Preparation of a Hybrid Organic-inorganic Monolith for Extraction and Purification of Quercetin and Myricetin from Chamaecyparis obtusa

doi:10.1007/s40242-014-3394-6

高等学校化学研究 ›› 2014, Vol. 30 ›› Issue (2): 216-221.doi: 10.1007/s40242-014-3394-6

Preparation of a Hybrid Organic-inorganic Monolith for Extraction and Purification of Quercetin and Myricetin from Chamaecyparis obtusa

ZHU Tao^1,2, LEE Yuri², ROW Kyungho²

1. School of Chemistry and Chemical Engineering, Tianjin University of Technology, Tianjin 300384, P. R. China;
2. Department of Chemical Engineering, Inha University, Incheon 402-751, Korea

收稿日期:2013-09-17 修回日期:2013-11-06 出版日期:2014-04-01 发布日期:2013-11-25
通讯作者: ROW Kyungho E-mail:rowkho@inha.ac.kr
基金资助:
Supported by the Basic Science Research Program Through the National Research Foundation of Korea(NRF) funded by the Ministry of Education, Science and Technology(No.2011-0010673).

Preparation of a Hybrid Organic-inorganic Monolith for Extraction and Purification of Quercetin and Myricetin from Chamaecyparis obtusa

ZHU Tao^1,2, LEE Yuri², ROW Kyungho²

1. School of Chemistry and Chemical Engineering, Tianjin University of Technology, Tianjin 300384, P. R. China;
2. Department of Chemical Engineering, Inha University, Incheon 402-751, Korea

Received:2013-09-17 Revised:2013-11-06 Online:2014-04-01 Published:2013-11-25
Contact: ROW Kyungho E-mail:rowkho@inha.ac.kr
Supported by:
Supported by the Basic Science Research Program Through the National Research Foundation of Korea(NRF) funded by the Ministry of Education, Science and Technology(No.2011-0010673).

摘要/Abstract

摘要：

A new hybrid organic-inorganic monolithic cartridge was synthesized and used as the selective sorbent for the extraction and purification of quercetin and myricetin from Chamaecyparis obtusa via a solid-phase extraction method. The morphology of the monolithic material was examined by field emission-scanning electron microscopy and a Brunauer-Emmett-Teller(BET) test. The adsorption capacity of the obtained material for quercetin and myricetin was investigated by fitting the adsorption data to four different adsorption equations, of which the Langmuir-Freundlich isotherm was selected as the most suitable model. Under optimized conditions, good calibration curves were observed at nine concentrations ranged from 0.5 μg/mL to 100.0 μg/mL of quercetin and myricetin. The extraction recovery ranged from 74.5% to 84.6% and the inter-and intra-day relative standard deviations were <6%. This type of hybrid monolith has potential for the separation and purification of bioactive compounds from natural plant extracts.

关键词: Extraction, Purification, Adsorption isotherm, Hybrid organic-inorganic monolith, Quercetin, Myricetin

Abstract:

Key words: Extraction, Purification, Adsorption isotherm, Hybrid organic-inorganic monolith, Quercetin, Myricetin

ZHU Tao, LEE Yuri, ROW Kyungho. Preparation of a Hybrid Organic-inorganic Monolith for Extraction and Purification of Quercetin and Myricetin from Chamaecyparis obtusa[J]. 高等学校化学研究, 2014, 30(2): 216-221.

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Preparation of a Hybrid Organic-inorganic Monolith for Extraction and Purification of Quercetin and Myricetin from Chamaecyparis obtusa

Preparation of a Hybrid Organic-inorganic Monolith for Extraction and Purification of Quercetin and Myricetin from Chamaecyparis obtusa

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