Catalytic Hydrogenation over Palladium Complex of Molecular Complex of Poly(4-vinylpyridine) with Acetic Acid

高等学校化学研究 ›› 2003, Vol. 19 ›› Issue (1): 76-79.

Catalytic Hydrogenation over Palladium Complex of Molecular Complex of Poly(4-vinylpyridine) with Acetic Acid

XI Xiang-li, ZHU Jing, CAO Shao-kui

Department of Materials Engineering, Zhengzhou University, Zhengzhou 450052, P. R. China

收稿日期:2001-12-04 出版日期:2003-01-24 发布日期:2011-08-06
基金资助:
Supported by the Outstanding Youngs Science Foudation of Henan Province(1999).

Catalytic Hydrogenation over Palladium Complex of Molecular Complex of Poly(4-vinylpyridine) with Acetic Acid

XI Xiang-li, ZHU Jing, CAO Shao-kui

Department of Materials Engineering, Zhengzhou University, Zhengzhou 450052, P. R. China

Received:2001-12-04 Online:2003-01-24 Published:2011-08-06
Supported by:
Supported by the Outstanding Youngs Science Foudation of Henan Province(1999).

摘要/Abstract

摘要： The palladium complex of the molecular complex of poly(4-vinylpyridine) with acetic acid(PVP/HAc-Pd) was prepared. Its catalytic activity for the hydrogenation of nitrobenzene was found much higher than that of the corresponding palladium complex of poly(4-vinylpyridine). In the presence of a strong inorganic alkali, especially potassium hydroxide, the catalytic activity is greatly improved. The suitable hydrogenation condition for PVP/HAc-Pd is to use 0.1 mol/L ethanol solution of potassium hydroxide as the hydrogenation medium and the hydrogenation is carried out at 45 ℃.

关键词: Palladium catalyst, Hydrogenation, Molecular complex, Nitrobenzene, Poly(4-vinylpyridine), Acetic acid

Abstract: The palladium complex of the molecular complex of poly(4-vinylpyridine) with acetic acid(PVP/HAc-Pd) was prepared. Its catalytic activity for the hydrogenation of nitrobenzene was found much higher than that of the corresponding palladium complex of poly(4-vinylpyridine). In the presence of a strong inorganic alkali, especially potassium hydroxide, the catalytic activity is greatly improved. The suitable hydrogenation condition for PVP/HAc-Pd is to use 0.1 mol/L ethanol solution of potassium hydroxide as the hydrogenation medium and the hydrogenation is carried out at 45 ℃.

Key words: Palladium catalyst, Hydrogenation, Molecular complex, Nitrobenzene, Poly(4-vinylpyridine), Acetic acid

XI Xiang-li, ZHU Jing, CAO Shao-kui. Catalytic Hydrogenation over Palladium Complex of Molecular Complex of Poly(4-vinylpyridine) with Acetic Acid[J]. 高等学校化学研究, 2003, 19(1): 76-79.

XI Xiang-li, ZHU Jing, CAO Shao-kui. Catalytic Hydrogenation over Palladium Complex of Molecular Complex of Poly(4-vinylpyridine) with Acetic Acid[J]. Chemical Research in Chinese Universities, 2003, 19(1): 76-79.

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Catalytic Hydrogenation over Palladium Complex of Molecular Complex of Poly(4-vinylpyridine) with Acetic Acid

Catalytic Hydrogenation over Palladium Complex of Molecular Complex of Poly(4-vinylpyridine) with Acetic Acid

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