Multiple Responsive Photonic Prints Through Localized Interpenetrating Polymer Network

doi:10.1007/s40242-023-3154-6

高等学校化学研究 ›› 2023, Vol. 39 ›› Issue (5): 803-808.doi: 10.1007/s40242-023-3154-6

Multiple Responsive Photonic Prints Through Localized Interpenetrating Polymer Network

ZHANG Tian¹, JIA Xiaolu², HOU Zaiyan¹, XIE Ge¹, ZHANG Lianbin¹, ZHU Jintao¹

1. Key Laboratory of Material Chemistry for Energy Conversion and Storage of Ministry of Education, State Key Laboratory of Materials Processing and Mold Technology, School of Chemistry and Chemical Engineering, Huazhong University of Science and Technology, Wuhan 430074, P. R. China;
2. School of Chemistry & Chemical Engineering, Zhoukou Normal University, Zhoukou 466001, P. R. China

收稿日期:2023-07-06 出版日期:2023-10-01 发布日期:2023-09-26
通讯作者: ZHANG Lianbin E-mail:zhanglianbin@hust.edu.cn
基金资助:
This work was supported by the National Natural Science Foundation of China (No.52022032), the Natural Science Foundation of Hubei Province, China (No.2022CFA048), and the Key Research Project of Henan Higher Education Institute, China (No.21A150066).

Multiple Responsive Photonic Prints Through Localized Interpenetrating Polymer Network

ZHANG Tian¹, JIA Xiaolu², HOU Zaiyan¹, XIE Ge¹, ZHANG Lianbin¹, ZHU Jintao¹

1. Key Laboratory of Material Chemistry for Energy Conversion and Storage of Ministry of Education, State Key Laboratory of Materials Processing and Mold Technology, School of Chemistry and Chemical Engineering, Huazhong University of Science and Technology, Wuhan 430074, P. R. China;
2. School of Chemistry & Chemical Engineering, Zhoukou Normal University, Zhoukou 466001, P. R. China

Received:2023-07-06 Online:2023-10-01 Published:2023-09-26
Contact: ZHANG Lianbin E-mail:zhanglianbin@hust.edu.cn
Supported by:
This work was supported by the National Natural Science Foundation of China (No.52022032), the Natural Science Foundation of Hubei Province, China (No.2022CFA048), and the Key Research Project of Henan Higher Education Institute, China (No.21A150066).

摘要/Abstract

摘要： Multiple responsive photonic prints that can be revealed by a thermal or light stimulus are prepared by locally producing interpenetrating polymer network (IPN) within photonic hydrogels. Thermo-responsive poly-(N-isopropylacrylamide) (PNIPAM) photonic hydrogels with self-assembled monodisperse carbon-encapsulated Fe₃O₄ nanoparticles (Fe₃O₄@C NPs) are first prepared by a photopolymerization process. Then photopolymerization of acrylamide (AM) is carried out within the photonic hydrogel with the help of a mask to generate an IPN structure locally. Because of the regionally different network structure and the resulting varied responsiveness, responsive photonic prints are obtained. Due to the thermo-responsive capability of the PNIPAM and the photothermal conversion capability of the incorporated Fe₃O₄@C NPs, the as-prepared photonic prints with a localized IPN structure can shift the structural color in a broad spectrum range under thermal or light stimuli. The current multiple responsive photonic prints with a localized IPN structure can realize full-color pattern display under thermal and light stimulations, providing a new path for anti-counterfeiting, display, and information encoding.

关键词: Photonic crystal, Photothermal, Hydrogel, Patterning, Stimuli-responsive

Abstract: Multiple responsive photonic prints that can be revealed by a thermal or light stimulus are prepared by locally producing interpenetrating polymer network (IPN) within photonic hydrogels. Thermo-responsive poly-(N-isopropylacrylamide) (PNIPAM) photonic hydrogels with self-assembled monodisperse carbon-encapsulated Fe₃O₄ nanoparticles (Fe₃O₄@C NPs) are first prepared by a photopolymerization process. Then photopolymerization of acrylamide (AM) is carried out within the photonic hydrogel with the help of a mask to generate an IPN structure locally. Because of the regionally different network structure and the resulting varied responsiveness, responsive photonic prints are obtained. Due to the thermo-responsive capability of the PNIPAM and the photothermal conversion capability of the incorporated Fe₃O₄@C NPs, the as-prepared photonic prints with a localized IPN structure can shift the structural color in a broad spectrum range under thermal or light stimuli. The current multiple responsive photonic prints with a localized IPN structure can realize full-color pattern display under thermal and light stimulations, providing a new path for anti-counterfeiting, display, and information encoding.

Key words: Photonic crystal, Photothermal, Hydrogel, Patterning, Stimuli-responsive

ZHANG Tian, JIA Xiaolu, HOU Zaiyan, XIE Ge, ZHANG Lianbin, ZHU Jintao. Multiple Responsive Photonic Prints Through Localized Interpenetrating Polymer Network[J]. 高等学校化学研究, 2023, 39(5): 803-808.

ZHANG Tian, JIA Xiaolu, HOU Zaiyan, XIE Ge, ZHANG Lianbin, ZHU Jintao. Multiple Responsive Photonic Prints Through Localized Interpenetrating Polymer Network[J]. Chemical Research in Chinese Universities, 2023, 39(5): 803-808.

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Multiple Responsive Photonic Prints Through Localized Interpenetrating Polymer Network

Multiple Responsive Photonic Prints Through Localized Interpenetrating Polymer Network

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