Nanoclusters as Synthons for Unit-Cell-Size Comparable One-Dimensional Nanostructures

doi:10.1007/s40242-023-3121-2

高等学校化学研究 ›› 2023, Vol. 39 ›› Issue (4): 568-579.doi: 10.1007/s40242-023-3121-2

Nanoclusters as Synthons for Unit-Cell-Size Comparable One-Dimensional Nanostructures

FU Hao^1,2, DU Yaping¹

1. Tianjin Key Lab for Rare Earth Materials and Applications, Center for Rare Earth and Inorganic Functional Materials, School of Materials Science and Engineering, National Institute for Advanced Materials, Nankai University, Tianjin 300350, P.R. China;
2. College of Chemistry, Nankai University, Tianjin 300071, P.R. China

收稿日期:2023-05-12 出版日期:2023-08-01 发布日期:2023-07-18
通讯作者: DU Yaping E-mail:ypdu@nankai.edu.cn
基金资助:
This work was supported by the National Natural Science Foundation of China (No.21971117), the Functional Research Funds for the Central Universities, Nankai University, China(No.63186005), the Project of Tianjin Key Lab for Rare Earth Materials and Applications, China(No.ZB19500202), the Open Funds of the State Key Laboratory of Rare Earth Resource Utilization, China (No.RERU2019001), the "111" Project from China(No.B18030), the Outstanding Youth Project of the Tianjin Natural Science Foundation, China (No.20JCJQJC00130), the Key Project of Tianjin Natural Science Foundation, China(No.20JCZDJC00650), and the Open Foundation of Guangxi Key Laboratory of Processing for Non-ferrous Metals and Featured Materials, China (No.2022GXYSOF07).

Nanoclusters as Synthons for Unit-Cell-Size Comparable One-Dimensional Nanostructures

FU Hao^1,2, DU Yaping¹

1. Tianjin Key Lab for Rare Earth Materials and Applications, Center for Rare Earth and Inorganic Functional Materials, School of Materials Science and Engineering, National Institute for Advanced Materials, Nankai University, Tianjin 300350, P.R. China;
2. College of Chemistry, Nankai University, Tianjin 300071, P.R. China

Received:2023-05-12 Online:2023-08-01 Published:2023-07-18
Contact: DU Yaping E-mail:ypdu@nankai.edu.cn
Supported by:
This work was supported by the National Natural Science Foundation of China (No.21971117), the Functional Research Funds for the Central Universities, Nankai University, China(No.63186005), the Project of Tianjin Key Lab for Rare Earth Materials and Applications, China(No.ZB19500202), the Open Funds of the State Key Laboratory of Rare Earth Resource Utilization, China (No.RERU2019001), the "111" Project from China(No.B18030), the Outstanding Youth Project of the Tianjin Natural Science Foundation, China (No.20JCJQJC00130), the Key Project of Tianjin Natural Science Foundation, China(No.20JCZDJC00650), and the Open Foundation of Guangxi Key Laboratory of Processing for Non-ferrous Metals and Featured Materials, China (No.2022GXYSOF07).

摘要/Abstract

摘要： The unit-cell-size comparable ultrathin nanowires(UCNWs) with typical cross-sectional dimension of around one nanometer, comparable to the unit-cell-size of inorganic materials, exhibit unique properties different from traditional nanomaterials. However, their facile and general synthesis is still a great challenge, since it not only demands the anisotropic growth in one direction, but also needs to completely restrict the growth in the other two dimensions. In this review, we summarize and introduce a strategy to prepare UCNWs using nanoclusters as synthons, which is promising to be a general synthesis method for UCNWs. We start with the introduction to the definition and characteristics of UCNWs. Subsequently, the key problems of UCNWs synthesis are analyzed from the perspective of thermodynamics and the strategy of using nanoclusters as synthons is proposed. Then, the related works about synthesis of UCNWs using magic-size clusters(MSCs) and polyoxometalate(POM) clusters as synthons are introduced and carefully discussed. Finally, challenges and opportunities are also elaborately discussed. This review is anticipated to provide a panoramic sketch and future directions toward the general synthesis of UCNWs.

