Adsorption and Visible Light Photocatalytic Degradation of Electrospun PAN@W18O49 Nanofibers

doi:10.1007/s40242-020-0357-y

高等学校化学研究 ›› 2021, Vol. 37 ›› Issue (3): 428-435.doi: 10.1007/s40242-020-0357-y

Adsorption and Visible Light Photocatalytic Degradation of Electrospun PAN@W₁₈O₄₉ Nanofibers

MA Yuying¹, HE Dayong¹, LIU Jiadi², WANG Yuannan¹, YANG Mei¹, WANG Hao¹, QIU Ju¹, LI Wenyan¹, LI Yongxin³, WANG Ce¹

1. Alan G. MacDiarmid Institute, College of Chemistry, Jilin University, Changchun 130012, P. R. China;
2. College of Plant Science, Jilin University, Changchun 130062, P. R. China;
3. College of New Energy and Environment, Jilin University, Changchun 130021, P. R. China

收稿日期:2020-11-02 修回日期:2020-12-02 出版日期:2021-06-01 发布日期:2021-05-31
通讯作者: WANG Ce E-mail:cwang@jlu.edu.cn
基金资助:
This work was supported by the National Natural Science Foundation of China (No.21875084) and the Fund of the Development and Reform Commission of Jilin Province, China(No.2020C023-5).

Adsorption and Visible Light Photocatalytic Degradation of Electrospun PAN@W₁₈O₄₉ Nanofibers

MA Yuying¹, HE Dayong¹, LIU Jiadi², WANG Yuannan¹, YANG Mei¹, WANG Hao¹, QIU Ju¹, LI Wenyan¹, LI Yongxin³, WANG Ce¹

1. Alan G. MacDiarmid Institute, College of Chemistry, Jilin University, Changchun 130012, P. R. China;
2. College of Plant Science, Jilin University, Changchun 130062, P. R. China;
3. College of New Energy and Environment, Jilin University, Changchun 130021, P. R. China

Received:2020-11-02 Revised:2020-12-02 Online:2021-06-01 Published:2021-05-31
Contact: WANG Ce E-mail:cwang@jlu.edu.cn
Supported by:
This work was supported by the National Natural Science Foundation of China (No.21875084) and the Fund of the Development and Reform Commission of Jilin Province, China(No.2020C023-5).

摘要/Abstract

摘要： Low density and high porosity polyacrylonitrile(PAN) nanofibers prepared by electrospinning were used as brackets for photocatalyst W₁₈O₄₉ to prepare a kind of light weight and easy recycling water purification material for the first time. The influence of tungsten source concentration on the formation of W₁₈O₄₉ during a solvothermal process was systematically investigated. The prepared PAN@W₁₈O₄₉ nanofibers(NFs) utilize the outstanding visible light photocatalytic performance and the adsorption performance of W₁₈O₄₉, and at the same time give the advantages of low density and easy recyclability. The pollutant removal performance of the composite nanofibers was investigated by using five contaminants including rhodamine B(RhB), methylene blue(MB), malachite green(MG), methyl orange(MO) and chlortetracycline(CTC) as substrates. Among them, the degradation process of rhodamine B has been studied in detail. After five cycles, the degradation efficiency did not decrease significantly, showing excellent reusability of PAN@W₁₈O₄₉ NFs. Besides, the adsorption performance of PAN@W₁₈O₄₉ NFs during the photocatalytic process was also studied in detail. Compared with recently reported literature, the degradation efficiency of organic pollutants by PAN@W₁₈O₄₉ NFs showed better performance, and PAN@W₁₈O₄₉ NFs felt had a promising prospect in the field of degradation of contaminants.

关键词: Photocatalysis, Adsorption, Electrospinning, Solvothermal reaction, Dye degradation

Abstract: Low density and high porosity polyacrylonitrile(PAN) nanofibers prepared by electrospinning were used as brackets for photocatalyst W₁₈O₄₉ to prepare a kind of light weight and easy recycling water purification material for the first time. The influence of tungsten source concentration on the formation of W₁₈O₄₉ during a solvothermal process was systematically investigated. The prepared PAN@W₁₈O₄₉ nanofibers(NFs) utilize the outstanding visible light photocatalytic performance and the adsorption performance of W₁₈O₄₉, and at the same time give the advantages of low density and easy recyclability. The pollutant removal performance of the composite nanofibers was investigated by using five contaminants including rhodamine B(RhB), methylene blue(MB), malachite green(MG), methyl orange(MO) and chlortetracycline(CTC) as substrates. Among them, the degradation process of rhodamine B has been studied in detail. After five cycles, the degradation efficiency did not decrease significantly, showing excellent reusability of PAN@W₁₈O₄₉ NFs. Besides, the adsorption performance of PAN@W₁₈O₄₉ NFs during the photocatalytic process was also studied in detail. Compared with recently reported literature, the degradation efficiency of organic pollutants by PAN@W₁₈O₄₉ NFs showed better performance, and PAN@W₁₈O₄₉ NFs felt had a promising prospect in the field of degradation of contaminants.

