高等学校化学研究 ›› 2015, Vol. 31 ›› Issue (3): 427-429.doi: 10.1007/s40242-015-4460-4
ZUO Yinyan1, CHEN Xia2, LIU Xiaobin1
ZUO Yinyan1, CHEN Xia2, LIU Xiaobin1
摘要:
Red long lasting phosphorescence(LLP) was firstly observed in LaAlO3:Eu3+ phosphor synthesized by solid state method at 1773 K. It reveals that the Eu3+ ions occupy the asymmetric La3+ sites, resulting in the orange-red emission of Eu3+. The LLP of the optimum LaAlO3:0.6%Eu3+ sample can come to about 2000 s according to a definition of 0.32 mcd/m2. The LLP decay curve can not be fitted even by a function of three exponential terms, due to the complicated retrapping process of carriers. The result of a classical multi-peak fitting method on thermoluminescence reveals that the excellent LLP performance of LaAlO3:Eu3+ material originates from the rich distribution of shallow traps(E=0.7875 eV).