nano-heterojunction[J]. Chemical Research in Chinese Universities, 2020, 36(6): 1013-1016.

参考文献

[1] Xue Z. H., Zhang S. N., Lin Y. X., Su H., Zhai G. Y., Han J. T., Yu Q. Y., Li X. H., Antonietti M., Chen J. S., J. Am. Chem. Soc., 2019, 141, 14976
[2] Shuang S., Lv R., Xie Z., Zhang Z., Sci. Rep., 2016, 6, 26670
[3] Li C. J., Tseng C. M., Lai S. N., Yang C. R., Huang W. H., Nanoscale Res. Lett., 2017, 12, 560
[4] Allen J. E., Hemesath E. R., Perea D. E., Lensch-Falk J. L., Li Z. Y., Yin F., Gass M. H., Wang P., Bleloch A. L., Palmer R. E., Lauhon L. J., Nat. Nanotech., 2008, 3, 168
[5] Shi R., Cao Y., Bao Y., Zhao Y., Waterhouse G. I. N., Fang Z., Wu L. Z., Tung C. H. Yin Y., Zhang T., Adv. Mater., 2017, 29, 1700803
[6] Yu Y., Wen W., Qian X. Y., Liu J. B., Wu J. M., Sci. Rep., 2017, 7, 41253
[7] Li X. H., Antonietti M., Chem. Soc. Rev., 2013, 42, 6593
[8] Zhou C., Shi R., Shang L., Wu L. Z., Tung C. H., Zhang T., Nano Res., 2018, 11, 3462
[9] Jiang S., Xiong C., Song S., Cheng B., ACS Sustainable Chem. Eng., 2019, 7, 2018
[10] Cheng N., Tian J., Liu Q., Ge C., Qusti A. H., Asiri A. M., Al-Youbi A. O., Sun X., ACS Appl. Mater. Interfaces, 2013, 5, 6815
[11] Zada A., Humayun M., Raziq F., Zhang X., Qu Y., Bai L., Qin C., Jing L., Fu H., Adv. Energy Mater., 2016, 6, 1601190
[12] Samanta S., Martha S., Parida K., ChemCatChem, 2014, 6, 1453
[13] Raziq F., Sun L., Wang Y., Zhang X., Humayun M., Ali S., Bai L., Qu Y., Yu H., Jing L., Adv. Energy Mater., 2018, 8, 1701580
[14] Kim Y. M., Yu S., J. Am. Chem. Soc., 2003, 125, 1696
[15] Jin M. J., Lee D. H., Angew. Chem. Int. Ed., 2010, 49, 1119
[16] Cordovilla C., Bartolomé C., Martínez-Ilarduya J. M., Espinet P., ACS Catal., 2015, 5, 3040
[17] Ghorbani-Choghamarani A., Norouzi M., New J. Chem., 2016, 40, 6299
[18] Stratakis M., Garcia H., Chem. Rev., 2012, 112, 4469
[19] Li H., Gao Y., Xiong Z., Liao C., Shih K., Appl. Surf. Sci., 2018, 439, 552
[20] Sengupta D., Saha J., De G., Basu B., J. Mater. Chem. A, 2014, 2, 3986
[21] Zhang X., Xie X., Wang H., Zhang J., Pan B., Xie Y., J. Am. Chem. Soc., 2013, 135, 18
[22] Mohini R., Lakshminarasimhan N., Mater. Res. Bull., 2016, 76, 307
[23] Li X. H., Baar M., Blechert S., Antonietti M., Sci. Rep., 2013, 3, 1743

