Preparation of β-Cyclodextrin/Fe3O4/Polyvinylpyrrolidone Composite Magnetic Microspheres for the Adsorption of Methyl Orange

doi:10.1007/s40242-017-7083-0

高等学校化学研究 ›› 2017, Vol. 33 ›› Issue (6): 1012-1016.doi: 10.1007/s40242-017-7083-0

• Articles • 上一篇

Preparation of β-Cyclodextrin/Fe₃O₄/Polyvinylpyrrolidone Composite Magnetic Microspheres for the Adsorption of Methyl Orange

SI Qingbo¹, WEN Qian², YANG Qingbiao², SONG Yan¹, LI Yaoxian²

1. Department of Materials Science and Engineering, Jilin Institute of Chemical Technology, Jilin 132022, P. R. China;
2. College of Chemistry, Jilin University, Changchun 130021, P. R. China

收稿日期:2017-03-07 修回日期:2017-07-25 出版日期:2017-12-01 发布日期:2017-09-26
通讯作者: SONG Yan,E-mail:songyan199809@163.com E-mail:songyan199809@163.com
基金资助:
Supported by the Science and Technology Innovation and Development Plan of Jilin City, China(No.20161204).

Preparation of β-Cyclodextrin/Fe₃O₄/Polyvinylpyrrolidone Composite Magnetic Microspheres for the Adsorption of Methyl Orange

SI Qingbo¹, WEN Qian², YANG Qingbiao², SONG Yan¹, LI Yaoxian²

1. Department of Materials Science and Engineering, Jilin Institute of Chemical Technology, Jilin 132022, P. R. China;
2. College of Chemistry, Jilin University, Changchun 130021, P. R. China

Received:2017-03-07 Revised:2017-07-25 Online:2017-12-01 Published:2017-09-26
Contact: SONG Yan,E-mail:songyan199809@163.com E-mail:songyan199809@163.com
Supported by:
Supported by the Science and Technology Innovation and Development Plan of Jilin City, China(No.20161204).

摘要/Abstract

摘要： Magnetic microspherical β-cyclodextrin(CD)/Fe₃O₄@polyvinylpyrrolidone(PVP) particles, in which embedded Fe₃O₄ particles were coated by β-CD/glutaraldehyde crosslinked PVP, were synthesized via electrostatic spray and thermal crosslinking technologies. The magnetic microspheres were characterized by infrared spectroscopy, X-ray diffraction, scanning electron microscopy(SEM) and magnetic measurements, and the adsorption performance of the β-CD/Fe₃O₄@PVP composite nanoparticles for methyl orange was studied. The results show that the β-CD/Fe₃O₄@PVP microspheres could be quickly separated from the adsorption system under an external magnetic field within 30 s and that the adsorption capacity of the microspheres for methyl orange reaches greater than 90%, with a maximum adsorption quantity of 47.62 mg/g.

关键词: Electrospray, β-Cyclodextrin, Adsorption, Methyl orange, Magnetic microsphere

Abstract: Magnetic microspherical β-cyclodextrin(CD)/Fe₃O₄@polyvinylpyrrolidone(PVP) particles, in which embedded Fe₃O₄ particles were coated by β-CD/glutaraldehyde crosslinked PVP, were synthesized via electrostatic spray and thermal crosslinking technologies. The magnetic microspheres were characterized by infrared spectroscopy, X-ray diffraction, scanning electron microscopy(SEM) and magnetic measurements, and the adsorption performance of the β-CD/Fe₃O₄@PVP composite nanoparticles for methyl orange was studied. The results show that the β-CD/Fe₃O₄@PVP microspheres could be quickly separated from the adsorption system under an external magnetic field within 30 s and that the adsorption capacity of the microspheres for methyl orange reaches greater than 90%, with a maximum adsorption quantity of 47.62 mg/g.

Key words: Electrospray, β-Cyclodextrin, Adsorption, Methyl orange, Magnetic microsphere

SI Qingbo, WEN Qian, YANG Qingbiao, SONG Yan, LI Yaoxian. Preparation of β-Cyclodextrin/Fe₃O₄/Polyvinylpyrrolidone Composite Magnetic Microspheres for the Adsorption of Methyl Orange[J]. 高等学校化学研究, 2017, 33(6): 1012-1016.

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Preparation of β-Cyclodextrin/Fe₃O₄/Polyvinylpyrrolidone Composite Magnetic Microspheres for the Adsorption of Methyl Orange

Preparation of β-Cyclodextrin/Fe₃O₄/Polyvinylpyrrolidone Composite Magnetic Microspheres for the Adsorption of Methyl Orange

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