Reductive Amination of Carbonyl Compounds with Ammonia and Hydrogenation of Nitriles to Primary Amines with Heterogeneous Cobalt Catalysts

doi:10.1007/s40242-019-8390-4

高等学校化学研究 ›› 2019, Vol. 35 ›› Issue (3): 457-462.doi: 10.1007/s40242-019-8390-4

Reductive Amination of Carbonyl Compounds with Ammonia and Hydrogenation of Nitriles to Primary Amines with Heterogeneous Cobalt Catalysts

LIU Junmei, GUO Wanwan, SUN Hao, LI Ruyue, FENG Zhipeng, ZHOU Xuyang, HUANG Jun

State Key Laboratory of Materials-oriented Chemical Engineering, College of Chemical Engineering, Nanjing Tech University, Nanjing 210009, P. R. China

收稿日期:2018-12-14 修回日期:2019-03-08 出版日期:2019-06-01 发布日期:2019-03-27
通讯作者: HUANG Jun E-mail:junhuang@njtech.edu.cn
基金资助:
Supported by the National Natural Science Foundation of China(No.21676140) and the Fund of the State Key Laboratory of Materials-oriented Chemical Engineering, China(No.ZK201711).

Reductive Amination of Carbonyl Compounds with Ammonia and Hydrogenation of Nitriles to Primary Amines with Heterogeneous Cobalt Catalysts

LIU Junmei, GUO Wanwan, SUN Hao, LI Ruyue, FENG Zhipeng, ZHOU Xuyang, HUANG Jun

State Key Laboratory of Materials-oriented Chemical Engineering, College of Chemical Engineering, Nanjing Tech University, Nanjing 210009, P. R. China

Received:2018-12-14 Revised:2019-03-08 Online:2019-06-01 Published:2019-03-27
Contact: HUANG Jun E-mail:junhuang@njtech.edu.cn
Supported by:
Supported by the National Natural Science Foundation of China(No.21676140) and the Fund of the State Key Laboratory of Materials-oriented Chemical Engineering, China(No.ZK201711).

摘要/Abstract

摘要： Reductive amination of aldehydes/ketones with aqueous NH₃ and hydrogenation of nitriles to primary amines with Co catalysts were reported. Co@NC-700 exhibited remarkable activity and high selectivity for the reductive amination of aldehydes/ketones with aqueous NH₃ and the hydrogenation of nitriles to primary amines. Several primary amines can be obtained with good to excellent yields via the reductive amination of aldehydes/ketones and the hydrogenation of nitriles. The nitrogen-doped carbon(C)-supported Co@NC-700 metal catalyst was prepared via the pyrolysis of bioMOF Co/adenine in activated C. Co@NC-700 can be reused five times without evident loss of activity.

关键词: Primary amine, Cobalt, Reductive amination, Aldehyde, Hydrogenation, Nitrile

Abstract: Reductive amination of aldehydes/ketones with aqueous NH₃ and hydrogenation of nitriles to primary amines with Co catalysts were reported. Co@NC-700 exhibited remarkable activity and high selectivity for the reductive amination of aldehydes/ketones with aqueous NH₃ and the hydrogenation of nitriles to primary amines. Several primary amines can be obtained with good to excellent yields via the reductive amination of aldehydes/ketones and the hydrogenation of nitriles. The nitrogen-doped carbon(C)-supported Co@NC-700 metal catalyst was prepared via the pyrolysis of bioMOF Co/adenine in activated C. Co@NC-700 can be reused five times without evident loss of activity.

Key words: Primary amine, Cobalt, Reductive amination, Aldehyde, Hydrogenation, Nitrile

LIU Junmei, GUO Wanwan, SUN Hao, LI Ruyue, FENG Zhipeng, ZHOU Xuyang, HUANG Jun. Reductive Amination of Carbonyl Compounds with Ammonia and Hydrogenation of Nitriles to Primary Amines with Heterogeneous Cobalt Catalysts[J]. 高等学校化学研究, 2019, 35(3): 457-462.

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Reductive Amination of Carbonyl Compounds with Ammonia and Hydrogenation of Nitriles to Primary Amines with Heterogeneous Cobalt Catalysts

Reductive Amination of Carbonyl Compounds with Ammonia and Hydrogenation of Nitriles to Primary Amines with Heterogeneous Cobalt Catalysts

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