Synthesis, Crystal Structure and Biological Activity of a Novel Amino Acid Salt (Hgly)4[HPMo12O40]2·22H2O

高等学校化学研究 ›› 2003, Vol. 19 ›› Issue (1): 15-19.

Synthesis, Crystal Structure and Biological Activity of a Novel Amino Acid Salt (Hgly)₄[HPMo₁₂O₄₀]₂·22H₂O

HAN Zheng-bo¹, CHANG Ya-ping², AN Hai-yan¹, WANG En-bo¹

1. Institute of Polyoxometalate Chemistry, Faculty of Chemistry, Northeast Normal University, Changchun 130024, P. R. China;
2. College of Medical, Jilin University, Changchun 130021, P. R. China

收稿日期:2001-11-20 出版日期:2003-01-24 发布日期:2011-08-06
基金资助:
Supported by National Natural Science Foundation of China(No.20171010).

Synthesis, Crystal Structure and Biological Activity of a Novel Amino Acid Salt (Hgly)₄[HPMo₁₂O₄₀]₂·22H₂O

HAN Zheng-bo¹, CHANG Ya-ping², AN Hai-yan¹, WANG En-bo¹

1. Institute of Polyoxometalate Chemistry, Faculty of Chemistry, Northeast Normal University, Changchun 130024, P. R. China;
2. College of Medical, Jilin University, Changchun 130021, P. R. China

Received:2001-11-20 Online:2003-01-24 Published:2011-08-06
Supported by:
Supported by National Natural Science Foundation of China(No.20171010).

摘要/Abstract

摘要： A novel compound, (Hgly)₄[HPMo₁₂O₄₀]₂·22H₂O, was synthesized and characterized by means of elemental analysis, IR and X-ray diffraction. The compound crystallized in a monoclinic space group Cc with a=4.0060(0.8) nm, b=1.2527(0.3) nm, c=1.9930(0.4) nm, β=96.36(3)°, V=9.940(3) nm³, Z=2, R₁=0.0576, wR₂=0.1746. The anti-tumor activity of this compound was tested in two human tumor cell lines in vitro.

关键词: Polyoxometalate, Gly, Crystal structure, Biological activity

Abstract: A novel compound, (Hgly)₄[HPMo₁₂O₄₀]₂·22H₂O, was synthesized and characterized by means of elemental analysis, IR and X-ray diffraction. The compound crystallized in a monoclinic space group Cc with a=4.0060(0.8) nm, b=1.2527(0.3) nm, c=1.9930(0.4) nm, β=96.36(3)°, V=9.940(3) nm³, Z=2, R₁=0.0576, wR₂=0.1746. The anti-tumor activity of this compound was tested in two human tumor cell lines in vitro.

Key words: Polyoxometalate, Gly, Crystal structure, Biological activity

HAN Zheng-bo, CHANG Ya-ping, AN Hai-yan, WANG En-bo. Synthesis, Crystal Structure and Biological Activity of a Novel Amino Acid Salt (Hgly)₄[HPMo₁₂O₄₀]₂·22H₂O[J]. 高等学校化学研究, 2003, 19(1): 15-19.

HAN Zheng-bo, CHANG Ya-ping, AN Hai-yan, WANG En-bo. Synthesis, Crystal Structure and Biological Activity of a Novel Amino Acid Salt (Hgly)₄[HPMo₁₂O₄₀]₂·22H₂O[J]. Chemical Research in Chinese Universities, 2003, 19(1): 15-19.

