Effect of Support on Catalytic Performance of Photothermal Fischer-Tropsch Synthesis to Produce Lower Olefins over Fe5C2-based Catalysts

doi:10.1007/s40242-020-0253-5

高等学校化学研究 ›› 2020, Vol. 36 ›› Issue (6): 1006-1012.doi: 10.1007/s40242-020-0253-5

Effect of Support on Catalytic Performance of Photothermal Fischer-Tropsch Synthesis to Produce Lower Olefins over Fe₅C₂-based Catalysts

LI Yuan, LI Ruizhe, LI Zhenhua, WEI Weiqin, OUYANG Shuxin, YUAN Hong, ZHANG Tierui

College of Chemistry, Central China Normal University, Wuhan 430079, P. R. China

收稿日期:2020-08-05 修回日期:2020-09-09 出版日期:2020-12-01 发布日期:2020-12-03
通讯作者: OUYANG Shuxin E-mail:oysx@mail.ccnu.edu.cn
基金资助:
Supported by the National Natural Science Foundation of China(No.21972052) and the Financial Support from the "Guizi Scholar" Program of Central China Normal University, China.

Effect of Support on Catalytic Performance of Photothermal Fischer-Tropsch Synthesis to Produce Lower Olefins over Fe₅C₂-based Catalysts

LI Yuan, LI Ruizhe, LI Zhenhua, WEI Weiqin, OUYANG Shuxin, YUAN Hong, ZHANG Tierui

College of Chemistry, Central China Normal University, Wuhan 430079, P. R. China

Received:2020-08-05 Revised:2020-09-09 Online:2020-12-01 Published:2020-12-03
Contact: OUYANG Shuxin E-mail:oysx@mail.ccnu.edu.cn
Supported by:
Supported by the National Natural Science Foundation of China(No.21972052) and the Financial Support from the "Guizi Scholar" Program of Central China Normal University, China.

摘要/Abstract

摘要： Photothermal Fischer-Tropsch synthesis(FTS) has been extensively studied, but few reports were focused on systematically exploring the influence of support on catalytic performance. Herein, a series of Fe₅C₂-based catalysts with different supports was fabricated via a one-step wet-chemical method for photothermal conversion of syngas to lower olefins. Under light irradiation, the optimized Fe₅C₂/α-Al₂O₃ catalyst demonstrated remarkable photothermal FTS activity, delivering selectivity to lower olefins of 50.3% with a CO conversion rate of 52.5%. Characterization studies using X-ray diffraction and Mössbauer spectroscopy analysis revealed that the active catalyst mainly contained Fe₅C₂ nanoparticles on α-Al₂O₃ support. It was found that the weak interaction between active phase and α-Al₂O₃ could promote the formation of Fe₅C₂, which contributed to the high selectivity to lower olefins.

关键词: χ-Fe₅C₂ catalyst, Fischer-Tropsch synthesis, Metal-support interaction, Photothermal catalysis

Abstract: Photothermal Fischer-Tropsch synthesis(FTS) has been extensively studied, but few reports were focused on systematically exploring the influence of support on catalytic performance. Herein, a series of Fe₅C₂-based catalysts with different supports was fabricated via a one-step wet-chemical method for photothermal conversion of syngas to lower olefins. Under light irradiation, the optimized Fe₅C₂/α-Al₂O₃ catalyst demonstrated remarkable photothermal FTS activity, delivering selectivity to lower olefins of 50.3% with a CO conversion rate of 52.5%. Characterization studies using X-ray diffraction and Mössbauer spectroscopy analysis revealed that the active catalyst mainly contained Fe₅C₂ nanoparticles on α-Al₂O₃ support. It was found that the weak interaction between active phase and α-Al₂O₃ could promote the formation of Fe₅C₂, which contributed to the high selectivity to lower olefins.

Key words: χ-Fe₅C₂ catalyst, Fischer-Tropsch synthesis, Metal-support interaction, Photothermal catalysis

LI Yuan, LI Ruizhe, LI Zhenhua, WEI Weiqin, OUYANG Shuxin, YUAN Hong, ZHANG Tierui. Effect of Support on Catalytic Performance of Photothermal Fischer-Tropsch Synthesis to Produce Lower Olefins over Fe₅C₂-based Catalysts[J]. 高等学校化学研究, 2020, 36(6): 1006-1012.

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Effect of Support on Catalytic Performance of Photothermal Fischer-Tropsch Synthesis to Produce Lower Olefins over Fe₅C₂-based Catalysts

Effect of Support on Catalytic Performance of Photothermal Fischer-Tropsch Synthesis to Produce Lower Olefins over Fe₅C₂-based Catalysts

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