Photocatalytic Stille Cross-coupling on Gold/g-C₃N₄Nano-heterojunction

Photocatalytic Stille Cross-coupling on Gold/g-C₃N₄Nano-heterojunction

可视化

摘要/Abstract

引用本文

使用本文

参考文献

相关文章 15

编辑推荐

Metrics

本文评价

[1]	SONG Weiyu, LV Xintong, GAO Yang, WANG Lu. Photocatalytic HER Performance of TiO₂-supported Single Atom Catalyst Based on Electronic Regulation:A DFT Study[J]. 高等学校化学研究, 2022, 38(4): 1025-1031.
[2]	DU Shihao, BIAN Xuanang, ZHAO Yunxuan, SHI Run, and ZHANG Tierui. Progress and Prospect of Photothermal Catalysis[J]. 高等学校化学研究, 2022, 38(3): 723-734.
[3]	LIU Shujing, GUO Jia. Two-dimensional Covalent Organic Frameworks: Intrinsic Synergy Promoting Photocatalytic Hydrogen Evolution[J]. 高等学校化学研究, 2022, 38(2): 373-381.
[4]	HU Guilin, HE Jingyi, LI Yongjun. Application of Graphdiyne and Its Analogues in Photocatalysis and Photoelectrochemistry[J]. 高等学校化学研究, 2021, 37(6): 1195-1212.
[5]	MA Yuying, HE Dayong, LIU Jiadi, WANG Yuannan, YANG Mei, WANG Hao, QIU Ju, LI Wenyan, LI Yongxin, WANG Ce. Adsorption and Visible Light Photocatalytic Degradation of Electrospun PAN@W₁₈O₄₉ Nanofibers[J]. 高等学校化学研究, 2021, 37(3): 428-435.
[6]	JIAN Shaoju, TIAN Zhiwei, ZHANG Kaiyin, DUAN Gaigai, YANG Weisen, JIANG Shaohua. Hydrothermal Synthesis of Ce-doped ZnO Heterojunction Supported on Carbon Nanofibers with High Visible Light Photocatalytic Activity[J]. 高等学校化学研究, 2021, 37(3): 565-570.
[7]	ZHAO Weifeng, HAO Ning, ZHANG Gai, MA Aijie, CHEN Weixing, ZHOU Hongwei, YANG Dong, XU Ben Bin, KONG Jie. In situ Carbon Modification of g-C₃N₄ from Urea co-Crystal with Enhanced Photocatalytic Activity Towards Degradation of Organic Dyes Under Visible Light[J]. 高等学校化学研究, 2020, 36(6): 1265-1271.
[8]	GU Xianmo, MA Pengwei, LIU Pei, WANG Ruiyi, LI Xincheng, ZHENG Zhanfeng. Visible-light-driven Hydroamination of Alkynes over a New Type of Activated Carbon Immobilized Cu²⁺ Photocatalyst[J]. 高等学校化学研究, 2020, 36(6): 1039-1044.
[9]	CHEN Ting, ZHONG Lei, YANG Zhen, MOU Zhigang, LIU Lei, WANG Yan, SUN Jianhua, LEI Weiwei. Enhanced Visible-light Photocatalytic Activity of g-C₃N₄/Nitrogen-doped Graphene Quantum Dots/TiO₂ Ternary Heterojunctions for Ciprofloxacin Degradation with Narrow Band Gap and High Charge Carrier Mobility[J]. 高等学校化学研究, 2020, 36(6): 1083-1090.
[10]	JIANG Wenshuai, ZONG Xupeng, WANG Xiayan, SUN Zaicheng. Transparent Coating with TiO₂ Nanorods for High-performance Photocatalytic Self-cleaning and Environmental Remediation[J]. 高等学校化学研究, 2020, 36(6): 1097-1101.
[11]	CEN Qing, XIAO Wei, LIU Yingqi, WANG Qi, NAFADY Ayman, MA Shengqian. Fabrication of Fe-POMs as Visible-light-active Heterogeneous Photocatalyst[J]. 高等学校化学研究, 2020, 36(6): 1128-1135.
[12]	WANG Changhua, ZHANG Xintong. Anatase/Bronze TiO₂ Heterojunction: Enhanced Photocatalysis and Prospect in Photothermal Catalysis[J]. 高等学校化学研究, 2020, 36(6): 992-999.
[13]	LI Xiaodong, SU Qing, LIU Ziqian, LUO Kexin, LI Guanghua, WU Qiaolin. A Triformylphloroglucinol-based Covalent Organic Polymer: Synthesis, Characterization and Its Application in Visible-light-driven Oxidative Coupling Reactions of Primary Amines[J]. 高等学校化学研究, 2020, 36(6): 1017-1023.
[14]	QI Yinhong, XU Jixiang, WANG Chao, ZHAN Tianrong, WANG Lei. Synthesis of Holey Graphitic Carbon Nitride with Highly Enhanced Photocatalytic Reduction Activity via Melamine-cyanuric Acid Precursor Route[J]. 高等学校化学研究, 2020, 36(6): 1024-1031.
[15]	YUAN Huiting, REN Huizhen, LI Minning, LI Zetong, LIU Mingrui, DONG Wenjun, WANG Ge, ZHUANG Tao. Synthesis of N-TiO₂@NH₂-MIL-88(Fe) Core-shell Structure for Efficient Fenton Effect Assisted Methylene Blue Degradation Under Visible Light[J]. 高等学校化学研究, 2020, 36(6): 1068-1075.