Facile Chemical Conversion Synthesis and Luminescence Properties of Uniform YF3 Nanowires

doi:10.1007/s40242-013-2311-8

高等学校化学研究 ›› 2013, Vol. 29 ›› Issue (1): 1-5.doi: 10.1007/s40242-013-2311-8

Facile Chemical Conversion Synthesis and Luminescence Properties of Uniform YF₃ Nanowires

XU Zhen-he¹, GAO Yu¹, GE Xin², SUN Ya-guang¹

1. College of Applied Chemistry, Shenyang University of Chemical Technology, Shenyang 110142, P. R. China;
2. State Key Laboratory of Rare Earth Resource Utilization, Changchun Institute of Applied Chemistry, Chinese Academy of Sciences, Changchun 130022, P. R. China

收稿日期:2012-08-20 修回日期:2012-10-18 出版日期:2013-02-01 发布日期:2013-01-23
基金资助:
Supported by the National Natural Science Foundation of China(No.21071100), the Scientific Research Foundation for the Returned Overseas Chinese Scholars of Ministry of Education of China and the BaiQianWan Talents Program and the Doctor Foundation of Liaoning Province of China(No.20071016).

Facile Chemical Conversion Synthesis and Luminescence Properties of Uniform YF₃ Nanowires

XU Zhen-he¹, GAO Yu¹, GE Xin², SUN Ya-guang¹

1. College of Applied Chemistry, Shenyang University of Chemical Technology, Shenyang 110142, P. R. China;
2. State Key Laboratory of Rare Earth Resource Utilization, Changchun Institute of Applied Chemistry, Chinese Academy of Sciences, Changchun 130022, P. R. China

Received:2012-08-20 Revised:2012-10-18 Online:2013-02-01 Published:2013-01-23
Supported by:
Supported by the National Natural Science Foundation of China(No.21071100), the Scientific Research Foundation for the Returned Overseas Chinese Scholars of Ministry of Education of China and the BaiQianWan Talents Program and the Doctor Foundation of Liaoning Province of China(No.20071016).

摘要/Abstract

摘要：

Well-dispersed YF₃ nanowires were synthesized by a designed hydrothermal conversion method with Y(OH)₃ nanowires as precursor. Various equipments were used to characterize the samples. The results show that Y(OH)₃ nanowires precursor was prepared through a simple hydrothermal process, which then served as the precursor for the fabrication of YF₃ nanowires by a hydrothermal process. The whole process was carried out under aqueous conditions without any organic solvent, surfactant or catalyst. The conversion process from Y(OH)₃ precursor to YF₃ nanowires was investigated by time-dependent experiments. The possible formation mechanism of YF₃ nanowires was presented in detail. Under UV excitation, 5%(mass fraction) Eu³⁺ or 5%(mass fraction) Tb³⁺ doped YF₃ samples exhibit strong red or green emission, corresponding to the characteristic lines of Eu³⁺and Tb³⁺, respectively. Moreover, the luminescence colors of the Eu³⁺ and Tb³⁺ codoped YF₃ samples can be tuned from red, yellow and green-yellow to green by simply adjusting the relative doping concentrations of the activator ions under a single wavelength excitation, which might find potential applications in the fields of, such as, light display systems and opto- electronic devices.

关键词: Luminescence, Hydrothermal synthesis, Rare earth, Inorganic compound

Abstract:

Key words: Luminescence, Hydrothermal synthesis, Rare earth, Inorganic compound

XU Zhen-he, GAO Yu, GE Xin, SUN Ya-guang. Facile Chemical Conversion Synthesis and Luminescence Properties of Uniform YF₃ Nanowires[J]. 高等学校化学研究, 2013, 29(1): 1-5.

XU Zhen-he, GAO Yu, GE Xin, SUN Ya-guang. Facile Chemical Conversion Synthesis and Luminescence Properties of Uniform YF₃ Nanowires[J]. Chemical Research in Chinese Universities, 2013, 29(1): 1-5.

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Facile Chemical Conversion Synthesis and Luminescence Properties of Uniform YF₃ Nanowires

Facile Chemical Conversion Synthesis and Luminescence Properties of Uniform YF₃ Nanowires

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