Sub-nanomaterials for Photo/Electro-catalytic CO2 Reduction: Achievements, Challenges, and Opportunities

doi:10.1007/s40242-023-3123-0

摘要/Abstract

摘要： With the increasing dilemma of energy crisis and climate change caused by excessive greenhouse gas emissions, it is an effective way to design low-cost and efficient catalysts to recycle CO₂ into value-added chemicals and fuels to solve these problems. Downsizing catalysts close to a single crystal cell, sub-nanomaterials(SNMs) show unique size-dependent properties and great potential applications in CO₂ reduction reaction (CO₂RR) compared with conventional nanomaterials. In this review, basic principles of CO₂RR and brief classification of SNMs are elucidated. Then, recent advances of SNMs in photo/electro-catalytic CO₂ reduction are comprehensively summarized. Finally, the current challenges and future outlooks are emphasized to pave the development of CO₂RR on SNMs. It is anticipated that this review would provide new insights to this unique scale and guided information on rational construction of SNMs for photo/electro-catalytic CO₂RR.

关键词: Sub-nanomaterial, CO₂ reduction, Electrocatalysis, Photocatalysis, Photoelectrocatalysis

Abstract: With the increasing dilemma of energy crisis and climate change caused by excessive greenhouse gas emissions, it is an effective way to design low-cost and efficient catalysts to recycle CO₂ into value-added chemicals and fuels to solve these problems. Downsizing catalysts close to a single crystal cell, sub-nanomaterials(SNMs) show unique size-dependent properties and great potential applications in CO₂ reduction reaction (CO₂RR) compared with conventional nanomaterials. In this review, basic principles of CO₂RR and brief classification of SNMs are elucidated. Then, recent advances of SNMs in photo/electro-catalytic CO₂ reduction are comprehensively summarized. Finally, the current challenges and future outlooks are emphasized to pave the development of CO₂RR on SNMs. It is anticipated that this review would provide new insights to this unique scale and guided information on rational construction of SNMs for photo/electro-catalytic CO₂RR.

Key words: Sub-nanomaterial, CO₂ reduction, Electrocatalysis, Photocatalysis, Photoelectrocatalysis

WANG Xinyi, ZHAO Zhenwei, ZAHRA Kiran, LI Junjun, ZHANG Zhicheng. Sub-nanomaterials for Photo/Electro-catalytic CO₂ Reduction: Achievements, Challenges, and Opportunities[J]. 高等学校化学研究, 2023, 39(4): 580-598.

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Sub-nanomaterials for Photo/Electro-catalytic CO₂ Reduction: Achievements, Challenges, and Opportunities

Sub-nanomaterials for Photo/Electro-catalytic CO₂ Reduction: Achievements, Challenges, and Opportunities

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