In situ Carbon Modification of g-C3N4 from Urea co-Crystal with Enhanced Photocatalytic Activity Towards Degradation of Organic Dyes Under Visible Light

doi:10.1007/s40242-020-0073-7

高等学校化学研究 ›› 2020, Vol. 36 ›› Issue (6): 1265-1271.doi: 10.1007/s40242-020-0073-7

In situ Carbon Modification of g-C₃N₄ from Urea co-Crystal with Enhanced Photocatalytic Activity Towards Degradation of Organic Dyes Under Visible Light

ZHAO Weifeng¹, HAO Ning¹, ZHANG Gai¹, MA Aijie¹, CHEN Weixing¹, ZHOU Hongwei¹, YANG Dong², XU Ben Bin³, KONG Jie²

1. School of Materials and Chemical Engineering, Xi'an Technological University, Xi'an 710021, P. R. China;
2. Department of Applied Chemistry, School of Science, Northwestern Polytechnical University, Xi'an 710072, P. R. China;
3. Department of Mechanical and Construction Engineering, Faculty of Engineering and Environment, Northumbria University, Newcastle upon Tyne, NE1 8ST, UK

收稿日期:2020-03-25 修回日期:2020-05-20 出版日期:2020-12-01 发布日期:2020-06-10
通讯作者: ZHAO Weifeng, CHEN Weixing, KONG Jie E-mail:zhaoweifeng@xatu.edu.cn;chenwx@xatu.edu.cn;kongjie@nwpu.edu.cn
基金资助:
Supported by the National Natural Science Foundation of China(Nos.61604120, 51603164), the Natural Science Foundation of Shaanxi Province, China(No.2019JM-527), the Natural Science Basic Research Plan in Shaanxi Province, China (No.2018JC-008), and the Key Research and Development Plan for Industry Innovation Chain(Cluster) of Shaanxi Province, China(No.2018ZDCXL-GY-09-07).

In situ Carbon Modification of g-C₃N₄ from Urea co-Crystal with Enhanced Photocatalytic Activity Towards Degradation of Organic Dyes Under Visible Light

ZHAO Weifeng¹, HAO Ning¹, ZHANG Gai¹, MA Aijie¹, CHEN Weixing¹, ZHOU Hongwei¹, YANG Dong², XU Ben Bin³, KONG Jie²

1. School of Materials and Chemical Engineering, Xi'an Technological University, Xi'an 710021, P. R. China;
2. Department of Applied Chemistry, School of Science, Northwestern Polytechnical University, Xi'an 710072, P. R. China;
3. Department of Mechanical and Construction Engineering, Faculty of Engineering and Environment, Northumbria University, Newcastle upon Tyne, NE1 8ST, UK

Received:2020-03-25 Revised:2020-05-20 Online:2020-12-01 Published:2020-06-10
Contact: ZHAO Weifeng, CHEN Weixing, KONG Jie E-mail:zhaoweifeng@xatu.edu.cn;chenwx@xatu.edu.cn;kongjie@nwpu.edu.cn
Supported by:
Supported by the National Natural Science Foundation of China(Nos.61604120, 51603164), the Natural Science Foundation of Shaanxi Province, China(No.2019JM-527), the Natural Science Basic Research Plan in Shaanxi Province, China (No.2018JC-008), and the Key Research and Development Plan for Industry Innovation Chain(Cluster) of Shaanxi Province, China(No.2018ZDCXL-GY-09-07).

摘要/Abstract

摘要： An in situ strategy was introduced for synthesizing carbon modified graphitic carbon nitride(g-C₃N₄) by using urea/4-aminobenzoic acid(PABA) co-crystal(PABA@Urea) as precursor materials. Via co-calcination of the PABA co-former and the urea in PABA@Urea co-crystals, C guest species were generated and compounded into g-C₃N₄ matrix in situ by replacing the lattice N of the carbon nitride and forming carbon dots onto its layer surface. The carbon modification dramatically enhanced visible-light harvesting and charge carrier separation. Therefore, visible light photo-catalytic oxidation of methylene blue(MB) pollution in water over the carbon modified g-C₃N₄(C/g-C₃N₄) was notably improved. Up to 99% of methylene blue(MB) was eliminated within 60 min by the optimal sample prepared from the PABA@Urea co-crystal with a PABA content of 0.1%(mass ratio), faster than the degradation rate over bare g-C₃N₄. The present study demonstrates a new way to boost up the photocatalysis performance of g-C₃N₄, which holds great potential concerning the degradation of organic dyes from water.

