Eco-friendly and Cleaner Process Using Online Microwave-assisted Steam Extraction Coupled with Solid-phase Extraction for Trace Analysis of Sulfonamides in Animal Feed

doi:10.1007/s40242-018-8166-2

高等学校化学研究 ›› 2018, Vol. 34 ›› Issue (6): 893-898.doi: 10.1007/s40242-018-8166-2

Eco-friendly and Cleaner Process Using Online Microwave-assisted Steam Extraction Coupled with Solid-phase Extraction for Trace Analysis of Sulfonamides in Animal Feed

LI Guijie^1,2, LIU Chang³, WANG Dawei¹, DING Lan²

1. College of Food Science, Jilin Agricultural University, Changchun 130118, P. R. China;
2. College of Chemistry, Jilin University, Changchun 130012, P. R. China;
3. Jilin Province Product Quality Supervision and Inspection Institute, Changchun 130103, P. R. China

收稿日期:2018-05-21 出版日期:2018-12-01 发布日期:2018-09-29
通讯作者: WANG Dawei, DING Lan E-mail:wangdawei@jlau.edu.cn;dinglan@jlu.edu.cn
基金资助:
Supported by the National High Technology Research and Development Program of China(No.2011AA100805) and the National Natural Science Foundation of China(No.20875037).

Eco-friendly and Cleaner Process Using Online Microwave-assisted Steam Extraction Coupled with Solid-phase Extraction for Trace Analysis of Sulfonamides in Animal Feed

LI Guijie^1,2, LIU Chang³, WANG Dawei¹, DING Lan²

1. College of Food Science, Jilin Agricultural University, Changchun 130118, P. R. China;
2. College of Chemistry, Jilin University, Changchun 130012, P. R. China;
3. Jilin Province Product Quality Supervision and Inspection Institute, Changchun 130103, P. R. China

Received:2018-05-21 Online:2018-12-01 Published:2018-09-29
Contact: WANG Dawei, DING Lan E-mail:wangdawei@jlau.edu.cn;dinglan@jlu.edu.cn
Supported by:
Supported by the National High Technology Research and Development Program of China(No.2011AA100805) and the National Natural Science Foundation of China(No.20875037).

摘要/Abstract

摘要： An environmentally friendly method for extracting sulfonamides(SAs) residues from animal feed was described and applied. The method used online microwave-assisted steam extraction coupled with solid phase extraction(MASE-SPE), which was followed by the analysis using high performance liquid chromatography-mass spectrometry(HPLC-MS/MS). The SAs residues were extracted successively with water steam under microwave irradiation, and thus directly introduced into an SPE column containing cation-exchange resin. The SAs were then eluted with methanol-ammonia(90:10, volume ratio) from the SPE column and followed by HPLC-MS/MS. The limits of detection(LODs) for the analytes ranged from 0.24 ng/g to 0.49 ng/g. The limits of quantification(LOQs) ranged from 0.82 ng/g to 1.63 ng/g. Average recoveries of SAs were 76.3%-92.1%. The developed method was a reliable and environmentally friendly alternative to previous methods with respect to time, solvent and labor consumption for the analysis of SAs in animal foodstuffs.

关键词: High performance liquid chromatography-mass spectrometry, Microwave-assisted steam extraction, Solid-phase extraction, Sulfonamide, Animal feed

Abstract: An environmentally friendly method for extracting sulfonamides(SAs) residues from animal feed was described and applied. The method used online microwave-assisted steam extraction coupled with solid phase extraction(MASE-SPE), which was followed by the analysis using high performance liquid chromatography-mass spectrometry(HPLC-MS/MS). The SAs residues were extracted successively with water steam under microwave irradiation, and thus directly introduced into an SPE column containing cation-exchange resin. The SAs were then eluted with methanol-ammonia(90:10, volume ratio) from the SPE column and followed by HPLC-MS/MS. The limits of detection(LODs) for the analytes ranged from 0.24 ng/g to 0.49 ng/g. The limits of quantification(LOQs) ranged from 0.82 ng/g to 1.63 ng/g. Average recoveries of SAs were 76.3%-92.1%. The developed method was a reliable and environmentally friendly alternative to previous methods with respect to time, solvent and labor consumption for the analysis of SAs in animal foodstuffs.

Key words: High performance liquid chromatography-mass spectrometry, Microwave-assisted steam extraction, Solid-phase extraction, Sulfonamide, Animal feed

LI Guijie, LIU Chang, WANG Dawei, DING Lan. Eco-friendly and Cleaner Process Using Online Microwave-assisted Steam Extraction Coupled with Solid-phase Extraction for Trace Analysis of Sulfonamides in Animal Feed[J]. 高等学校化学研究, 2018, 34(6): 893-898.

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Eco-friendly and Cleaner Process Using Online Microwave-assisted Steam Extraction Coupled with Solid-phase Extraction for Trace Analysis of Sulfonamides in Animal Feed

Eco-friendly and Cleaner Process Using Online Microwave-assisted Steam Extraction Coupled with Solid-phase Extraction for Trace Analysis of Sulfonamides in Animal Feed

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