Key words: Photocatalysis, Adsorption, Electrospinning, Solvothermal reaction, Dye degradation

MA Yuying, HE Dayong, LIU Jiadi, WANG Yuannan, YANG Mei, WANG Hao, QIU Ju, LI Wenyan, LI Yongxin, WANG Ce. Adsorption and Visible Light Photocatalytic Degradation of Electrospun PAN@W₁₈O₄₉ Nanofibers[J]. 高等学校化学研究, 2021, 37(3): 428-435.

参考文献 48

[1]	Liu J., Wei Y., Li P., Zhao Y., Zou R., The Journal of Physical Chemistry C, 2017, 121(24), 13249
[2]	Le-Clech P., Chen V., Fane T. A. G., Journal of Membrane Science, 2006, 284(1/2), 17
[3]	Hunge Y. M., Yadav A. A., Mathe V. L., Journal of Materials Science:Materials in Electronics, 2018, 29(8), 6183
[4]	Najem M., Nada A. A., Weber M., Sayegh S., Razzouk A., Salameh C., Eid C., Bechelany M., Materials(Basel), 2020, 13(8)
[5]	Pereira R. A., Pereira M. F. R., Alves M. M., Pereira L., Applied Catalysis B:Environmental, 2014, 144, 713
[6]	Wang J., Li H. B., Li A. M., Shuang C. D., Zhou Q., Chem. Eng. J., 2014, 253, 237
[7]	Sridewi N., Lee Y.-F., Sudesh K., International Journal of Photoenergy, 2011, 2011, 1
[8]	Ranjith K. S., Satilmis B., Uyar T., Mater. Today, 2018, 21(9), 989
[9]	Du F., Sun L., Huang Z., Chen Z., Xu Z., Ruan G., Zhao C., Chemosphere, 2020, 239, 124764
[10]	Choi H. G., Jung Y. H., Kim D. K., J. Am. Ceram. Soc., 2005, 88(6), 1684
[11]	Lee K., Seo W. S., Park J. T., J. Am. Chem. Soc., 2003, 125(12), 3408
[12]	Guo C. S., Yin S., Yan M., Kobayashi M., Kakihana M., Sato T., Inorg. Chem., 2012, 51(8), 4763
[13]	Chen X. B., Liu L., Yu P. Y., Mao S. S., Science, 2011, 331(6018), 746
[14]	Bai H., Yi W. C., Liu J. Y., Lv Q., Zhang Q., Ma Q., Yang H. F., Xi G. C., Nanoscale, 2016, 8(28), 13545
[15]	Jia C. C., Zhang X., Matras-Postolek K., Huang B. B., Yang P., Carbon, 2018, 139, 415
[16]	Huang Z. F., Song J. J., Pan L., Lv F. L., Wang Q. F., Zou J. J., Zhang X. W., Wang L., Chem. Commun., 2014, 50(75), 10959
[17]	Bai H., Su N., Li W. T., Zhang X., Yan Y., Li P., Ouyang S. X., Ye J. H., Xi G. C., Journal of Materials Chemistry A, 2013, 1(20), 6125
[18]	Sun S. B., Chang X. T., Dong L. H., Zhang Y. D., Li Z. J., Qiu Y. Y., J. Solid State Chem., 2011, 184(8), 2190
[19]	Xu M., Jia S., Li H., Zhang Z., Guo Y., Chen C., Chen S., Yan J., Zhao W., Yun J., Mater. Lett., 2018, 230, 224
[20]	Shang J., Li W., Zhu Y., J. Mol. Catal. A:Chem., 2003, 202(1/2), 187
[21]	Im J. S., Kim M. I., Lee Y.-S., Mater. Lett., 2008, 62(21/22), 3652
[22]	Shah A. P., Jain S., Mokale V. J., Shimpi N. G., Journal of Industrial and Engineering Chemistry, 2019, 77, 154
[23]	Abdel-Mottaleb M. M., Khalil A., Osman T. A., Khattab A., J. Mech. Behav. Biomed. Mater., 2019, 98, 205
[24]	Barhoum A., Pal K., Rahier H., Uludag H., Kim I. S., Bechelany M., Applied Materials Today, 2019, 17, 1
