Two New Borates Built by Different Types of {B9} Cluster Units

doi:10.1007/s40242-022-1473-7

高等学校化学研究 ›› 2022, Vol. 38 ›› Issue (3): 744-749.doi: 10.1007/s40242-022-1473-7

Two New Borates Built by Different Types of {B₉} Cluster Units

CHEN Juan, WANG Jiajia, CHEN Chongan and YANG Guoyu

Key Laboratory of Cluster Science, Ministry of Education, School of Chemistry and Chemical Engineering, Beijing Institute of Technology, Beijing 102488, P. R. China

收稿日期:2021-11-26 修回日期:2021-12-27 出版日期:2022-06-01 发布日期:2022-05-26
通讯作者: YANG Guoyu E-mail:ygy@bit.edu.cn
基金资助:
This work was supported by the National Natural Science Foundation of China(Nos.21831001, 21571016, 91122028) and the National Natural Science Foundation of China for Distinguished Young Scholars(No.20725101).

Two New Borates Built by Different Types of {B₉} Cluster Units

CHEN Juan, WANG Jiajia, CHEN Chongan and YANG Guoyu

Key Laboratory of Cluster Science, Ministry of Education, School of Chemistry and Chemical Engineering, Beijing Institute of Technology, Beijing 102488, P. R. China

Received:2021-11-26 Revised:2021-12-27 Online:2022-06-01 Published:2022-05-26
Contact: YANG Guoyu E-mail:ygy@bit.edu.cn
Supported by:
This work was supported by the National Natural Science Foundation of China(Nos.21831001, 21571016, 91122028) and the National Natural Science Foundation of China for Distinguished Young Scholars(No.20725101).

摘要/Abstract

摘要： Two new belt-like borates Na₄[B₉O₁₄(OH)₃]·0.5H₂O(1) and Na₅[B₉O₁₄(OH)₄](2) have been synthesized under solvothermal conditions. Both compounds contain unprecedented B₉O₁₆(OH)_n^(n+5)-[n=3(1), 4(2)] clusters, which are constructed from four B₃O₃ rings via three BO₄ tetrahedra. Compound 1 exhibits a rare 1D belt with two types of 8-membered ring(MR) windows based on B₉O₁₆(OH)₃^8- clusters. Compound 2 features two different 1D belts built by different B₉O₁₆(OH)₄^9- units, which is first discovered in borate family. UV-Vis diffuse reflectance spectra reveal that compounds 1 and 2 have the cut-off edges below 190 nm, indicating that they may have potential application in deep UV(DUV) region.

关键词: Oxoboron cluster, Synthesis, Borate, Supramolecular framework, Structure

Abstract: Two new belt-like borates Na₄[B₉O₁₄(OH)₃]·0.5H₂O(1) and Na₅[B₉O₁₄(OH)₄](2) have been synthesized under solvothermal conditions. Both compounds contain unprecedented B₉O₁₆(OH)_n^(n+5)-[n=3(1), 4(2)] clusters, which are constructed from four B₃O₃ rings via three BO₄ tetrahedra. Compound 1 exhibits a rare 1D belt with two types of 8-membered ring(MR) windows based on B₉O₁₆(OH)₃^8- clusters. Compound 2 features two different 1D belts built by different B₉O₁₆(OH)₄^9- units, which is first discovered in borate family. UV-Vis diffuse reflectance spectra reveal that compounds 1 and 2 have the cut-off edges below 190 nm, indicating that they may have potential application in deep UV(DUV) region.

Key words: Oxoboron cluster, Synthesis, Borate, Supramolecular framework, Structure

CHEN Juan, WANG Jiajia, CHEN Chongan and YANG Guoyu. Two New Borates Built by Different Types of {B₉} Cluster Units[J]. 高等学校化学研究, 2022, 38(3): 744-749.

CHEN Juan, WANG Jiajia, CHEN Chongan and YANG Guoyu. Two New Borates Built by Different Types of {B₉} Cluster Units[J]. Chemical Research in Chinese Universities, 2022, 38(3): 744-749.

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Two New Borates Built by Different Types of {B₉} Cluster Units

Two New Borates Built by Different Types of {B₉} Cluster Units

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