Towards Scalable Fabrications and Applications of 2D Layered Material-based Vertical and Lateral Heterostructures

doi:10.1007/s40242-020-0200-5

高等学校化学研究 ›› 2020, Vol. 36 ›› Issue (4): 525-550.doi: 10.1007/s40242-020-0200-5

Towards Scalable Fabrications and Applications of 2D Layered Material-based Vertical and Lateral Heterostructures

WAN Xi¹, LI Hao², CHEN Kun³, XU Jianbin²

1. Engineering Research Center of IoT Technology Applications(Ministry of Education), Department of Electronic Engineering, Jiangnan University, Wuxi 214122, P. R. China;
2. Department of Electronic Engineering and Materials Science and Technology Research Center, The Chinese University of Hong Kong, Shatin, N. T., Hong Kong SAR 999077, P. R. China;
3. State Key Laboratory of Optoelectronic Materials and Technologies, School of Electronics and Information Technology and Guangdong Province Key Laboratory of Display Material, Sun Yat-sen University, Guangzhou 510275, P. R. China

收稿日期:2020-06-20 修回日期:2020-07-13 出版日期:2020-08-01 发布日期:2020-07-14
通讯作者: WAN Xi, CHEN Kun, XU Jianbin E-mail:xwan@jiangnan.edu.cn;chenk69@mail.sysu.edu.cn;jbxu@ee.cuhk.edu.hk
基金资助:
Supported by the National Natural Science Foundation of China(Nos.61804067, 51802360), the Natural Science Foundation of Jiangsu Province, China(No.BK20170193), the E&I(Entrepreneurship and Innovation) Plan of Jiangsu Province, China (No.1256010241180240), the Fundamental Research Funds for the Central Universities of China(Nos.JUSRP11746, JUSRP51726B), the Six Talent Peaks Project in Jiangsu Province, China(No.DZXX-021), the 111 Project, China(No.B12018), the Natural Science Foundation of Guangdong Province for Distinguished Young Scholars, China(No.2018B030306043), the Science and Technology Program of Guangzhou, China(No.201904010449), the Key Cultivation Program for Young Teachers of Sun Yat-sen University, China(No.20lgzd13), the Project of the Research Grants Council of Hong Kong, China(Nos.AoE/P-02/12, 14203018, N_CUHK438/18) and the Innovation and Technology Fund of China(No.ITS/390/18).

Towards Scalable Fabrications and Applications of 2D Layered Material-based Vertical and Lateral Heterostructures

WAN Xi¹, LI Hao², CHEN Kun³, XU Jianbin²

1. Engineering Research Center of IoT Technology Applications(Ministry of Education), Department of Electronic Engineering, Jiangnan University, Wuxi 214122, P. R. China;
2. Department of Electronic Engineering and Materials Science and Technology Research Center, The Chinese University of Hong Kong, Shatin, N. T., Hong Kong SAR 999077, P. R. China;
3. State Key Laboratory of Optoelectronic Materials and Technologies, School of Electronics and Information Technology and Guangdong Province Key Laboratory of Display Material, Sun Yat-sen University, Guangzhou 510275, P. R. China

Received:2020-06-20 Revised:2020-07-13 Online:2020-08-01 Published:2020-07-14
Contact: WAN Xi, CHEN Kun, XU Jianbin E-mail:xwan@jiangnan.edu.cn;chenk69@mail.sysu.edu.cn;jbxu@ee.cuhk.edu.hk
Supported by:
Supported by the National Natural Science Foundation of China(Nos.61804067, 51802360), the Natural Science Foundation of Jiangsu Province, China(No.BK20170193), the E&I(Entrepreneurship and Innovation) Plan of Jiangsu Province, China (No.1256010241180240), the Fundamental Research Funds for the Central Universities of China(Nos.JUSRP11746, JUSRP51726B), the Six Talent Peaks Project in Jiangsu Province, China(No.DZXX-021), the 111 Project, China(No.B12018), the Natural Science Foundation of Guangdong Province for Distinguished Young Scholars, China(No.2018B030306043), the Science and Technology Program of Guangzhou, China(No.201904010449), the Key Cultivation Program for Young Teachers of Sun Yat-sen University, China(No.20lgzd13), the Project of the Research Grants Council of Hong Kong, China(Nos.AoE/P-02/12, 14203018, N_CUHK438/18) and the Innovation and Technology Fund of China(No.ITS/390/18).

摘要/Abstract

摘要： Among 108423 unique, experimentally known 3D compounds, there exist 1825 ones that are either easily or potentially exfoliable. This increasingly broad library of 2D layered materials(2DLMs) with variable physical properties as well as the unique ability to vertical stacking or lateral stitching 2DLMs into complex heterostructures enables a new dimension for materials engineering and device design, offering novel functional electronics and optoelectronics for flexible industry. In this review, we present a comprehensive summary of the state-of-the-art scalable fabrication technologies, the unique properties as well as the potential device applications of the emerging 2D heterostructures. Firstly, we depict an overall picture of the 2D vertical van der Waals heterostructures. Secondly, we focus on the 2D lateral heterostructures by CVD technique. For a quick access and full coverage, both the vertical and lateral 2D heterostructures are classified into several types according to their chemical compounds with different dimensions. In the end, both the challenges and potential applications of these 2D heterostructures are discussed.

关键词: Two-dimensional (2D), Graphene, Hexagonal boron nitride (hBN), Transition metal dichalcogenide, Fabrication, Vertical, Lateral, Heterostructure

Abstract: Among 108423 unique, experimentally known 3D compounds, there exist 1825 ones that are either easily or potentially exfoliable. This increasingly broad library of 2D layered materials(2DLMs) with variable physical properties as well as the unique ability to vertical stacking or lateral stitching 2DLMs into complex heterostructures enables a new dimension for materials engineering and device design, offering novel functional electronics and optoelectronics for flexible industry. In this review, we present a comprehensive summary of the state-of-the-art scalable fabrication technologies, the unique properties as well as the potential device applications of the emerging 2D heterostructures. Firstly, we depict an overall picture of the 2D vertical van der Waals heterostructures. Secondly, we focus on the 2D lateral heterostructures by CVD technique. For a quick access and full coverage, both the vertical and lateral 2D heterostructures are classified into several types according to their chemical compounds with different dimensions. In the end, both the challenges and potential applications of these 2D heterostructures are discussed.

Key words: Two-dimensional (2D), Graphene, Hexagonal boron nitride (hBN), Transition metal dichalcogenide, Fabrication, Vertical, Lateral, Heterostructure

WAN Xi, LI Hao, CHEN Kun, XU Jianbin. Towards Scalable Fabrications and Applications of 2D Layered Material-based Vertical and Lateral Heterostructures[J]. 高等学校化学研究, 2020, 36(4): 525-550.

WAN Xi, LI Hao, CHEN Kun, XU Jianbin. Towards Scalable Fabrications and Applications of 2D Layered Material-based Vertical and Lateral Heterostructures[J]. Chemical Research in Chinese Universities, 2020, 36(4): 525-550.

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Towards Scalable Fabrications and Applications of 2D Layered Material-based Vertical and Lateral Heterostructures

Towards Scalable Fabrications and Applications of 2D Layered Material-based Vertical and Lateral Heterostructures

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