Preparation of Cu-MgO Catalysts via Urea-nitrate Combustion Method and Their Catalytic Performance in Vapor Phase Hydrogenation of Furfural

doi:10.1007/s40242-017-6315-7

高等学校化学研究 ›› 2017, Vol. 33 ›› Issue (3): 442-446.doi: 10.1007/s40242-017-6315-7

Preparation of Cu-MgO Catalysts via Urea-nitrate Combustion Method and Their Catalytic Performance in Vapor Phase Hydrogenation of Furfural

WANG Licheng, BU Tiantong, WANG Zhenlü

Key Laboratory of Surface and Interface Chemistry of Jilin Province, College of Chemistry, Jilin University, Changchun 130021, P. R. China

收稿日期:2016-07-25 修回日期:2016-08-29 出版日期:2017-06-01 发布日期:2016-10-17
通讯作者: WANG Zhenlü,E-mail:wzl@jlu.edu.cn E-mail:wzl@jlu.edu.cn
基金资助:
Supported by the Jilin Province Science and Technology Research Plan(Key Scientific Research Project), China (No.20150204020GX).

Preparation of Cu-MgO Catalysts via Urea-nitrate Combustion Method and Their Catalytic Performance in Vapor Phase Hydrogenation of Furfural

WANG Licheng, BU Tiantong, WANG Zhenlü

Key Laboratory of Surface and Interface Chemistry of Jilin Province, College of Chemistry, Jilin University, Changchun 130021, P. R. China

Received:2016-07-25 Revised:2016-08-29 Online:2017-06-01 Published:2016-10-17
Contact: WANG Zhenlü,E-mail:wzl@jlu.edu.cn E-mail:wzl@jlu.edu.cn
Supported by:
Supported by the Jilin Province Science and Technology Research Plan(Key Scientific Research Project), China (No.20150204020GX).

摘要/Abstract

摘要：

A series of Cu-MgO catalysts was prepared via a urea-nitrate combustion method, and their catalytic per-formance was examined in the vapor phase hydrogenation of furfural. Characterization results showed that the amount of urea had important effects on the surface area, Cu dispersion and crystallite size of the catalysts. The Cu-MgO catalyst with a Cu loading of 12.1%(mass fraction) showed higher furfural conversion than the catalyst prepared by coprecipitation. The high activity was attributed to the higher dispersion of Cu on the catalyst surface. These results suggest that the combustion method is an efficient and simple route for the preparation of high activity Cu-MgO catalysts for furfural hydrogenation.

关键词: Furfural, Furfuryl alcohol, Hydrogenation, Cu-MgO catalyst, Combustion

Abstract:

Key words: Furfural, Furfuryl alcohol, Hydrogenation, Cu-MgO catalyst, Combustion

WANG Licheng, BU Tiantong, WANG Zhenlü. Preparation of Cu-MgO Catalysts via Urea-nitrate Combustion Method and Their Catalytic Performance in Vapor Phase Hydrogenation of Furfural[J]. 高等学校化学研究, 2017, 33(3): 442-446.

参考文献

[1] Li H., Zhang S., Luo H., Mater. Lett., 2004, 58, 2741
[2] Li H., Luo H., Zhuang L., Dai W., Qiao M., J. Mol. Catal. A:Chem., 2003, 203, 267
[3] Rao S. R., Baker R. T. K., Vannice M., Catal. Lett., 1999, 60, 51
[4] Rao S., Dandekar A., Baker R. T. K., Vannice M. A., J. Catal., 1997, 171, 406
[5] Liu B. J., Lu L. H., Wang B. C., Cai T. X., Katsuyoshi I., Appl. Catal. A:Gen., 1998, 171, 117
[6] Kijenski J., Winiarek P., Paryjczak T., Lewicki A., Mikolajska A., Appl. Catal. A:Gen., 2002, 233, 171
[7] Wu J., Shen Y., Liu C. L., Wang H. B., Geng C. J., Zhang Z. X., Ca-tal. Commun., 2005, 6, 633
[8] Nagaraja B. M., Siva Kumar V., Shasikala V., Padmasri A. H., Sreedhar B., David Raju B., Rama Rao K. S., Catal. Commun., 2003, 4, 287
[9] Zheng J., Zhu W. C., Ma C. X., Hou Y. Z., Zhang W. X., Wang Z. L., Reac. Kinet. Mech. Cat., 2010, 99, 455
[10] Ji D. H., Liu G., Jia M. J., Zhang W. X., Wang G. J., Wu T. H., Wang Z. L., Chem. J. Chinese Universities, 2007, 28(8), 1543
[11] Marinsek M., Zupan K., Maeek J., J. Power Source, 2002, 106, 178
[12] Delimaris D., Ioannides T., Appl. Catal. B:Environ., 2009, 89, 295
[13] Avgouropoulos G., Ioannides T., Appl. Catal. A:Gen., 2003, 244, 155
[14] Purohit R. D., Sharma B. P., Pillai K. T., Tyagic A. K., Mater. Res. Bull., 2001, 36, 2711
[15] Guo X. M., Mao D. S., Lu G. Z., Wang S., Wu G. S., J. Catal., 2010, 271, 178
[16] Tabakva T., Idakiev V., Papavasiliou J., Avgourooulos G., Ioannides T., Catal. Commun., 2007, 8, 101
[17] Nagaraja B. M., Padmasri A. H., Raju B. D., Rao K. S. R., J. Mol. Catal. A:Chem., 2007, 265, 90
[18] Yuan Z. L., Wang J. H., Wang L. N., Xie W. H., Chen P., Hou Z. Y., Zheng X. M., Bioresource Technol., 2010, 101, 7088
[19] Jia M. J., Zhang W. X., Wu T. H., J. Mol. A:Chem., 2002, 185, 151
[20] Chary K.V. R., Sagar G. V., Srikanth C. S., Rao V. V., J. Phys. Chem. B, 2007, 111, 543
[21] Bienholz A., Hofmann H., Claus P., App. Catal. A:Gen., 2011, 391, 153
[22] Avgouropoulos G., Ioannides T., Matralis H., Appl. Catal. B:Environ., 2005, 56, 87
[23] Avgouropoulos G., Ioannides T., Appl. Catal. B:Environ., 2006, 67, 1
[24] Zhang Y. P., Fei J. H., Yu Y. M., Zheng X. M., Energy Convers Manage, 2006, 47, 3360
[25] Chen X. F., Li H. X., Luo H. S., Qiao M. H., Appl. Catal. A:Gen., 2002, 233, 13
[26] Xu W. J., Wang H. F., Liu X. H., Ren J. W., Wang Y. Q., Lu G. Z., Chem. Commun., 2011, 47, 3924
[27] Lei H., Hou Z. Y., Xie J. W., Fuel, 2016, 164, 191

Preparation of Cu-MgO Catalysts via Urea-nitrate Combustion Method and Their Catalytic Performance in Vapor Phase Hydrogenation of Furfural

Preparation of Cu-MgO Catalysts via Urea-nitrate Combustion Method and Their Catalytic Performance in Vapor Phase Hydrogenation of Furfural

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