Crystal Structure and Third order Nonlinear Optical Properties of cis-Configuration Biferrocene Trinuclear Complexes

高等学校化学研究 ›› 1999, Vol. 15 ›› Issue (3): 218-225.

Crystal Structure and Third order Nonlinear Optical Properties of cis-Configuration Biferrocene Trinuclear Complexes

WU Jie-ying, TIAN Yu-peng, XIE Fu-xin, NI Shi-sheng

Department of Chemistry, Anhui University, Hefei 230039, P. R. China

收稿日期:1998-10-06 出版日期:1999-08-24 发布日期:2011-08-17
通讯作者: TIAN Yu-peng
基金资助:
Supported by the NationalNatural Science Foundation of China,Natural Science Foundation of Anhui Province and Foundation of State Key Laboratory of Coordination Chemistry of Nanjing University.

Crystal Structure and Third order Nonlinear Optical Properties of cis-Configuration Biferrocene Trinuclear Complexes

WU Jie-ying, TIAN Yu-peng, XIE Fu-xin, NI Shi-sheng

Department of Chemistry, Anhui University, Hefei 230039, P. R. China

Received:1998-10-06 Online:1999-08-24 Published:2011-08-17
Supported by:
Supported by the NationalNatural Science Foundation of China,Natural Science Foundation of Anhui Province and Foundation of State Key Laboratory of Coordination Chemistry of Nanjing University.

摘要/Abstract

摘要： The syntheses and characterization of novel biferrocene trinuclear complexes of Schiff base ligand, S-methyl-N-(ferrocenyl-1-methyl methylidene)dithiocarbazate [hereafter abbreviated as HL (1)], are described. The X-ray diffraction studies have established the structures of PdL₂(3) and CuL₂ (4). The geometry of Pd(Ⅱ) in (3) is close to a square plane and in the novel cis-configuration the two ferrocene moieties are in cis configuration, while that of Cu(Ⅱ) in (4) is close to a tetrahedral configuration. The electrochemical measurements suggested that the square planar configuration of Ni(Ⅱ) and Pd(Ⅱ) moieties can effectively transmit the redox effects of the ferrocene moieties, while the tetrahedral configuration of the Cu(Ⅱ) complex can not transmit the redox effects. The degenerate four wave mixing (DFWM) measurements showed that the complexes exhibit obviously nonlinear optical (NLO) response. The magnitude of their third order NLO susceptibility can be explained by their structure and electrochemical properties.

关键词: Electrochemistry, cis-Configuration biferrocene, Third-order nonlinear optical property

Abstract: The syntheses and characterization of novel biferrocene trinuclear complexes of Schiff base ligand, S-methyl-N-(ferrocenyl-1-methyl methylidene)dithiocarbazate [hereafter abbreviated as HL (1)], are described. The X-ray diffraction studies have established the structures of PdL₂(3) and CuL₂ (4). The geometry of Pd(Ⅱ) in (3) is close to a square plane and in the novel cis-configuration the two ferrocene moieties are in cis configuration, while that of Cu(Ⅱ) in (4) is close to a tetrahedral configuration. The electrochemical measurements suggested that the square planar configuration of Ni(Ⅱ) and Pd(Ⅱ) moieties can effectively transmit the redox effects of the ferrocene moieties, while the tetrahedral configuration of the Cu(Ⅱ) complex can not transmit the redox effects. The degenerate four wave mixing (DFWM) measurements showed that the complexes exhibit obviously nonlinear optical (NLO) response. The magnitude of their third order NLO susceptibility can be explained by their structure and electrochemical properties.

Key words: Electrochemistry, cis-Configuration biferrocene, Third-order nonlinear optical property

WU Jie-ying, TIAN Yu-peng, XIE Fu-xin, NI Shi-sheng . Crystal Structure and Third order Nonlinear Optical Properties of cis-Configuration Biferrocene Trinuclear Complexes[J]. 高等学校化学研究, 1999, 15(3): 218-225.

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Crystal Structure and Third order Nonlinear Optical Properties of cis-Configuration Biferrocene Trinuclear Complexes

Crystal Structure and Third order Nonlinear Optical Properties of cis-Configuration Biferrocene Trinuclear Complexes

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