Visible-light-driven Hydroamination of Alkynes over a New Type of Activated Carbon Immobilized Cu2+ Photocatalyst

doi:10.1007/s40242-020-0166-3

高等学校化学研究 ›› 2020, Vol. 36 ›› Issue (6): 1039-1044.doi: 10.1007/s40242-020-0166-3

Visible-light-driven Hydroamination of Alkynes over a New Type of Activated Carbon Immobilized Cu²⁺ Photocatalyst

GU Xianmo¹, MA Pengwei¹, LIU Pei¹, WANG Ruiyi¹, LI Xincheng^1,2, ZHENG Zhanfeng^1,2

1. State Key Laboratory of Coal Conversion, Institute of Coal Chemistry, Chinese Academy of Sciences, Taiyuan 030001, P. R. China;
2. Center of Materials Science and Optoelectronics Engineering, University of Chinese Academy of Sciences, Beijing 100049, P. R. China

收稿日期:2020-06-02 修回日期:2020-07-22 出版日期:2020-12-01 发布日期:2020-07-29
通讯作者: ZHENG Zhanfeng E-mail:zfzheng@sxicc.ac.cn
基金资助:
Supported by the National Natural Science Foundation of China(Nos.21773284, 21703276) and the Hundred Talents Program of the Chinese Academy of Sciences and Shanxi Province, China.

Visible-light-driven Hydroamination of Alkynes over a New Type of Activated Carbon Immobilized Cu²⁺ Photocatalyst

GU Xianmo¹, MA Pengwei¹, LIU Pei¹, WANG Ruiyi¹, LI Xincheng^1,2, ZHENG Zhanfeng^1,2

1. State Key Laboratory of Coal Conversion, Institute of Coal Chemistry, Chinese Academy of Sciences, Taiyuan 030001, P. R. China;
2. Center of Materials Science and Optoelectronics Engineering, University of Chinese Academy of Sciences, Beijing 100049, P. R. China

Received:2020-06-02 Revised:2020-07-22 Online:2020-12-01 Published:2020-07-29
Contact: ZHENG Zhanfeng E-mail:zfzheng@sxicc.ac.cn
Supported by:
Supported by the National Natural Science Foundation of China(Nos.21773284, 21703276) and the Hundred Talents Program of the Chinese Academy of Sciences and Shanxi Province, China.

摘要/Abstract

摘要： A new type of activated carbon immobilized copper(Cu/AC) photocatalyst was prepared by a facile impregnation-adsorption method, where Cu²⁺ is chemically adsorbed by abundant oxygenated functional groups on large-surface-area activated carbon surface. Cu/AC exhibited good activity and selectivity to imine for the hydro-amination of alkynes at 60℃ under visible light irradiation. The reaction is initialized by the activation of alkynes molecules at Cu active sites with the aid of light as evidenced by the solid-state NMR and laser photolysis measurements and the control experiments. This strategy for catalyst design is potentially extended to the immobilization of other metal homogeneous catalysts for various heterogeneous catalytic systems.

关键词: Activated carbon, Copper, Hydroamination, Photocatalysis

Abstract: A new type of activated carbon immobilized copper(Cu/AC) photocatalyst was prepared by a facile impregnation-adsorption method, where Cu²⁺ is chemically adsorbed by abundant oxygenated functional groups on large-surface-area activated carbon surface. Cu/AC exhibited good activity and selectivity to imine for the hydro-amination of alkynes at 60℃ under visible light irradiation. The reaction is initialized by the activation of alkynes molecules at Cu active sites with the aid of light as evidenced by the solid-state NMR and laser photolysis measurements and the control experiments. This strategy for catalyst design is potentially extended to the immobilization of other metal homogeneous catalysts for various heterogeneous catalytic systems.

Key words: Activated carbon, Copper, Hydroamination, Photocatalysis

GU Xianmo, MA Pengwei, LIU Pei, WANG Ruiyi, LI Xincheng, ZHENG Zhanfeng. Visible-light-driven Hydroamination of Alkynes over a New Type of Activated Carbon Immobilized Cu²⁺ Photocatalyst[J]. 高等学校化学研究, 2020, 36(6): 1039-1044.

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Visible-light-driven Hydroamination of Alkynes over a New Type of Activated Carbon Immobilized Cu²⁺ Photocatalyst

Visible-light-driven Hydroamination of Alkynes over a New Type of Activated Carbon Immobilized Cu²⁺ Photocatalyst

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