关键词: Graphitic carbon nitride, Carbon composite, Photocatalysis, Photodegradation

Abstract: An in situ strategy was introduced for synthesizing carbon modified graphitic carbon nitride(g-C₃N₄) by using urea/4-aminobenzoic acid(PABA) co-crystal(PABA@Urea) as precursor materials. Via co-calcination of the PABA co-former and the urea in PABA@Urea co-crystals, C guest species were generated and compounded into g-C₃N₄ matrix in situ by replacing the lattice N of the carbon nitride and forming carbon dots onto its layer surface. The carbon modification dramatically enhanced visible-light harvesting and charge carrier separation. Therefore, visible light photo-catalytic oxidation of methylene blue(MB) pollution in water over the carbon modified g-C₃N₄(C/g-C₃N₄) was notably improved. Up to 99% of methylene blue(MB) was eliminated within 60 min by the optimal sample prepared from the PABA@Urea co-crystal with a PABA content of 0.1%(mass ratio), faster than the degradation rate over bare g-C₃N₄. The present study demonstrates a new way to boost up the photocatalysis performance of g-C₃N₄, which holds great potential concerning the degradation of organic dyes from water.

Key words: Graphitic carbon nitride, Carbon composite, Photocatalysis, Photodegradation

ZHAO Weifeng, HAO Ning, ZHANG Gai, MA Aijie, CHEN Weixing, ZHOU Hongwei, YANG Dong, XU Ben Bin, KONG Jie. In situ Carbon Modification of g-C₃N₄ from Urea co-Crystal with Enhanced Photocatalytic Activity Towards Degradation of Organic Dyes Under Visible Light[J]. 高等学校化学研究, 2020, 36(6): 1265-1271.