关键词: Controlled synthesis, Ultrathin nanowire, One-dimensional structure, Magic-size cluster, Polyoxometalate

Abstract: The unit-cell-size comparable ultrathin nanowires(UCNWs) with typical cross-sectional dimension of around one nanometer, comparable to the unit-cell-size of inorganic materials, exhibit unique properties different from traditional nanomaterials. However, their facile and general synthesis is still a great challenge, since it not only demands the anisotropic growth in one direction, but also needs to completely restrict the growth in the other two dimensions. In this review, we summarize and introduce a strategy to prepare UCNWs using nanoclusters as synthons, which is promising to be a general synthesis method for UCNWs. We start with the introduction to the definition and characteristics of UCNWs. Subsequently, the key problems of UCNWs synthesis are analyzed from the perspective of thermodynamics and the strategy of using nanoclusters as synthons is proposed. Then, the related works about synthesis of UCNWs using magic-size clusters(MSCs) and polyoxometalate(POM) clusters as synthons are introduced and carefully discussed. Finally, challenges and opportunities are also elaborately discussed. This review is anticipated to provide a panoramic sketch and future directions toward the general synthesis of UCNWs.

Key words: Controlled synthesis, Ultrathin nanowire, One-dimensional structure, Magic-size cluster, Polyoxometalate

FU Hao, DU Yaping. Nanoclusters as Synthons for Unit-Cell-Size Comparable One-Dimensional Nanostructures[J]. 高等学校化学研究, 2023, 39(4): 568-579.

FU Hao, DU Yaping. Nanoclusters as Synthons for Unit-Cell-Size Comparable One-Dimensional Nanostructures[J]. Chemical Research in Chinese Universities, 2023, 39(4): 568-579.

