Functionalizable and Recyclable Aliphatic Polycarbonates Derived from Biomass Feedstocks and CO2

doi:10.1007/s40242-023-3165-3

高等学校化学研究 ›› 2023, Vol. 39 ›› Issue (5): 809-815.doi: 10.1007/s40242-023-3165-3

Functionalizable and Recyclable Aliphatic Polycarbonates Derived from Biomass Feedstocks and CO₂

WU Yanchen, FAN Huazhong, SHAN Siyi, WANG Siqi, CAI Zhongzheng, ZHU Jian-Bo

National Engineering Laboratory of Eco-Friendly Polymeric Materials (Sichuan), College of Chemistry, Sichuan University, Chengdu 610064, P. R. China

收稿日期:2023-07-19 出版日期:2023-10-01 发布日期:2023-09-26
通讯作者: CAI Zhongzheng, ZHU Jian-Bo E-mail:zzcai@scu.edu.cn;jbzhu@scu.edu.cn
基金资助:
This work was supported by the National Natural Science Foundation of China (No.22071163) and the Fundamental Research Funds for the Central Universities of China (Nos.YJ201924, YJ202209).

Functionalizable and Recyclable Aliphatic Polycarbonates Derived from Biomass Feedstocks and CO₂

WU Yanchen, FAN Huazhong, SHAN Siyi, WANG Siqi, CAI Zhongzheng, ZHU Jian-Bo

National Engineering Laboratory of Eco-Friendly Polymeric Materials (Sichuan), College of Chemistry, Sichuan University, Chengdu 610064, P. R. China

Received:2023-07-19 Online:2023-10-01 Published:2023-09-26
Contact: CAI Zhongzheng, ZHU Jian-Bo E-mail:zzcai@scu.edu.cn;jbzhu@scu.edu.cn
Supported by:
This work was supported by the National Natural Science Foundation of China (No.22071163) and the Fundamental Research Funds for the Central Universities of China (Nos.YJ201924, YJ202209).

摘要/Abstract

摘要： Two bio-based seven-membered cyclic carbonate monomers M1 and M2 were synthesized in three steps from myrcene, which could produce polycarbonates via ring-opening polymerization using metal or organic catalysts. The functionalizable olefin moieties in resulting polycarbonates have driven post-polymerization modifications via radical cross-linking and hydrogenation, enabling the resulting polymers with tunable thermal properties. More importantly, the chemical recycling of P(M)s was achieved through "monomer → polymer ⇄ dimer", which presented a platform for the synthesis of chemically recyclable biobased polycarbonates.

关键词: Biomass, CO₂, Polycarbonate, Functionalization, Chemical recyclability

Abstract: Two bio-based seven-membered cyclic carbonate monomers M1 and M2 were synthesized in three steps from myrcene, which could produce polycarbonates via ring-opening polymerization using metal or organic catalysts. The functionalizable olefin moieties in resulting polycarbonates have driven post-polymerization modifications via radical cross-linking and hydrogenation, enabling the resulting polymers with tunable thermal properties. More importantly, the chemical recycling of P(M)s was achieved through "monomer → polymer ⇄ dimer", which presented a platform for the synthesis of chemically recyclable biobased polycarbonates.

Key words: Biomass, CO₂, Polycarbonate, Functionalization, Chemical recyclability

WU Yanchen, FAN Huazhong, SHAN Siyi, WANG Siqi, CAI Zhongzheng, ZHU Jian-Bo. Functionalizable and Recyclable Aliphatic Polycarbonates Derived from Biomass Feedstocks and CO₂[J]. 高等学校化学研究, 2023, 39(5): 809-815.

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Functionalizable and Recyclable Aliphatic Polycarbonates Derived from Biomass Feedstocks and CO₂

Functionalizable and Recyclable Aliphatic Polycarbonates Derived from Biomass Feedstocks and CO₂

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