Sequential Extraction of Natural Surface Coatings: Comparison with Single Stage Extraction and Its Application in Investigating Adsorption Characteristics of Surface Coating Components for Metals

高等学校化学研究 ›› 2012, Vol. 28 ›› Issue (1): 41-46.

Sequential Extraction of Natural Surface Coatings: Comparison with Single Stage Extraction and Its Application in Investigating Adsorption Characteristics of Surface Coating Components for Metals

HUA Xiu-yi, LIU Xiao-xue, DONG De-ming*, LI Ming, LI Yao-rui

Key Laboratory of Groundwater Resources and Environment, Ministry of Education, Key Lab of Water Resources and Aquatic Environment of Jilin Province, College of Environment and Resources, Jilin University, Changchun 130012, P. R. China

收稿日期:2011-07-11 修回日期:2011-09-23 出版日期:2012-01-25 发布日期:2011-12-27
基金资助:
Supported by the National Natural Science Foundation of China(No.20877033) and the Major Science and Technology Program for Water Pollution Control and Treatment, China(No.2009ZX07207-001-03).

Sequential Extraction of Natural Surface Coatings: Comparison with Single Stage Extraction and Its Application in Investigating Adsorption Characteristics of Surface Coating Components for Metals

HUA Xiu-yi, LIU Xiao-xue, DONG De-ming*, LI Ming, LI Yao-rui

Key Laboratory of Groundwater Resources and Environment, Ministry of Education, Key Lab of Water Resources and Aquatic Environment of Jilin Province, College of Environment and Resources, Jilin University, Changchun 130012, P. R. China

Received:2011-07-11 Revised:2011-09-23 Online:2012-01-25 Published:2011-12-27
Supported by:
Supported by the National Natural Science Foundation of China(No.20877033) and the Major Science and Technology Program for Water Pollution Control and Treatment, China(No.2009ZX07207-001-03).

摘要/Abstract

摘要： Multistage sequential extraction with different sequences was applied to extracting natural surface coatings( NSCs), and the results were compared with those by single stage extraction technique. The optimal sequential extraction scheme with the best performance was selected and incorporated into the method of selective extraction followed by adsorption and statistic analyses to study the adsorption parameters of Fe oxides, Mn oxides and organic matters in NSCs for Pb and Cd, to validate the applicability of the sequential extraction scheme. The Langmuir adsorption parameters of each component of surface coating estimated according to the adsorption data of single stage extraction of NSCs were all similar to those of sequential extraction of NSCs, and the maximum difference between the metal adsorption abilities of the components estimated via the two extraction techniques was only about 20%, indicating that either extraction techniques could be used. The optimal sequential extraction scheme obtained was first extracted with NH₂OH·HCl, then with Na₂S₂O₄, and finally with oxalic acid.

关键词: Natural surface coating(NSC), Sequential extraction, Single stage extraction, Adsorption, Component

Abstract: Multistage sequential extraction with different sequences was applied to extracting natural surface coatings( NSCs), and the results were compared with those by single stage extraction technique. The optimal sequential extraction scheme with the best performance was selected and incorporated into the method of selective extraction followed by adsorption and statistic analyses to study the adsorption parameters of Fe oxides, Mn oxides and organic matters in NSCs for Pb and Cd, to validate the applicability of the sequential extraction scheme. The Langmuir adsorption parameters of each component of surface coating estimated according to the adsorption data of single stage extraction of NSCs were all similar to those of sequential extraction of NSCs, and the maximum difference between the metal adsorption abilities of the components estimated via the two extraction techniques was only about 20%, indicating that either extraction techniques could be used. The optimal sequential extraction scheme obtained was first extracted with NH₂OH·HCl, then with Na₂S₂O₄, and finally with oxalic acid.

Key words: Natural surface coating(NSC), Sequential extraction, Single stage extraction, Adsorption, Component

HUA Xiu-yi, LIU Xiao-xue, DONG De-ming, LI Ming, LI Yao-rui. Sequential Extraction of Natural Surface Coatings: Comparison with Single Stage Extraction and Its Application in Investigating Adsorption Characteristics of Surface Coating Components for Metals[J]. 高等学校化学研究, 2012, 28(1): 41-46.

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Sequential Extraction of Natural Surface Coatings: Comparison with Single Stage Extraction and Its Application in Investigating Adsorption Characteristics of Surface Coating Components for Metals

Sequential Extraction of Natural Surface Coatings: Comparison with Single Stage Extraction and Its Application in Investigating Adsorption Characteristics of Surface Coating Components for Metals

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