参考文献

[1] Mannix A. J., Kiraly B., Hersam M. C., Guisinger N. P., Nat. Rev. Chem., 2017, 1, 0014
[2] Nasilowski M., Mahler B., Lhuillier E., Ithurria S., Dubertret B., Chem. Rev., 2016, 116, 10934
[3] Quan L., Kang J., Ning C., Yang P., Chem. Rev., 2019, 119, 9153
[4] Gutiérrez H. R., Kuno Hong S. S., Ruoff R. S., Huang Gupta J. A., ACS Nano, 2013, 7, 2898
[5] Garnett E., Mai L., Yang P., Chem. Rev., 2019, 119, 8955
[6] Ni B., Shi Y., Wang X., Adv. Mater., 2018, 30, e1802031
[7] Voiry D., Shin H. S., Loh K. P., Chhowalla M., Nat. Rev. Chem., 2018, 2, 0105
[8] Xu H., Shang H., Wang C., Du Y., Adv. Funct. Mater., 2020, 30, 2000793
[9] Li M., Zhao Z., Cheng T., Fortunelli A., Chen C., Yu R., Zhang Q., Gu L., Merinov B. V., Lin Z., Zhu E., Yu T., Jia Q., Guo J., Zhang L., Goddard W. A., Huang Y., Duan X., Science, 2016, 354, 1414
[10] Zhang H., Wang Y., Zuo S., Zhou W., Zhang J., Lou X. W. D., J. Am. Chem. Soc., 2021, 143, 2173
[11] Peng L., Hu L., Fang X., Adv. Mater., 2013, 25, 5321
[12] Tong Y., Bohn B. J., Bladt E., Wang K., Muller-Buschbaum P., Bals S., Urban A. S., Polavarapu L., Feldmann J., Angew. Chem. Int. Ed., 2017, 56, 13887
[13] Chueh Y. L., Hsieh C. H., Chang M. T., Chou L. J., Lao C. S., Song J. H., Gan J. Y., Wang Z. L., Adv. Mater., 2007, 19, 143
[14] Wang D., Liu X., Kang Y., Wang X., Wu Y., Fang S., Yu H., Memon M. H., Zhang H., Hu W., Mi Z., Fu L., Sun H., Long S., Nat. Electron., 2021, 4, 645
[15] Wang X., Xu X., Niu C., Meng J., Huang M., Liu X., Liu Z., Mai L., Nano Lett., 2017, 17, 544
[16] Shao B., Wan S., Yang C., Shen J., Li Y., You H., Chen D., Fan C., Liu K., Zhang H., Angew. Chem. Int. Ed., 2020, 59, 18213
[17] Meng Z., Liu Q., Zhang Y., Sun J., Yang C., Li H., Loznik M., Göstl R., Chen D., Wang F., Clark N. A., Zhang H., Herrmann A., Liu K., Adv. Mater., 2022, 34, 2106208
[18] Wei Z., Sun J., Lu S., Liu Y., Wang B., Zhao L., Wang Z., Liu K., Li J., Su J., Wang F., Zhang H., Yang Y., Adv. Mater., 2022, 34, 2110062
[19] Wan S., Cong W., Shao B., Wu B., He Q., Cheng Q., Shen J., Chen D., Hu H., Ye F., Fan C., Zhang H., Liu K., Nano Today, 2021, 38, 101115
[20] Sun J., Zhang J., Zhao L., Wan S., Wu B., Ma C., Li J., Wang F., Xing X., Chen D., Zhang H., Liu K., CCS Chem., 2023, 5, 1242
[21] Gülseren O., Ercolessi F., Tosatti E., Phys. Rev. Lett., 1998, 80, 3775
[22] Kondo Y., Takayanagi K., Science, 2000, 289, 606
[23] Barrigon E., Heurlin M., Bi Z., Monemar B., Samuelson L., Chem. Rev., 2019, 119, 9170
[24] Cademartiri L., Malakooti R., O'Brien P. G., Migliori A., Petrov S., Kherani N. P., Ozin G. A., Angew. Chem. Int. Ed., 2008, 47, 3814
[25] Cademartiri L., Ozin G. A., Adv. Mater., 2009, 21, 1013
[26] Whitesides G. M., Nature, 2006, 442, 368
[27] Cademartiri L., Montanari E., Calestani G., Migliori A., Guagliardi A., Ozin G. A., J. Am. Chem. Soc., 2006, 128, 10337
