Preparation, Characterization, Luminescent and Electrochemical Properties of Ru(bpy)2-functionalized Silica Nanoparticles

doi:10.1007/s40242-016-6090-x

高等学校化学研究 ›› 2016, Vol. 32 ›› Issue (4): 695-701.doi: 10.1007/s40242-016-6090-x

Preparation, Characterization, Luminescent and Electrochemical Properties of Ru(bpy)₂-functionalized Silica Nanoparticles

HUANG Hongxiang¹, HE Wenli², MA Yueyang²

1. State Key Laboratory of Molecular Engineering of Polymer, Department of Macromolecular Science, Fudan University, Shanghai 200433, P. R. China;
2. Department of Chemistry, Fudan University, Shanghai 200433, P. R. China

收稿日期:2016-03-11 修回日期:2016-06-06 出版日期:2016-08-01 发布日期:2016-06-20
通讯作者: HUANG Hongxiang E-mail:hxhuang@fudan.edu.cn
基金资助:
Supported by the National Natural Science Foundation of China(No.21373058).

Preparation, Characterization, Luminescent and Electrochemical Properties of Ru(bpy)₂-functionalized Silica Nanoparticles

HUANG Hongxiang¹, HE Wenli², MA Yueyang²

1. State Key Laboratory of Molecular Engineering of Polymer, Department of Macromolecular Science, Fudan University, Shanghai 200433, P. R. China;
2. Department of Chemistry, Fudan University, Shanghai 200433, P. R. China

Received:2016-03-11 Revised:2016-06-06 Online:2016-08-01 Published:2016-06-20
Contact: HUANG Hongxiang E-mail:hxhuang@fudan.edu.cn
Supported by:
Supported by the National Natural Science Foundation of China(No.21373058).

摘要/Abstract

摘要：

Ru(II)-complex functionalized silica nanoparticles(nano-SiO₂) were prepared via a coordination reaction of cis-dichlorobis(2,2'-bipyridine)ruthenium[Ru(bpy)₂Cl₂] complex with poly(4-vinylpyridine)(P4VP)-modified nano-SiO₂ particles. Both the Ru-complex and the functionalized nano-SiO₂P4VP-Ru(bpy) hybrids were doped in poly(methyl methacrylate)(PMMA) to form optically transparent thin films. The composition and spectroscopic properties of the nano-SiO₂P4VP-Ru(bpy) hybrids were evaluated with the help of thermogravimetric and elemental analysis, and UV-Vis absorption spectroscopy, infrared spectroscopy, X-ray photoelectron spectroscopy, and fluorescence spectroscopy. Microscopy images revealed that the nanohybrids were approximately 12 nm in diameter and readily formed aggregates following the functionalization with P4VP and Ru(bpy)₂Cl₂. The as-prepared nano-SiO₂P4VP-Ru(bpy) hybrids produced emissions at approximately 604 and 654 nm under radiation both in solution and in doped thin films. Finally, cyclic voltammetry studies on the nanohybrid-modified electrode revealed a redox couple with the cathodic and anodic potentials at approximately 0.28 and 0.73 V(vs. Ag/AgCl), attributed to the one electron transfer of Ru(bpy)₂^2+/3+ immobilized on the nano-SiO₂ particles.

关键词: Doped poly(methyl methacrylate)(PMMA) film, Electrochemistry, Fluorescence, Ru complex, Silica nanohybrid

Abstract:

Key words: Doped poly(methyl methacrylate)(PMMA) film, Electrochemistry, Fluorescence, Ru complex, Silica nanohybrid

HUANG Hongxiang, HE Wenli, MA Yueyang. Preparation, Characterization, Luminescent and Electrochemical Properties of Ru(bpy)₂-functionalized Silica Nanoparticles[J]. 高等学校化学研究, 2016, 32(4): 695-701.

HUANG Hongxiang, HE Wenli, MA Yueyang. Preparation, Characterization, Luminescent and Electrochemical Properties of Ru(bpy)₂-functionalized Silica Nanoparticles[J]. Chemical Research in Chinese Universities, 2016, 32(4): 695-701.

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Preparation, Characterization, Luminescent and Electrochemical Properties of Ru(bpy)₂-functionalized Silica Nanoparticles

Preparation, Characterization, Luminescent and Electrochemical Properties of Ru(bpy)₂-functionalized Silica Nanoparticles

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