A Highly Efficient Ni/Al2O3-LaOx Catalyst for the Reductive Amination of Furfural to Furfurylamine: the Promoting Effect of La

doi:10.1007/s40242-023-3216-9

高等学校化学研究 ›› 2024, Vol. 40 ›› Issue (1): 36-46.doi: 10.1007/s40242-023-3216-9

A Highly Efficient Ni/Al₂O₃-LaO_x Catalyst for the Reductive Amination of Furfural to Furfurylamine: the Promoting Effect of La

YANG Yinze^1,2,3, ZHANG Liyan^1,2,3, ZHOU Leilei^1,2,3, CHENG Haiyang^1,3, ZHAO Fengyu^1,2,3

1. State Key Laboratory of Electroanalytical Chemistry, Changchun Institute of Applied Chemistry, Chinese Academy of Sciences, Changchun 130022, P. R. China;
2. School of Applied Chemistry and Engineering, University of Science Technology of China, Hefei 230026, P. R. China;
3. Jilin Province Key Laboratory of Green Chemistry and Process, Changchun Institute of Applied Chemistry, Chinese Academy of Sciences, Changchun 130022, P. R. China

收稿日期:2023-09-15 出版日期:2024-02-01 发布日期:2024-01-24
通讯作者: CHENG Haiyang, ZHAO Fengyu E-mail:hycyl@ciac.ac.cn;zhaofy@ciac.ac.cn
基金资助:
This work was supported by the National Key Research and Development Program of China (No. 2022YFA1504901), the National Natural Science Foundation of China (No. NSFC 22072142), and the Science and Technology Development Program of Jilin Province, China (No. YDZJ202301ZYTS539).

A Highly Efficient Ni/Al₂O₃-LaO_x Catalyst for the Reductive Amination of Furfural to Furfurylamine: the Promoting Effect of La

YANG Yinze^1,2,3, ZHANG Liyan^1,2,3, ZHOU Leilei^1,2,3, CHENG Haiyang^1,3, ZHAO Fengyu^1,2,3

1. State Key Laboratory of Electroanalytical Chemistry, Changchun Institute of Applied Chemistry, Chinese Academy of Sciences, Changchun 130022, P. R. China;
2. School of Applied Chemistry and Engineering, University of Science Technology of China, Hefei 230026, P. R. China;
3. Jilin Province Key Laboratory of Green Chemistry and Process, Changchun Institute of Applied Chemistry, Chinese Academy of Sciences, Changchun 130022, P. R. China

Received:2023-09-15 Online:2024-02-01 Published:2024-01-24
Contact: CHENG Haiyang, ZHAO Fengyu E-mail:hycyl@ciac.ac.cn;zhaofy@ciac.ac.cn
Supported by:
This work was supported by the National Key Research and Development Program of China (No. 2022YFA1504901), the National Natural Science Foundation of China (No. NSFC 22072142), and the Science and Technology Development Program of Jilin Province, China (No. YDZJ202301ZYTS539).

摘要/Abstract

摘要： The reductive amination of furfural to furfurylamine is an important and still challenging topic in the field of biomass conversion. In this work, we prepared a series of Ni/Al₂O₃-LaO_x catalysts by co-precipitation method, the role of La played in promoting the catalytic performances of reductive amination furfural was discussed based on the changes in the electronic state of Ni species, acidity, and Ni particle size. The catalytic activity and the selectivity of furfurylamine are highly dependent on the surface properties and the structure of the catalyst. The addition of La promoted the amount of strong acidic sites and the H₂dissociation and spillover on the surface, thus inducing the improvement of the catalytic activity and furfurylamine selectivity. The Ni/Al₂O₃-0.5LaO_xcatalyst with suitable acid sites gave a high yield of furfurylamine (94.9%) under mild reaction conditions. Moreover, the catalyst could be recycled five times without significant loss in activity. The Ni/Al₂O₃-LaO_x catalyst is of great promise in the production of amines via reductive amination reaction.

关键词: Reductive amination, Furfural, Nickel catalyst, Furfurylamine, Lanthanum

Abstract: The reductive amination of furfural to furfurylamine is an important and still challenging topic in the field of biomass conversion. In this work, we prepared a series of Ni/Al₂O₃-LaO_x catalysts by co-precipitation method, the role of La played in promoting the catalytic performances of reductive amination furfural was discussed based on the changes in the electronic state of Ni species, acidity, and Ni particle size. The catalytic activity and the selectivity of furfurylamine are highly dependent on the surface properties and the structure of the catalyst. The addition of La promoted the amount of strong acidic sites and the H₂dissociation and spillover on the surface, thus inducing the improvement of the catalytic activity and furfurylamine selectivity. The Ni/Al₂O₃-0.5LaO_xcatalyst with suitable acid sites gave a high yield of furfurylamine (94.9%) under mild reaction conditions. Moreover, the catalyst could be recycled five times without significant loss in activity. The Ni/Al₂O₃-LaO_x catalyst is of great promise in the production of amines via reductive amination reaction.

Key words: Reductive amination, Furfural, Nickel catalyst, Furfurylamine, Lanthanum

YANG Yinze, ZHANG Liyan, ZHOU Leilei, CHENG Haiyang, ZHAO Fengyu. A Highly Efficient Ni/Al₂O₃-LaO_x Catalyst for the Reductive Amination of Furfural to Furfurylamine: the Promoting Effect of La[J]. 高等学校化学研究, 2024, 40(1): 36-46.

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A Highly Efficient Ni/Al₂O₃-LaO_x Catalyst for the Reductive Amination of Furfural to Furfurylamine: the Promoting Effect of La

A Highly Efficient Ni/Al₂O₃-LaO_x Catalyst for the Reductive Amination of Furfural to Furfurylamine: the Promoting Effect of La

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