[28] Thomson J. W., Cademartiri L., MacDonald M., Petrov S., Calestani G., Zhang P., Ozin G. A., J. Am. Chem. Soc., 2010, 132, 9058
[29] Cademartiri L., Guerin G., Bishop K. J., Winnik M. A., Ozin G. A., J. Am. Chem. Soc., 2012, 134, 9327
[30] Hu S., Liu H., Wang P., Wang X., J. Am. Chem. Soc., 2013, 135, 11115
[31] Yuan F., Ouyang C., Yang M., Shi W., Ren W., Shen Y., Wei Y., Deng X., Wang X., Angew. Chem. Int. Ed., 2023, 62, e202214571
[32] Liu H., Gong Q., Yue Y., Guo L., Wang X., J. Am. Chem. Soc., 2017, 139, 8579
[33] Zhang S., Lin H., Yang H., Ni B., Li H., Wang X., Adv. Funct. Mater., 2019, 29, 1903477
[34] Zhang S., Shi W., Yu B., Wang X., J. Am. Chem. Soc., 2022, 144, 16389
[35] Huo D., Kim M. J., Lyu Z., Shi Y., Wiley B. J., Xia Y., Chem. Rev., 2019, 119, 897
[36] Wang C., Hou Y., Kim J., Sun S., Angew. Chem. Int. Ed., 2007, 46, 6333
[37] Du Y., Zhang Y., Yan Z., Sun L., Yan C. H., J. Am. Chem. Soc., 2009, 131, 16364
[38] Huo Z., Tsung C. K., Huang W., Zhang X., Yang P., Nano Lett., 2008, 8, 2041
[39] Yu T., Joo J., Park Y., Hyeon T., J. Am. Chem. Soc., 2006, 128, 1786
[40] Ni B., Zhang Q., Ouyang C., Zhang S., Yu B., Zhuang J., Gu L., Wang X., CCS Chem., 2020, 2, 642
[41] Cunningham P. D., Coropceanu I., Mulloy K., Cho W., Talapin D. V., ACS Nano, 2020, 14, 3847
[42] Fu H., Xu Y., Qiu D., Ma T., Yue G., Zeng Z., Song L., Wang S., Zhang S., Du Y., Yan C. H., Angew. Chem. Int. Ed., 2022, 61, e202212251
[43] LaMer V. K., Dinegar R. H., J. Am. Chem. Soc., 1950, 72, 4847
[44] LaMer V. K., Ind. Eng. Chem. Res., 1952, 44, 1270
[45] Thanh N. T., Maclean N., Mahiddine S., Chem. Rev., 2014, 114, 7610
[46] Embden J., Chesman A. S. R., Jasieniak J. J., Chem. Mater., 2015, 27, 2246
[47] Ryadnov M. G., Woolfson D. N., J. Am. Chem. Soc., 2004, 126, 7454
[48] Levin A., Hakala T. A., Schnaider L., Bernardes G. J. L., Gazit E., Knowles T. P. J., Nat. Rev. Chem., 2020, 4, 615
[49] Jiang Y., Zhang W., Yang F., Wan C., Cai X., Liu J., Zhang Q., Li Z., Han W., Sci. Adv., 2021, 7, eabd0492
[50] So C. R., Hayamizu Y., Yazici H., Gresswell C., Khatayevich D., Tamerler C., Sarikaya M., ACS Nano, 2012, 6, 1648
[51] Nalbach M., Raiteri P., Klassen S., Schäfer S., Gale J. D., Bechstein R., Kühnle A., J. Phys. Chem. C, 2017, 121, 24144
[52] Fu C., Lin H., Macleod J. M., Krayev A., Rosei F., Perepichka D. F., Chem. Mater., 2016, 28, 951
[53] Liu L., Li Q., Zhang S., Wang X., Hoffmann S. V., Li J., Liu Z., Besenbacher F., Dong, M., Adv. Sci., 2016, 3, 1500369
[54] Chen J., Zhu E., Liu J., Zhang S., Lin Z., Duan X., Heinz H., Huang Y., Yoreo J. J., Science, 2018, 362, 1135
[55] Wang W., Zhang M., Pan Z., Biesold G. M., Liang S., Rao H., Lin Z., Zhong X., Chem. Rev., 2022, 122, 4091
