Porous NiCo2O4 Nanowire Arrays as Supercapacitor Electrode Materials with Extremely High Cycling Stability

doi:10.1007/s40242-020-0149-4

高等学校化学研究 ›› 2020, Vol. 36 ›› Issue (4): 715-720.doi: 10.1007/s40242-020-0149-4

Porous NiCo₂O₄ Nanowire Arrays as Supercapacitor Electrode Materials with Extremely High Cycling Stability

CHEN Chaoxian, ZHAO Chenyang, LI Cuihua, LIU Jianhong, GUI Dayong

College of Chemistry and Environmental Engineering, Shenzhen University, Shenzhen 518055, P. R. China

收稿日期:2020-05-04 修回日期:2020-06-30 出版日期:2020-08-01 发布日期:2020-07-30
通讯作者: GUI Dayong E-mail:dygui@szu.edu.cn
基金资助:
Supported by the Natural Science Foundation of Guangdong Province, China(No.2017A030313322) and the Project of the Huizhou Ledman Optoelectronic Technology Co., Ltd., China(No.17006157).

Porous NiCo₂O₄ Nanowire Arrays as Supercapacitor Electrode Materials with Extremely High Cycling Stability

CHEN Chaoxian, ZHAO Chenyang, LI Cuihua, LIU Jianhong, GUI Dayong

College of Chemistry and Environmental Engineering, Shenzhen University, Shenzhen 518055, P. R. China

Received:2020-05-04 Revised:2020-06-30 Online:2020-08-01 Published:2020-07-30
Contact: GUI Dayong E-mail:dygui@szu.edu.cn
Supported by:
Supported by the Natural Science Foundation of Guangdong Province, China(No.2017A030313322) and the Project of the Huizhou Ledman Optoelectronic Technology Co., Ltd., China(No.17006157).

摘要/Abstract

摘要： In this work, NiCo₂O₄(NCO) was synthesized via microwave hydrothermal method and a further annea- ling treatment. Research results have shown that the surface defects(Co²⁺ site) and pore size of the materials can be adjusted by simply changing the calcination temperatures, and porous nanowire arrays structure can be obtained. The porous structure is conducive to the penetration of the electrolyte and enables the NCO to fully participate in the electrochemical reaction. What's more, the NCO material has ample space to buffer the volume change in the cycle test, improving the cycling stability. The NCO obtained at 350℃ has better performance. It exhibits a specific capacitance of 648.69 F/g at 1 A/g and good rate capability. Especially, at 10 A/g, the specific capacitance can still be maintained at 80.00% after 10000 galvanostatic charge/discharge(GCD) cycles, showing excellent cycling stability.

关键词: NiCo₂O₄, Porous nanowire array, High cycling stability, Supercapacitor

Abstract: In this work, NiCo₂O₄(NCO) was synthesized via microwave hydrothermal method and a further annea- ling treatment. Research results have shown that the surface defects(Co²⁺ site) and pore size of the materials can be adjusted by simply changing the calcination temperatures, and porous nanowire arrays structure can be obtained. The porous structure is conducive to the penetration of the electrolyte and enables the NCO to fully participate in the electrochemical reaction. What's more, the NCO material has ample space to buffer the volume change in the cycle test, improving the cycling stability. The NCO obtained at 350℃ has better performance. It exhibits a specific capacitance of 648.69 F/g at 1 A/g and good rate capability. Especially, at 10 A/g, the specific capacitance can still be maintained at 80.00% after 10000 galvanostatic charge/discharge(GCD) cycles, showing excellent cycling stability.

Key words: NiCo₂O₄, Porous nanowire array, High cycling stability, Supercapacitor

CHEN Chaoxian, ZHAO Chenyang, LI Cuihua, LIU Jianhong, GUI Dayong. Porous NiCo₂O₄ Nanowire Arrays as Supercapacitor Electrode Materials with Extremely High Cycling Stability[J]. 高等学校化学研究, 2020, 36(4): 715-720.

