Covalent Triazine Framework Nanosheets for Efficient Energy Storage and Conversion

doi:10.1007/s40242-020-0179-y

高等学校化学研究 ›› 2020, Vol. 36 ›› Issue (4): 640-647.doi: 10.1007/s40242-020-0179-y

Covalent Triazine Framework Nanosheets for Efficient Energy Storage and Conversion

SUN Tian, WANG Congxu, XU Yuxi

School of Engineering, Westlake University, Hangzhou 310024, P. R. China

收稿日期:2020-06-12 修回日期:2020-07-10 出版日期:2020-08-01 发布日期:2020-07-30
通讯作者: XU Yuxi E-mail:xuyuxi@westlake.edu.cn
基金资助:
Supported by the National Natural Science Foundation of China(Nos.51873039, 51673042) and the Young Elite Scientist Sponsorship Program by China Association for Science and Technology(CAST)(No.2017QNRC001).

Covalent Triazine Framework Nanosheets for Efficient Energy Storage and Conversion

SUN Tian, WANG Congxu, XU Yuxi

School of Engineering, Westlake University, Hangzhou 310024, P. R. China

Received:2020-06-12 Revised:2020-07-10 Online:2020-08-01 Published:2020-07-30
Contact: XU Yuxi E-mail:xuyuxi@westlake.edu.cn
Supported by:
Supported by the National Natural Science Foundation of China(Nos.51873039, 51673042) and the Young Elite Scientist Sponsorship Program by China Association for Science and Technology(CAST)(No.2017QNRC001).

摘要/Abstract

摘要： Two-dimensional crystalline covalent triazine frameworks(CTFs) have received much attention because of their unique triazine structure, which endows CTFs with high thermal and chemical stability, high proportion of nitrogen and permanent porosity. Based on this unique structure characteristic, CTFs have shown great potential in energy storage and conversion due to the intrinsically strong conjugated structure, delocalized electron and rich active sites. However, charge carrier(electron, hole or ion) transport can't reach the deep active sites and charge diffusion was impeded by defects in bulk CTFs. Hence, to break through this barrier, increasing attention has been paid to get few layered CTFs or CTFs nanosheets in order to shorten the pathways of charge diffusion and expose more active sites. This review summarizes the synthetic methodologies of CTFs nanosheets and the potential application in photocatalytic and electrochemical energy storage and conversion.

关键词: Bulk crystalline covalent triazine framework (CTF), CTFs nanosheet, Synthesis, Photocatalysis, Electrochemical energy storage

Abstract: Two-dimensional crystalline covalent triazine frameworks(CTFs) have received much attention because of their unique triazine structure, which endows CTFs with high thermal and chemical stability, high proportion of nitrogen and permanent porosity. Based on this unique structure characteristic, CTFs have shown great potential in energy storage and conversion due to the intrinsically strong conjugated structure, delocalized electron and rich active sites. However, charge carrier(electron, hole or ion) transport can't reach the deep active sites and charge diffusion was impeded by defects in bulk CTFs. Hence, to break through this barrier, increasing attention has been paid to get few layered CTFs or CTFs nanosheets in order to shorten the pathways of charge diffusion and expose more active sites. This review summarizes the synthetic methodologies of CTFs nanosheets and the potential application in photocatalytic and electrochemical energy storage and conversion.

Key words: Bulk crystalline covalent triazine framework (CTF), CTFs nanosheet, Synthesis, Photocatalysis, Electrochemical energy storage

SUN Tian, WANG Congxu, XU Yuxi. Covalent Triazine Framework Nanosheets for Efficient Energy Storage and Conversion[J]. 高等学校化学研究, 2020, 36(4): 640-647.

SUN Tian, WANG Congxu, XU Yuxi. Covalent Triazine Framework Nanosheets for Efficient Energy Storage and Conversion[J]. Chemical Research in Chinese Universities, 2020, 36(4): 640-647.

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Covalent Triazine Framework Nanosheets for Efficient Energy Storage and Conversion

Covalent Triazine Framework Nanosheets for Efficient Energy Storage and Conversion

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