[56] Kudera S., Zanella M., Giannini C., Rizzo A., Li Y., Gigli G., Cingolani R., Ciccarella G., Spahl W., Parak W. J., Manna L., Adv. Mater., 2007, 19, 548
[57] Baletto F., Ferrando R., Rev. Mod. Phys., 2005, 77, 371
[58] Song Y. F., Tsunashima R., Chem. Soc. Rev., 2012, 41, 7384
[59] Wang S., Yang G., Chem. Rev., 2015, 115, 4893
[60] Bootharaju M. S., Baek W., Lee S., Chang H., Kim J., Hyeon T., Small, 2021, 17, e2002067
[61] Singh V., Priyanka More P. V., Hemmer E., Mishra Y. K., Khanna P. K., Mater. Adv., 2021, 2, 1204
[62] Fojtik A., Weller H., Koch U., Henglein A., Phys. Chem., 1984, 88, 969
[63] Peng Z. A., Peng X. G., J. Am. Chem. Soc., 2002, 124, 3343
[64] Yu Q., Liu C., J. Phys. Chem. C, 2009, 113, 12766
[65] Soloviev V. N., Eichhofer A., Fenske D., Banin U., J. Am. Chem. Soc., 2000, 122, 2673
[66] Yang J., Fainblat R., Kwon S. G., Muckel F., Yu J. H., Terlinden H., Kim B. H., Lavarone D., Choi M. K., Kim I. Y., Park I., Hong H. K., Lee J., Son J. S., Lee Z., Kang K., Hwang S. J., Bacher G., Hyeon T., J. Am. Chem. Soc., 2015, 137, 12776
[67] Kwon Y., Oh J., Lee E., Lee S. H., Agnes A., Bang G., Kim J., Kim D., Kim S., Nat. Commun., 2020, 11, 3127
[68] Cao Y., Guo J., Shi R., Waterhouse G. I. N., Pan J., Du Z., Yao Q., Wu L. Z., Tung C. H., Xie J., Zhang T., Nat. Commun., 2018, 9, 2379
[69] Fu H., Yang D., Qiu D., Yan C. H., Cai R., Du Y., Tan W., J. Phys. Chem. Lett., 2022, 13, 1855
[70] Harrell S. M., McBride J. R., Rosenthal S. J., Chem. Mater., 2013, 25, 1199
[71] Joo J., Son J. S., Kwon S. G., Yu J. H., Hyeon T., J. Am. Chem. Soc., 2006, 128, 5632
[72] Son J. S., Wen X. D., Joo J., Chae J., Baek S. I., Park K., Kim J. H., An K., Yu J. H., Kwon S. G., Choi S. H., Wang Z., Kim Y. W., Kuk Y., Hoffmann R., Hyeon T., Angew. Chem. Int. Ed., 2009, 48, 6861
[73] Liu Y. H., Wayman V. L., Gibbons P. C., Loomis R. A., Buhro W. E., Nano Lett., 2010, 10, 352
[74] Ithurria S., Bousquet G., Dubertret B., J. Am. Chem. Soc., 2011, 133, 3070
[75] Liu Y. H., Wang F., Wang Y., Gibbons P. C., Buhro W. E., J. Am. Chem. Soc., 2011, 133, 17005
[76] Wang Y., Liu Y. H., Zhang Y., Wang F., Kowalski P. J., Rohrs H. W., Loomis R. A., Gross M. L., Buhro W. E., Angew. Chem. Int. Ed., 2012, 51, 6154
[77] Wang Y., Zhang Y., Wang F., Giblin D. E., Hoy J., Rohrs H. W., Loomis R. A., Buhro W. E., Chem. Mater., 2014, 26, 2233
[78] Wang Y., Zhou Y., Zhang Y., Buhro W. E., Inorg. Chem., 2015, 54, 1165
[79] Yang J., Muckel F., Baek W., Fainblat R., Chang H., Bacher G., Hyeon T., J. Am. Chem. Soc., 2017, 139, 6761
[80] Berends A. C., de Mello Donega C., J. Phys. Chem. Lett., 2017, 8, 4077
[81] Busatto S., De Mello Donega C., ACS Mater. Au, 2022, 2, 237
[82] Nevers D. R., Williamson C. B., Savitzky B. H., Hadar I., Banin U., Kourkoutis L. F., Hanrath T., Robinson R. D., J. Am. Chem. Soc., 2018, 140, 3652