参考文献 41

[1]	Shanmugavani A., Selvan R. K., Electrochimica Acta, 2016, 189, 283
[2]	Zheng Y., Tian Y., Liu S., Tan X., Wang S., Guo Q., Luo J., Li Z., Journal of Alloys and Compounds, 2019, 806, 170
[3]	Conway B. E., Journal of Electrochemical Society, 1991, 138, 1539
[4]	Zhang Y., Yu S., Lou G., Shen Y., Chen H., Shen Z., Zhao S., Zhang J., Chai S., Zou Q., Journal of Materials Science, 2017, 52, 11201
[5]	Shang P., Zhang J., Tang W., Xu Q., Guo S., Advanced Functional Materials, 2016, 26, 7766
[6]	Li Z., Xu K., Pan Y., Nanotechnology Reviews, 2019, 8, 35
[7]	Yu G., Xie X., Pan L., Bao Z., Cui Y., Nano Energy, 2013, 2, 213
[8]	Li W., Xu K., An L., Jiang F., Zhou X., Yang J., Chen Z., Zou R., Hu J., Journal of Materials Chemistry A, 2014, 2, 1443
[9]	Lu X., Wang G., Zhai T., Yu M., Gan J., Tong Y., Li Y., Nano Letter, 2012, 12, 1690
[10]	Vijayakumar S., Nagamuthu S., Muralidharan G., Applied Materials & Interfaces, 2013, 5, 2188
[11]	Li Y., Han X., Yi T., He Y., Li X., Journal of Energy Chemistry, 2019, 31, 54
[12]	Dubal D. P., Gomez-Romero P., Sankapal B. R., Holze R., Nano Energy, 2014, 11, 377
[13]	Yang F., Zhang K., Li W., Xu K., Journal of Colloid and Interface Science, 2019, 556, 386
[14]	Deng X., Fan Y., Zhou Q., Huang H., Zhou W., Lan Z., Liang X., Li G., Guo J., Tang S., Electrochimica Acta, 2019, 319, 783
[15]	Yuan C., Li J., Hou L., Zhang X., Shen L., Lou X. W.(David), Advanced Functional Materials, 2012, 22, 4592
[16]	Rakhi R. B., Chen W., Cha D., Alshareef H. N., Nano Letter, 2012, 12, 2559
[17]	Zhao H., Liu L., Vellacheri R., Lei Y., Advanced Science, 2017, 4, 1700188
[18]	Liu C., Jiang W., Hu F., Wu X., Xue D., Inorganic Chemistry Frontiers, 2018, 5, 835
[19]	Zhang Y., Wang X., Shen M., Fu X., Huang M., Liu X., Zhang Y. X., Journal of Materials Science, 2019, 54, 4821
[20]	Sethi M., Bhat D. K., Journal of Alloys and Compounds, 2019, 781, 1013
[21]	Zhang H., Xiao D., Li Q., Ma Y., Yuan S., Xie L., Chen C., Lu C., Journal of Energy Chemistry, 2017, 27, 195
[22]	Xiao T., Li J., Zhuang X., Zhang W., Wang S., Chen X., Xiang P., Jiang L., Tan X., Electrochimica Acta, 2018, 269, 397
[23]	Guan C., Liu X., Ren W., Li X., Cheng C., Wang J., Advanced Energy Materials, 2017, 7, 1602391
[24]	Fu H. Y., Wang Z. Y., Li Y. H., Zhang Y. F., Materials Research Innovations, 2015, 19, S255
[25]	Cheng G., Kou T., Zhang J., Si C., Gao H., Zhang Z., Nano Energy, 2017, 38, 155
[26]	Cui B., Lin H., Liu Y., Li J., Sun P., Zhao X., Liu C., Journal Physical Chemistry C, 2009, 113, 14083
[27]	Guo D., Zhang L., Song X., Tan L., Ma H., Jiao J., Zhu D., Li F., New Journal of Chemistry, 2018, 42, 8478
[28]	Yan D., Wang W., Luo X., Chen C., Zeng Y., Zhu Z., Chemical Engineering Journal, 2018, 334, 864
[29]	Shen L., Che Q., Li H., Zhang X., Advanced Functional Materials, 2014, 24, 2630
[30]	Gao S., Liao F., Ma S., Zhu L., Shao M., Journal of Materials Chemistry A, 2015, 3, 16520
[31]	Zhao L., Wang L., Yu P., Tian C., Feng H., Diao Z., Fu H., Dalton Transactions, 2017, 46, 4717
[32]	Largeot C., Portet C., Chmiola J., Taberna P. L., Gogotsi Y., Simon P., Journal of American Chemical Society, 2008, 130, 2730
[33]	Naresh B., Krishna T. N. V., Rao S. S., Kim H. J., Materials Letters, 2019, 248, 218
[34]	Jabeen N., Xia Q., Yang M., Xia H., ACS Applied Materials & Interfaces, 2016, 8, 6093
[35]	Ai Y., Ma J., Wang Z. M., Earth and Environmental Science, 2018, 170, 032095
[36]	Yedluri A. K., Kim H., RSC Advances, 2019, 9, 1115
[37]	Deng F., Yu L., Cheng G., Lin T., Sun M., Ye F., Li Y., Journal of Power Sources, 2014, 251, 202
[38]	Waghmode R. B., Torane A. P., Journal of Materials Science:Materials in Electronics, 2016, 27, 6133
[39]	Zhang Y., Ma M., Yang J., Su H., Huang W., Dong X., Nanoscale, 2014, 6, 4303
[40]	Wang H., Wang X., Yang J., ACS Applied Materials & Interfaces, 2013, 5, 6255
[41]	Xu J., Liu F., Peng X., Li J., Yang Y., Jin D., Chemistryselect, 2017, 2, 5189

Porous NiCo₂O₄ Nanowire Arrays as Supercapacitor Electrode Materials with Extremely High Cycling Stability

Porous NiCo₂O₄ Nanowire Arrays as Supercapacitor Electrode Materials with Extremely High Cycling Stability

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