[1]	CHEN Zhangwu and LI Fen. Proton-induced Conversion from Non-Aufbau to Aufbau Electronic Structure of an Organic Radical with Turn-on Fluorescence[J]. 高等学校化学研究, 2022, 38(3): 798-802.
[2]	HUA Chen, YI Pin, LIU Wencong, WANG Mengfan, NIU Zheng, LANG Jianping. Coordination Polymers with Bipyridyl Diene and Triene Ligands: Synthesis, Structures and Luminescent Properties[J]. 高等学校化学研究, 2022, 38(1): 209-216.
[3]	Matthew J. OWEN, Jasper H. N. YIK, Congwang YE, Brianca NETTO, Dominik R. HAUDENSCHILD, Gang-yu LIU. A Green Approach to Producing Polymer Microparticles for Local Sustained Release of Flavopiridol[J]. 高等学校化学研究, 2021, 37(5): 1116-1124.
[4]	LIU Fei, LI Ren, YE Jing, REN Yujie, TANG Zhipeng, LI Rongchen, ZHANG Cuihua, LI Qunlin. Study of Aldo-keto Reductase 1C3 Inhibitor with Novel Framework for Treating Leukaemia Based on Virtual Screening and In vitro Biological Activity Testing[J]. 高等学校化学研究, 2021, 37(3): 778-786.
[5]	ZHANG Ling, FU Yihong, DING Yue, MENG Jiao, WANG Zhenchao, WANG Peiyi. Antibacterial Activity of Novel 18β-Glycyrrhetinic Hydrazide or Amide Derivatives[J]. 高等学校化学研究, 2021, 37(3): 662-667.
[6]	CEN Qing, XIAO Wei, LIU Yingqi, WANG Qi, NAFADY Ayman, MA Shengqian. Fabrication of Fe-POMs as Visible-light-active Heterogeneous Photocatalyst[J]. 高等学校化学研究, 2020, 36(6): 1128-1135.
[7]	ZHANG Wenqi, LIN Zhengguo, CHI Yingnan, HONG Jie, YAN Li, HU Changwen. Assembly of Three Scandium-containing Heteropolytungstates Based on a Building-block Synthetic Strategy[J]. 高等学校化学研究, 2020, 36(6): 1161-1167.
[8]	LI Zhihui, GUO Xiaotong, ZHANG Yaning, LIU Guangzhou, ZHANG Shuyong. Abnormal Blood Glucose Concentration on Degradation Behavior of AZ31 Magnesium Alloy[J]. 高等学校化学研究, 2020, 36(6): 1217-1226.
[9]	El Houssine MABROUK, Nadia ARROUSSE, Adil KORCHI, Mohammed LACHGAR, Ahmad OUBAIR, Abdelrhani ELACHQAR, Mohamed JABHA, Mohammed LACHKAR, Fadoua El HAJJAJI, Zakia RAIS, Mustapha TALEB. Intelligence Way from Eco-friendly Synthesis Strategy of New Heterocyclic Pyrazolic Carboxylic α-Amino Esters[J]. 高等学校化学研究, 2020, 36(6): 1183-1189.
[10]	XIONG Jin'en, LI Shuang, LI Yi, CHEN Yingli, LIU Yu, GAN Junlan, JU Jiahui, XIAN Yaoling, XIONG Xiaohui. Fluorescent Aptamer-Polyethylene Glycol Functionalized Graphene Oxide Biosensor for Profenofos Detection in Food[J]. 高等学校化学研究, 2020, 36(5): 787-794.
[11]	ZHAO Yanhui, YU Haifeng, LIAO Peiqiu, WANG Wenju. Green and Efficient Synthesis of 3-Pyrazolyl Indoles in Water[J]. 高等学校化学研究, 2020, 36(5): 847-852.
[12]	ZANG Jiahe, ZHANG Qing'an, SUN Dalin. Crystal Structures and Electrochemical Properties of R_1.5Ca_1.5MgNi₁₄(R=Nd, Gd and Er) Hydrogen Storage Alloys[J]. 高等学校化学研究, 2019, 35(6): 1040-1045.
[13]	WANG Dongmei, LOU Shengjun, YING Yiting, GUO Zhiqi, WANG Lijun. Assembly of Two Isostructural Metal-organic Frameworks Based on Hetero-N,O Donor Ligand for Detecting Nitro Explosives[J]. 高等学校化学研究, 2019, 35(5): 762-766.
[14]	MA Xiao, WANG Xiaohong, SHANG Fan, DING Zimei, HANG Xiaojing, HUANG Jie. Studies on 3-Amino-4-(1H-tetrazol-5-yl)-furazan: Crystal Structure, Thermal Behavior and Energetic Performance[J]. 高等学校化学研究, 2019, 35(5): 848-853.
[15]	DONG Pengfei, LI Na, ZHAO Haiyan, CUI Min, ZHANG Cong, HAN Hongyan, REN Jujie. POMs as Active Center for Sensitively Electrochemical Detection of Bisphenol A and Acetaminophen[J]. 高等学校化学研究, 2019, 35(4): 592-597.

Synthesis, Crystal Structure and Biological Activity of a Novel Amino Acid Salt (Hgly)₄[HPMo₁₂O₄₀]₂·22H₂O

Synthesis, Crystal Structure and Biological Activity of a Novel Amino Acid Salt (Hgly)₄[HPMo₁₂O₄₀]₂·22H₂O

PDF (PC)

可视化

摘要/Abstract

引用本文

使用本文

参考文献

相关文章 15

编辑推荐

Metrics

本文评价