[83] Han H., Kallakuri S., Yao Y., Williamson C. B., Nevers D. R., Savitzky B. H., Skye R. S., Xu M., Voznyy O., Dshemuchadse J., Kourkoutis L. F., Weinstein S. J., Hanrath T., Robinson R. D., Nat. Mater., 2022, 21, 518
[84] Busatto S., Spallacci C., Meeldijk J. D., Howes S., de Mello Donega C., J. Phys. Chem. C, 2022, 126, 15280
[85] Gumerova N. I., Rompel A., Nat. Rev. Chem., 2018, 2, 0112
[86] Cheng X., Zhang S., Wang X., Nano Lett., 2021, 21, 9845
[87] Liu J., Shi W., Ni B., Yang Y., Li S., Zhuang J., Wang X., Nat. Chem., 2019, 11, 839
[88] Horn M. R., Singh A., Alomari S., Goberna-Ferrón S., Benages-Vilau R., Chodankar N., Motta N., Ostrikov K., MacLeod J., Sonar P., Gomez-Romero P., Dubal D., Energy Environ. Sci., 2021, 14, 1652
[89] Zhang S., Shi W., Siegler T. D., Gao X., Ge F., Korgel B. A., He Y., Li S., Wang X., Angew. Chem. Int. Ed., 2019, 58, 8730
[90] Liu Q., Wang X., Angew. Chem. Int. Ed., 2023, 62, e202217764
[91] Zhang S., Shi W., Rong S., Li S., Zhuang J., Wang X., J. Am. Chem. Soc., 2020, 142, 1375
[92] Zhang S., Wang X., Acc. Chem. Res., 2022, 3, 1285
[93] Lu Q., Huang B., Zhang Q., Chen S., Gu L., Song L., Yang Y., Wang X., J. Am. Chem. Soc., 2021, 143, 9858
[94] Liu Q., Zhang Q., Shi W., Hu H., Zhuang J., Wang X., Nat. Chem., 2022, 14, 433
[95] Zhang S., Shi W., Wang X., Science, 2022, 377, 100
[96] Zhang S., Lu Q., Yu B., Cheng X., Zhuang J., Wang X., Adv. Funct. Mater., 2021, 31, 2100703
[97] Zhang S., Liu N., Wang H., Lu Q., Shi W., Wang X., Adv. Mater., 2021, 33, e2100576
[98] Yang H., Yang D., Wang X., Angew. Chem. Int. Ed., 2020, 59, 15527
[99] Liu J., Shi W., Wang X., J. Am. Chem. Soc., 2021, 143, 16217
[100] Liu Q., He S., Yu B., Cheng X., Shi W., Wang X., Adv. Mater., 2022, 34, e2206178
[101] Liu J., Wang S., Liu N., Yang D., Wang H., Hu H., Zhuang J., Wang X., Small, 2021, 17, e2006260
[102] Yang D., Zuo S., Yang H., Wang X., Adv. Energy Mater., 2021, 11, 2100272
[103] Schaaff T. G., Shafigullin M. N., Khoury J. T., Vezmar I., Whetten R. L., Cullen W. G., First P. N., J. Phys. Chem. B, 1997, 101, 7885
[104] Xie Y., Shen Y., Duan G., Han J., Zhang L., Lu X., Mater. Chem. Front., 2020, 4, 2205
[105] Kwon Y., Kim S., NPG Asia Mater., 2021, 13, 37
[106] Ning J., Banin U., Chem. Commun., 2017, 53, 2626
[107] Sadeghi O., Zakharov L. N., Nyman M., Science, 2015, 347, 1359
[108] George E. P., Raabe D., Ritchie R. O., Nat. Rev. Mater., 2019, 4, 515
[109] Oses C., Toher C., Curtarolo S., Nat. Rev. Mater., 2020, 5, 295
[110] Liu J., Li Y., Chen Z., Liu N., Zheng L., Shi W., Wang X., J. Am. Chem. Soc., 2022, 144, 23191
[111] Elimelech O., Oded M., Harries D., Banin U., ACS Nano, 2023, 17, 5852
[112] Tully R. B., Courtois H., Hoffman Y., Pomarede D., Nature, 2014, 513, 71

