Preparation and Properties of Electrospun Sheath-core Modified-PMMA Nanofibers with Photoluminescence and Photochromic Functions

doi:10.1007/s40242-021-1100-z

高等学校化学研究 ›› 2021, Vol. 37 ›› Issue (3): 549-557.doi: 10.1007/s40242-021-1100-z

Preparation and Properties of Electrospun Sheath-core Modified-PMMA Nanofibers with Photoluminescence and Photochromic Functions

WANG Yan¹, XI Peng^1,2, SHU Dengkun¹, MENG Shuang¹, LIU Kai¹, WANG Xiaoqing¹, CHENG Bowen^1,3

1. School of Material Science and Engineering, Tiangong University, Tianjin 300387, P. R. China;
2. Tianjin Key Laboratory of Advanced Fibers and Energy Storage, Tiangong University, Tianjin 300387, P. R. China;
3. School of Light Industry Science and Engineering, Tianjin University of Science & Technology, Tianjin 300222, P. R. China

收稿日期:2021-03-12 修回日期:2021-04-18 出版日期:2021-06-01 发布日期:2021-05-08
通讯作者: XI Peng, CHENG Bowen E-mail:xipeng@tiangong.edu.cn;Bowen@tjpu.edu.cn
基金资助:
This work was supported by the Fund for Fundamental Application of Tianjin, China(No. 18JCZDJC38300).

Preparation and Properties of Electrospun Sheath-core Modified-PMMA Nanofibers with Photoluminescence and Photochromic Functions

WANG Yan¹, XI Peng^1,2, SHU Dengkun¹, MENG Shuang¹, LIU Kai¹, WANG Xiaoqing¹, CHENG Bowen^1,3

1. School of Material Science and Engineering, Tiangong University, Tianjin 300387, P. R. China;
2. Tianjin Key Laboratory of Advanced Fibers and Energy Storage, Tiangong University, Tianjin 300387, P. R. China;
3. School of Light Industry Science and Engineering, Tianjin University of Science & Technology, Tianjin 300222, P. R. China

Received:2021-03-12 Revised:2021-04-18 Online:2021-06-01 Published:2021-05-08
Contact: XI Peng, CHENG Bowen E-mail:xipeng@tiangong.edu.cn;Bowen@tjpu.edu.cn
Supported by:
This work was supported by the Fund for Fundamental Application of Tianjin, China(No. 18JCZDJC38300).

摘要/Abstract

摘要： Multi-functional nanofibers are playing an important role in the optical field, and are widely used in fluorescence indication, product anti-counterfeit identification and smart clothing. Nanofibers with photoluminescence and photochromic functions are already attracting more interest from researchers. In this work, based on electrospun technology, the modified-PMMA nanofibers[PMMA=poly(methyl methacrylate)] with photoluminescence and photochromic functions were prepared through the design of the sheath-core structure(SCNFs 1-4). Compared with other samples, SCNF-4 shows outstanding photoluminescence and photochromic functions. SCNF-4 can produce green light and its fluorescence intensity and fluorescence lifetime can reach 7144 a.u. and 1031.32 μs, respectively. In photochromic functions, SCNF-4 can show purple in 1 min under the 365 nm ultraviolet light, and the color can be preserved for more than 4 h under the sunlight. When SCNF-4 is irradiated by far infrared light, the color of the samples can fade quickly in 40 s. Under the irradiation of ultraviolet light of different wavelengths, SCNF-4 can display multi-color fluorescence and achieve a reversible transition between white and purple. The design of the sheath-core structure realizes the complementarity of photoluminescence and photochromic functions of the electrospun modified-PMMA nanofibers, which is important to promote the wide application of multi-functional nanofibers in the optical field.

关键词: Nanofiber, Electrospun, Photochromic function, Photoluminescence

Abstract: Multi-functional nanofibers are playing an important role in the optical field, and are widely used in fluorescence indication, product anti-counterfeit identification and smart clothing. Nanofibers with photoluminescence and photochromic functions are already attracting more interest from researchers. In this work, based on electrospun technology, the modified-PMMA nanofibers[PMMA=poly(methyl methacrylate)] with photoluminescence and photochromic functions were prepared through the design of the sheath-core structure(SCNFs 1-4). Compared with other samples, SCNF-4 shows outstanding photoluminescence and photochromic functions. SCNF-4 can produce green light and its fluorescence intensity and fluorescence lifetime can reach 7144 a.u. and 1031.32 μs, respectively. In photochromic functions, SCNF-4 can show purple in 1 min under the 365 nm ultraviolet light, and the color can be preserved for more than 4 h under the sunlight. When SCNF-4 is irradiated by far infrared light, the color of the samples can fade quickly in 40 s. Under the irradiation of ultraviolet light of different wavelengths, SCNF-4 can display multi-color fluorescence and achieve a reversible transition between white and purple. The design of the sheath-core structure realizes the complementarity of photoluminescence and photochromic functions of the electrospun modified-PMMA nanofibers, which is important to promote the wide application of multi-functional nanofibers in the optical field.

Key words: Nanofiber, Electrospun, Photochromic function, Photoluminescence

WANG Yan, XI Peng, SHU Dengkun, MENG Shuang, LIU Kai, WANG Xiaoqing, CHENG Bowen. Preparation and Properties of Electrospun Sheath-core Modified-PMMA Nanofibers with Photoluminescence and Photochromic Functions[J]. 高等学校化学研究, 2021, 37(3): 549-557.

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Preparation and Properties of Electrospun Sheath-core Modified-PMMA Nanofibers with Photoluminescence and Photochromic Functions

Preparation and Properties of Electrospun Sheath-core Modified-PMMA Nanofibers with Photoluminescence and Photochromic Functions

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