参考文献

[1] Wang X. C., Maeda K., Thomas A., Takanabe K., Xin G., Carlsson J. M., Domen K., Antonietti M., Nat. Mater., 2009, 8, 76
[2] Ong W. J., Tan L. L., Ng Y. H., Yong S. T., Chai S. P., Chem. Rev., 2016, 116(12), 7159
[3] He K., Xie J., Luo X., Wen J. Q., Ma S., Li X., Fang Y. P., Zhang X. C., Chinese J. Catal., 2017, 38(2), 240
[4] Jiang J., Cao S., Hu C., Chen C. H., Chinese J. Catal., 2017, 38(12), 1981
[5] Liu B., Ye L., Wang R., Yang, J. F., Zhang Y. X., Guan R., Tian L. H., Chen X. B., ACS Appl. Mater. Inter., 2018, 10(4), 4001
[6] Chen F., Yang H., Luo W., Wang P., Yu H. G., Chinese J. Catal., 2017, 38(12), 1990
[7] Pawar R. C., Khare V., Lee C. S., Dalton Trans., 2014, 43, 12514
[8] Yu H., Chen F., Wang X., Appl. Surf. Sci., 2015, 358, 385
[9] Hua E. B., Liu G., Zhang G., Xu X., Dalton Trans., 2018, 47, 4360
[10] Teng Z. Y., Yang N. L., Lv H. Y., Wang S. C., Hu M. Z., Wang C. Y., Wang D., Wang G. X., Chem, 2019, 5, 664
[11] Jun Y. S., Lee E. Z., Wang X., Hong W. H., Stucky G. D., Thomas A., Adv. Fun. Mater., 2013, 23(29), 3661
[12] Cui Y., Wang Y., Wang H., Cao F., Chen F. Y., Chinese J. Catal., 2016, 37(11), 1899
[13] Zheng Y., Lin L., Ye X., Guo F., Wang X., Angew. Chem., Int. Ed., 2014, 53, 11926
[14] Yuan B., Wei J. X., Hu T. J., Yao H. B., Jiang Z. H., Fang Z. W., Chu Z. Y., Chinese J. Catal., 2015, 36(7), 1009
[15] Han Q., Chen N., Zhang J., Qu L. T., Mater. Horiz., 2017, 4(5), 832
[16] Lai S. K., Xie C., Teng K. S., Li Y. Y., Tan F. R., Yan F., Lau S. P., Adv. Opt. Mater., 2016, 4, 555
[17] Li H. L., Li F. P., Wan Z. Y., Jiao Y. C., Liu Y. Y., Wang P., Zhang X. Y., Qin X. Y., Dai Y., Huan B., Appl. Catal. B:Environ., 2018, 229, 114
[18] Panneri S., Gangulya P., Mohan M., Naircd B. N., Mohamed A. A. P., Warrier K. G., Hareesh U. S., ACS Sustainable Chem. Eng., 2017, 5(2), 1610
[19] Vangala V. R., Chow P. S., Tan R. B. H., Cryst. Growth Des., 2012, 12(12), 5925
[20] Jun Y. S., Park J., Lee S. U., Thomas A., Hong W. H., Stucky G. D., Angew. Chem. Int. Edit., 2013, 52(42), 11289
[21] Shalom M., Guttentag M., Fettkenhauer C., Inal S., Neher D., Llobet A., Antonietti M., Chem. Mater., 2014, 26, 5812
[22] Ishida Y., Chabanne L., Antonietti M., Shalom M., Langmuir, 2014, 30, 447
[23] Miao P., Cheng K. Y., Li H. Q., Gu J. W., Wang S., Wang D., Liu T. X., Xu B. B., Kong J., ACS Appl. Mater. Interfaces, 2019, 11(19), 17706
[24] Xu Q. L., Cheng B., Yu J. G., Liu G., Carbon, 2017, 118, 241
[25] Zhang X. F., Chen L. X., Yun J., Wang X. D., Kong J., J. Mater. Chem. A, 2017, 5(22), 10986
[26] Liu J. H., Zhang T. K., Wang Z. C., Dawsona G., Chen W., J. Mater. Chem., 2011, 21(38), 14398
[27] Fang S., Xia Y., Lv K., LI Q., Sun J., Li M., Appl. Catal. B:Environ., 2016, 185, 225
[28] Mohamed M. A., Jaafar J., Zain M. F. M., Minggu L. J., Kassim M. B., Rosmi M. S., Alias N. H., Nor N. A. M., Salleh W. N. W., Othman M. H. D., Appl. Surf. Sci., 2018, 436, 302
[29] Shan Q. Y., Guan B., Zhu S. J., Zhang H. J., Zhang Y. X., RSC Advances, 2016, 6, 83209
[30] Wang X. F., Cheng J. J., Yu H. G., Yu J. G., Dalton Trans., 2017, 46(19), 6417
[31] Li X., Pan K., Qu Y., Wang G. F., Nano Res., 2018, 11(3), 1322
[32] Zhao Q. L., Zhang Z. L., Huang B. H., Peng J., Zhang M., Pang D. W., Chem. Commun., 2008, 41, 5116
[33] Ming H., Ma Z., Liu Y., Pan K. M., Yu H., Wang F., Kang Z. H., Dalton Trans., 2012, 41(19), 9256
[34] Bu T. J., Ma X. W., Zhao B., Song W., Chem. Res. Chinese Universities, 2018, 34(2), 290
[35] Xing W. N., Li C. M., Chen G., Han Z. H., Zhou Y. S., Hu Y. D., Meng Q., Appl. Catal. B:Environ., 2017, 203, 65
[36] Xu Q. L., Cheng B., Yu J. G., Liu G., Carbon, 2017, 118, 241
[37] Zhao Z. W., Sun Y. J., Dong F., Zhang Y. X., Zhao H., RSC Adv., 2015, 5(49), 39549
[38] Ye C., Li J. X., Li Z. J., Li X. B., Fan X. B., Zhang L. P., Chen B., Tung C. H., Wu L. Z., ACS Catal., 2015, 5(11), 6973
[39] Kang Y. Y., Yang Y. Q., Yin L. C., Kang X. D., Liu G., Cheng H. M., Adv. Mater., 2015, 27(31), 4572
[40] Silva E. S. D., Moura N. M. M., Coutinho A., Goran D., Faria J. L., ChemSusChem, 2018, 11(16), 2681
[41] Dong G. H., Zhao K., Zhang L. Z., Chem. Commun., 2012, 48(49), 6178
[42] She X. J., Liu L., Ji H. Y., Mo Z., Li Y. P., Huang L. Y., Du D. L., Hui X., Li H. M., Appl. Catal. B:Environ., 2016, 187, 144
[43] Fan D., Wang Z. Y., Sun Y. J., Ho W., Zhang H. D., J. Colloid Interface Sci., 2013, 401, 70
[44] Jia Y., Chen J., Yao X. D., Mater. Chem. Front., 2018, 2, 1250
[45] Li Y. P., Wu S. L., Huang L. Y., Wang J. L., Xu H., Li H. M., Mater. Lett., 2014, 137, 281
[46] Ding J., Wang L., Liu Q., Chai Y., Liu X., Dai W. L., Appl. Catal. B:Environ., 2015, 176, 91
[47] Cui Y. J., Ding Z. X., Liu P., Antonietti M., Fu X. Z., Wang X. C., Phys. Chem. Chem. Phys., 2012, 14, 1455
[48] Gao G. P., Jiao Y., Ma F. X., Jiao Y. L., Waclawika E., Du A. J., Phys. Chem. Chem. Phys., 2015, 17, 31140

In situ Carbon Modification of g-C₃N₄ from Urea co-Crystal with Enhanced Photocatalytic Activity Towards Degradation of Organic Dyes Under Visible Light

In situ Carbon Modification of g-C₃N₄ from Urea co-Crystal with Enhanced Photocatalytic Activity Towards Degradation of Organic Dyes Under Visible Light