Nanoclusters as Synthons for Unit-Cell-Size Comparable One-Dimensional Nanostructures

Nanoclusters as Synthons for Unit-Cell-Size Comparable One-Dimensional Nanostructures

可视化

摘要/Abstract

引用本文

使用本文

参考文献

相关文章 15

编辑推荐

Metrics

本文评价

[1]	LIU Junli, NIE Siyang, WU Liang, WANG Xun. High-entropy Metal Oxide-polyoxometalate-palladium Sub-1 nm Nanowires for Semi-hydrogenation Reaction of Alkynes[J]. 高等学校化学研究, 2023, 39(4): 624-629.
[2]	HUANG Xinjie, WANG Ziru, WANG Tian, WANG Wei, HE Peilei. Fe-substituted Polyoxometalate-based Spherical Assemblies as Catalysts for Olefin Epoxidation[J]. 高等学校化学研究, 2023, 39(4): 660-665.
[3]	LIU Xiaodong, WANG Xiangchen, XU Na, ZHANG Zhong, LI Xiaohui, LIU Guocheng, WANG Xiuli. A Multifunctional {P₂Mo₅}-based Hybrid Applying to Catalysis, Electrocatalysis and Dye Adsorption[J]. 高等学校化学研究, 2022, 38(6): 1553-1560.
[4]	CEN Qing, XIAO Wei, LIU Yingqi, WANG Qi, NAFADY Ayman, MA Shengqian. Fabrication of Fe-POMs as Visible-light-active Heterogeneous Photocatalyst[J]. 高等学校化学研究, 2020, 36(6): 1128-1135.
[5]	DONG Pengfei, LI Na, ZHAO Haiyan, CUI Min, ZHANG Cong, HAN Hongyan, REN Jujie. POMs as Active Center for Sensitively Electrochemical Detection of Bisphenol A and Acetaminophen[J]. 高等学校化学研究, 2019, 35(4): 592-597.
[6]	WANG Shuo, GAO Yu, SU Xiaofang, YAN Likai. Exploration on Charge Transfer and Absorption Spectra of Spiro[fluorene-9,90-xanthene]-based Polyoxometalate Hybrids Toward High Performance Dye-sensitized Solar Cell[J]. 高等学校化学研究, 2018, 34(5): 767-771.
[7]	SONG Jiangfeng, WANG Jun, ZHOU Ruisha, CUI Xiaobing. A New Inorganic 2D Framework Based on Bi-bismuth-capping Keggin Polyoxometalate with Photodegradation and Selective Absorption of Organic Dyes[J]. 高等学校化学研究, 2017, 33(3): 333-338.
[8]	WANG Xiang, LIN Lin, LIN Hongyan, LIU Guocheng. Syntheses, Structure and Properties of a 3d-4d/2-ptz Heterometallic Organic Chain-modified POM-based Framework[J]. 高等学校化学研究, 2017, 33(1): 7-11.
[9]	GAI Beibei, HE Hui, ZHAO Yanhui, MAO Zhu, FU Hai. Ionothermal Synthesis and Characterization of Two Polyoxometalate-based Supramolecules[J]. 高等学校化学研究, 2016, 32(4): 527-529.
[10]	WANG Xiuli, LIU Danna, HAN Na, LIN Hongyan, LUAN Jian, TIAN Aixiang. Two New Inorganic-organic Hybrid Compounds Constructed from Different Polymolybdates and Transition Metal-amine Subunits[J]. 高等学校化学研究, 2015, 31(3): 337-341.
[11]	DUAN Weijie, JIAO Shihui, LIU Xu, CHEN Jinlei, CAO Xuan, CHEN Yan, XU Wei, CUI Xiaobing, XU Jiqing, PANG Guangsheng. Two New Supramolecular Hybrids Based on Bi-capped Keggin {PMo₁₂V₂O₄₂} Clusters and Transition Metal Mixed-organic-ligand Complexes[J]. 高等学校化学研究, 2015, 31(2): 179-186.
[12]	LIU Yabing, DUAN Weijie, CUI Xiaobing, XU Jiqing. Hydrothermal Syntheses and Characterization of Two 1D Chain Complexes and Tetra-capped Keggin Clusters[J]. 高等学校化学研究, 2015, 31(1): 4-8.
[13]	ZHOU Yunshan, QU Ningning, WANG Xuan, ZHANG Lijuan, SHI Zonghai, HASSAN ul Sadaf. Third-order Optical Nonlinearities of a Series of Compounds Derived from a Keplerate Type Molybdenum-oxide-based Polyoxometalate[J]. 高等学校化学研究, 2014, 30(5): 715-719.
[14]	KONG Da-liang, WEI Bo, ZHOU Sheng-yan, YANG Hai-shan, JIANG Yang. Volume-related Efficiency of Gadolinium Polyoxometalates as MRI Contrast Agents[J]. 高等学校化学研究, 2013, 29(6): 1055-1058.
[15]	HU Xi-yu, CHEN Bing-nian, WANG Li, CHEN Fa-he. Inhibition of α/β-K₆P₂W₁₈O₆₂·10H₂O on the Activity of Mushroom Tyrosinase and Its Antimicrobial Effects[J]. 高等学校化学研究, 2012, 28(5): 862-865 .