Controllable Synthesis of Hollow Multishell Structured Co3O4 with Improved Rate Performance and Cyclic Stability for Supercapacitors

doi:10.1007/s40242-019-0040-3

高等学校化学研究 ›› 2020, Vol. 36 ›› Issue (1): 68-73.doi: 10.1007/s40242-019-0040-3

Controllable Synthesis of Hollow Multishell Structured Co₃O₄ with Improved Rate Performance and Cyclic Stability for Supercapacitors

WANG Cong^1,2, WANG Jiangyan¹, HU Wenping², WANG Dan¹

1. State Key Laboratory of Biochemical Engineering, Institute of Process Engineering, Chinese Academy of Sciences, Beijing 100190, P. R. China;
2. Department of Chemistry, School of Science & Collaborative Innovation Center of Chemical Science and Engineering, Tianjin University, Tianjin 300072, P. R. China

收稿日期:2019-11-08 修回日期:2019-12-03 出版日期:2020-02-01 发布日期:2020-01-20
通讯作者: WANG Dan E-mail:danwang@ipe.ac.cn
基金资助:
Supported by the National Natural Science Foundation of China(Nos.21590795, 21821005, 51772296, 51772294, 51702321, 51972306, 51802306).

Controllable Synthesis of Hollow Multishell Structured Co₃O₄ with Improved Rate Performance and Cyclic Stability for Supercapacitors

WANG Cong^1,2, WANG Jiangyan¹, HU Wenping², WANG Dan¹

1. State Key Laboratory of Biochemical Engineering, Institute of Process Engineering, Chinese Academy of Sciences, Beijing 100190, P. R. China;
2. Department of Chemistry, School of Science & Collaborative Innovation Center of Chemical Science and Engineering, Tianjin University, Tianjin 300072, P. R. China

Received:2019-11-08 Revised:2019-12-03 Online:2020-02-01 Published:2020-01-20
Contact: WANG Dan E-mail:danwang@ipe.ac.cn
Supported by:
Supported by the National Natural Science Foundation of China(Nos.21590795, 21821005, 51772296, 51772294, 51702321, 51972306, 51802306).

摘要/Abstract

摘要： Hollow multishelled structures(HoMSs) Co₃O₄ with specially appointed shell number(double-, triple- and quadruple-) were accurately prepared by a sequential templating approach. Due to the superiorities of inimitable porous multishelled structure, triple-HoMSs Co₃O₄ achieved the best performance among all the samples with a specific capacitance of 1028.9 F/g at 10 mV/s and 688.2 F/g at 0.5 A/g, respectively. Furthermore, the electrode delivered a high rate performance(89.8% retention at 10 A/g) and excellent cycle stability(6.8% loss over 2000 cycles), showing a great promise for practical application in the future.

关键词: Hollow multishelled structure, Cobalt oxide, Supercapacitor

Abstract: Hollow multishelled structures(HoMSs) Co₃O₄ with specially appointed shell number(double-, triple- and quadruple-) were accurately prepared by a sequential templating approach. Due to the superiorities of inimitable porous multishelled structure, triple-HoMSs Co₃O₄ achieved the best performance among all the samples with a specific capacitance of 1028.9 F/g at 10 mV/s and 688.2 F/g at 0.5 A/g, respectively. Furthermore, the electrode delivered a high rate performance(89.8% retention at 10 A/g) and excellent cycle stability(6.8% loss over 2000 cycles), showing a great promise for practical application in the future.

Key words: Hollow multishelled structure, Cobalt oxide, Supercapacitor

WANG Cong, WANG Jiangyan, HU Wenping, WANG Dan. Controllable Synthesis of Hollow Multishell Structured Co₃O₄ with Improved Rate Performance and Cyclic Stability for Supercapacitors[J]. 高等学校化学研究, 2020, 36(1): 68-73.