可视化

摘要/Abstract

引用本文

使用本文

参考文献

相关文章 15

编辑推荐

Metrics

本文评价

[1]	SONG Weiyu, LV Xintong, GAO Yang, WANG Lu. Photocatalytic HER Performance of TiO₂-supported Single Atom Catalyst Based on Electronic Regulation:A DFT Study[J]. 高等学校化学研究, 2022, 38(4): 1025-1031.
[2]	WEI Xiao, LI Xinhao, WANG Kaixue and CHEN Jiesheng. Design of Functional Carbon Composite Materials for Energy Conversion and Storage[J]. 高等学校化学研究, 2022, 38(3): 677-687.
[3]	DU Shihao, BIAN Xuanang, ZHAO Yunxuan, SHI Run, and ZHANG Tierui. Progress and Prospect of Photothermal Catalysis[J]. 高等学校化学研究, 2022, 38(3): 723-734.
[4]	LIU Shujing, GUO Jia. Two-dimensional Covalent Organic Frameworks: Intrinsic Synergy Promoting Photocatalytic Hydrogen Evolution[J]. 高等学校化学研究, 2022, 38(2): 373-381.
[5]	HU Guilin, HE Jingyi, LI Yongjun. Application of Graphdiyne and Its Analogues in Photocatalysis and Photoelectrochemistry[J]. 高等学校化学研究, 2021, 37(6): 1195-1212.
[6]	MA Yuying, HE Dayong, LIU Jiadi, WANG Yuannan, YANG Mei, WANG Hao, QIU Ju, LI Wenyan, LI Yongxin, WANG Ce. Adsorption and Visible Light Photocatalytic Degradation of Electrospun PAN@W₁₈O₄₉ Nanofibers[J]. 高等学校化学研究, 2021, 37(3): 428-435.
[7]	JIAN Shaoju, TIAN Zhiwei, ZHANG Kaiyin, DUAN Gaigai, YANG Weisen, JIANG Shaohua. Hydrothermal Synthesis of Ce-doped ZnO Heterojunction Supported on Carbon Nanofibers with High Visible Light Photocatalytic Activity[J]. 高等学校化学研究, 2021, 37(3): 565-570.
[8]	GU Xianmo, MA Pengwei, LIU Pei, WANG Ruiyi, LI Xincheng, ZHENG Zhanfeng. Visible-light-driven Hydroamination of Alkynes over a New Type of Activated Carbon Immobilized Cu²⁺ Photocatalyst[J]. 高等学校化学研究, 2020, 36(6): 1039-1044.
[9]	CHEN Ting, ZHONG Lei, YANG Zhen, MOU Zhigang, LIU Lei, WANG Yan, SUN Jianhua, LEI Weiwei. Enhanced Visible-light Photocatalytic Activity of g-C₃N₄/Nitrogen-doped Graphene Quantum Dots/TiO₂ Ternary Heterojunctions for Ciprofloxacin Degradation with Narrow Band Gap and High Charge Carrier Mobility[J]. 高等学校化学研究, 2020, 36(6): 1083-1090.
[10]	JIANG Wenshuai, ZONG Xupeng, WANG Xiayan, SUN Zaicheng. Transparent Coating with TiO₂ Nanorods for High-performance Photocatalytic Self-cleaning and Environmental Remediation[J]. 高等学校化学研究, 2020, 36(6): 1097-1101.
[11]	CEN Qing, XIAO Wei, LIU Yingqi, WANG Qi, NAFADY Ayman, MA Shengqian. Fabrication of Fe-POMs as Visible-light-active Heterogeneous Photocatalyst[J]. 高等学校化学研究, 2020, 36(6): 1128-1135.
[12]	WANG Changhua, ZHANG Xintong. Anatase/Bronze TiO₂ Heterojunction: Enhanced Photocatalysis and Prospect in Photothermal Catalysis[J]. 高等学校化学研究, 2020, 36(6): 992-999.
[13]	YU Qiuying, LIN Xiu, LI Xinhao, CHEN Jiesheng. Photocatalytic Stille Cross-coupling on Gold/g-C₃N₄Nano-heterojunction[J]. 高等学校化学研究, 2020, 36(6): 1013-1016.
[14]	LI Xiaodong, SU Qing, LIU Ziqian, LUO Kexin, LI Guanghua, WU Qiaolin. A Triformylphloroglucinol-based Covalent Organic Polymer: Synthesis, Characterization and Its Application in Visible-light-driven Oxidative Coupling Reactions of Primary Amines[J]. 高等学校化学研究, 2020, 36(6): 1017-1023.
[15]	QI Yinhong, XU Jixiang, WANG Chao, ZHAN Tianrong, WANG Lei. Synthesis of Holey Graphitic Carbon Nitride with Highly Enhanced Photocatalytic Reduction Activity via Melamine-cyanuric Acid Precursor Route[J]. 高等学校化学研究, 2020, 36(6): 1024-1031.