Recent Progress on 2D Transition Metal Compounds-based Electrocatalysts for Efficient Nitrogen Reduction

doi:10.1007/s40242-020-0171-6

高等学校化学研究 ›› 2020, Vol. 36 ›› Issue (4): 648-661.doi: 10.1007/s40242-020-0171-6

Recent Progress on 2D Transition Metal Compounds-based Electrocatalysts for Efficient Nitrogen Reduction

DONG Wenfei¹, CHEN Xiaoyu¹, PENG Juan¹, LIU Wanyi¹, JIN Xiaoyong¹, NI Gang¹, LIU Zheng^2,3,4

1. State Key Laboratory of High-efficiency Utilization of Coal and Green Chemical Engineering, National Demonstration Center for Experimental Chemistry Education, College of Chemistry and Chemical Engineering, Ningxia University, Yinchuan 750021, P. R. China;
2. School of Materials Science and Engineering, Nanyang Technological University, Singapore 639798, Singapore;
3. CINTRA CNRS/NTU/THALES, Research Techno Plaza, Singapore 639798, Singapore;
4. Environmental Chemistry and Materials Centre, Nanyang Environment and Water Research Institute, Singapore 639798, Singapore

收稿日期:2020-06-06 修回日期:2020-07-07 出版日期:2020-08-01 发布日期:2020-07-30
通讯作者: PENG Juan, LIU Zheng E-mail:z.liu@ntu.edu.sg;pengjuan@nxu.edu.cn
基金资助:
Supported by the Natural Science Foundation of Ningxia, China(No.2018AAC03012), the National Natural Science Foundation of China(No.21765016), the Ningxia Leading Scientific and Technological Innovation Talents Project, China (No.KJT2018002) and the National First-rate Discipline Project of Ningxia, China(NXYLXK2017A04).

Recent Progress on 2D Transition Metal Compounds-based Electrocatalysts for Efficient Nitrogen Reduction

DONG Wenfei¹, CHEN Xiaoyu¹, PENG Juan¹, LIU Wanyi¹, JIN Xiaoyong¹, NI Gang¹, LIU Zheng^2,3,4

1. State Key Laboratory of High-efficiency Utilization of Coal and Green Chemical Engineering, National Demonstration Center for Experimental Chemistry Education, College of Chemistry and Chemical Engineering, Ningxia University, Yinchuan 750021, P. R. China;
2. School of Materials Science and Engineering, Nanyang Technological University, Singapore 639798, Singapore;
3. CINTRA CNRS/NTU/THALES, Research Techno Plaza, Singapore 639798, Singapore;
4. Environmental Chemistry and Materials Centre, Nanyang Environment and Water Research Institute, Singapore 639798, Singapore

Received:2020-06-06 Revised:2020-07-07 Online:2020-08-01 Published:2020-07-30
Contact: PENG Juan, LIU Zheng E-mail:z.liu@ntu.edu.sg;pengjuan@nxu.edu.cn
Supported by:
Supported by the Natural Science Foundation of Ningxia, China(No.2018AAC03012), the National Natural Science Foundation of China(No.21765016), the Ningxia Leading Scientific and Technological Innovation Talents Project, China (No.KJT2018002) and the National First-rate Discipline Project of Ningxia, China(NXYLXK2017A04).

摘要/Abstract

摘要： Ammonia is a commodity chemical with high added value. Electrochemical reduction of nitrogen has great promise for the sustainable synthesis of ammonia in recent years. Because of its rich resources and unique electronic structure and characteristics, 2D transition metal compounds have been used as electrocatalysts for electrochemical reduction of nitrogen for clean and sustainable production of ammonia. This review outlines the latest development in the use of 2D transition metal compounds as high-efficiency electrocatalysts for nitrogen reduction reaction(NRR). First, we introduce the N₂ reduction mechanism, and briefly summarize the performance indicators of the catalyst. Then, we focused on the functionalization of unique 2D materials to design high-performance 2D electrocatalysts in respect of simulation calculation and experimental development. Finally, the current challenges and future opportunities for NRR electrocatalysts are introduced.

关键词: Electrochemical NH₃ synthesis, Transition metal, Nitrogen fixation, Electrocatalysis

Abstract: Ammonia is a commodity chemical with high added value. Electrochemical reduction of nitrogen has great promise for the sustainable synthesis of ammonia in recent years. Because of its rich resources and unique electronic structure and characteristics, 2D transition metal compounds have been used as electrocatalysts for electrochemical reduction of nitrogen for clean and sustainable production of ammonia. This review outlines the latest development in the use of 2D transition metal compounds as high-efficiency electrocatalysts for nitrogen reduction reaction(NRR). First, we introduce the N₂ reduction mechanism, and briefly summarize the performance indicators of the catalyst. Then, we focused on the functionalization of unique 2D materials to design high-performance 2D electrocatalysts in respect of simulation calculation and experimental development. Finally, the current challenges and future opportunities for NRR electrocatalysts are introduced.

Key words: Electrochemical NH₃ synthesis, Transition metal, Nitrogen fixation, Electrocatalysis

DONG Wenfei, CHEN Xiaoyu, PENG Juan, LIU Wanyi, JIN Xiaoyong, NI Gang, LIU Zheng. Recent Progress on 2D Transition Metal Compounds-based Electrocatalysts for Efficient Nitrogen Reduction[J]. 高等学校化学研究, 2020, 36(4): 648-661.

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Recent Progress on 2D Transition Metal Compounds-based Electrocatalysts for Efficient Nitrogen Reduction

Recent Progress on 2D Transition Metal Compounds-based Electrocatalysts for Efficient Nitrogen Reduction

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