[25]	Li H., Zhu Y., Cao H., Yang X., Li C., Mater. Res. Bull., 2013, 48(2), 232
[26]	Pascariu P., Airinei A., Olaru N., Olaru L., Nica V., Ceram. Int., 2016, 42(6), 6775
[27]	Tao R., Shao C., Li X., Li X., Liu S., Yang S., Zhao C., Liu Y., J. Colloid Interface Sci., 2018, 529, 404
[28]	Guo X., Dong X., Wang J., Yu W., Liu G., Chem. Eng. J., 2014, 250, 148
[29]	Wang X. X., Zhou X. J., Shao C. L., Li X. H., Liu Y. C., Appl. Surf. Sci., 2018, 455, 952
[30]	Liu D., Li G., Zhao C., Wang X., Sun M., Sun X., Yan M., Guo C., Journal of Materials Science:Materials in Electronics, 2018, 29(17), 15029
[31]	Hai G., Huang J., Cao L., Jie Y., Li J., Wang X., Zhang G., J. Alloys Compd., 2017, 690, 239
[32]	Tian Y. Y., Cong S., Su W. M., Chen H. Y., Li Q. W., Geng F. X., Zhao Z. G., Nano Lett., 2014, 14(4), 2150
[33]	Lv Y., Zhu Y., Zhu Y., The Journal of Physical Chemistry C, 2013, 117(36), 18520
[34]	Xi G., Ouyang S., Li P., Ye J., Ma Q., Su N., Bai H., Wang C., Angew. Chem. Int. Ed. Engl., 2012, 51(10), 2395
[35]	Li X., Yang S., Sun J., He P., Xu X., Ding G., Carbon, 2014, 78, 38
[36]	Yang L. F., Yang Y. J., Liu T. Y., Ma X. L., Lee S. W., Wang Y. H., New J. Chem., 2018, 42(18), 15253
[37]	Makula P., Pacia M., Macyk W., J. Phys. Chem. Lett., 2018, 9(23), 6814
[38]	Xiao L., Li G., Chu X., Yan G., Materials Research Express, 2019, 6(11), 115904
[39]	Liu J., Hui Q., Chang M.-J., Cui W.-N., Xi T., Wang L.-D., Sun M., Yuan B., Ni F.-R., Journal of Materials Science:Materials in Electronics, 2020, 31, 17688
[40]	Fakharian-Qomi M. J., Sadeghzadeh-Attar A., ChemistrySelect, 2020, 5(20), 6001
[41]	Panthi G., Gyawali K. R., Park M., Nanomaterials(Basel), 2020, 10(5), 929
[42]	Panthi G., Kwon O. H., Kuk Y.-S., Gyawali K. R., Park Y. W., Park M., Catalysts, 2020, 10(3), 348
[43]	Ren J., Zhu Y., RSC Advances, 2020, 10(10), 6114
[44]	Chang M.-J., Cui W.-N., Liu J., Wang K., Du H.-L., Qiu L., Fan S.-M., Luo Z.-M., Journal of Materials Science & Technology, 2020, 36, 97
[45]	Chang M.-J., Cui W.-N., Wang H., Liu J., Li H.-L., Du H.-L., Peng L.-G., Colloids and Surfaces A:Physicochemical and Engineering Aspects, 2019, 562, 127
[46]	Wang X., Zhou X., Shao C., Li X., Liu Y., Applied Surface Science, 2018, 455, 952
[47]	Zhao R., Li X., Sun B. L., Li Y. Z., Li Y. M., Yang R., Wang C., Journal of Materials Chemistry A, 2017, 5(3), 1133
[48]	Song W., Zhao B., Wang C., Ozaki Y., Lu X., Journal of Materials Chemistry B, 2019, 7(6), 850

Adsorption and Visible Light Photocatalytic Degradation of Electrospun PAN@W₁₈O₄₉ Nanofibers

Adsorption and Visible Light Photocatalytic Degradation of Electrospun PAN@W₁₈O₄₉ Nanofibers

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