参考文献 43

[1]	AraveLeela M. R., Gowda S. R., Shaijumon M. M., Ajayan P. M., Adv. Mater., 2012, 24, 5045
[2]	Xu Y., Wang X., An C., Wang Y., Jiao L., Yuan H., J. Mater. Chem. A, 2014, 2, 16480
[3]	Ke Q., Tang C., Yang Z., Zheng M., Mao L., Liu H., Wang J., Elec-trochim. Acta, 2015, 163, 9
[4]	Peng S., Li L., Tan H., Cai R., Shi W., Li C., Mhaisalkar S. G., Srinivasan S., Ramakrishna S., Yan Q., Adv. Funct. Mater., 2014, 24, 2155
[5]	Wang G., Zhang L., Zhang J., Chem. Soc. Rev., 2012, 41, 797
[6]	Tang H., Wang J., Yin H., Zhao H., Wang D., Tang Z., Adv. Mater., 2015, 27, 1117
[7]	Zhang L., Zhao X., Chem. Soc. Rev., 2009, 38, 2520
[8]	Chen S., Ramachandran R., Mani V., Sarawathi R., Int. J. Electrochem. Sci., 2014, 9, 4072
[9]	Rakhi R. B., Chen W., Cha D., Alshareef H. N., Nano Lett., 2012, 12, 2559
[10]	Yuan C., Yang L., Hou L., Shen L., Zhang X., Lou X., Energy Environ. Sci., 2012, 5, 7883
[11]	Fan H., Quan L., Yuan M., Zhu S., Wang K., Zhong Y., Chang L., Shao H., Wang J., Zhang J., Cao C., Electrochim. Acta, 2016, 188, 222
[12]	Yan J., Wang Q., Wei T., Fan Z., Adv. Energy Mater., 2013, 4, 1
[13]	Simon P., Gogotsi Y., Nat. Mater., 2008, 7, 845
[14]	Wang D., Wang Q., Wang T., Inorg. Chem., 2011, 50, 6482
[15]	Wang X., Li M., Chang Z., Yang Y., Wu Y., Liu X., ACS Appl. Mater. Inter., 2015, 7, 2280
[16]	Yu X., Yu L., Wu H., Lou X., Angew. Chem., Int. Ed., 2015, 54, 5331
[17]	Xia X., Tu J., Mai Y., Wang X., Gu C., Zhao X., J. Mater. Chem., 2011, 21, 9319
[18]	Zhang Y., Wang Y., Xie Y., Cheng T., Lai W., Pang H., Huang W., Nanoscale, 2014, 6, 14354
[19]	Du H., Jiao L., Wang Q., Yang J., Guo L., Si Y., Wang Y., Yuan H., Nano Res., 2013, 6, 87
[20]	Chen Y., Li Z., Lou X., Angew. Chem., Int. Ed., 2015, 54, 10521
[21]	Wang J., Tang H., Ren H., Yu R., Qian J., Mao D., Zhao H., Wang D., Adv. Sci., 2014, 1, 1400011
[22]	Guo J., Yin Z., Zang X., Dai Z., Zhang Y., Huang W., Dong X., Nano Res., 2017, 10, 405
[23]	Zhao X., Yu R., Tang H., Mao D., Qi J., Wang B., Zhang Y., Zhao H., Hu W., Wang D., Adv. Mater., 2017, 29, 1700550
[24]	Chen M., Wang J., Tang H., Yang Y., Wang B., Zhao H., Wang D., Inorg. Chem. Front., 2016, 3, 1065
[25]	Park G. D., Lee J. H., Lee J. K., Kang Y. C., Nano Res., 2014, 7, 1738
[26]	Lai X., Halpert J. E., Wang D., Energy Environ. Sci., 2012, 5, 5604
[27]	Wang J., Yang N., Tang H., Dong Z., Jin Q., Yang M., Kiisailus D., Zhao H., Tang Z., Wang D., Angew. Chem., Int. Ed., 2013, 125, 6545
[28]	Dong Z., Ren H., Hessel C. M., Wang J., Yu R., Jin Q., Yang M., Hu Z., Chen Y., Tang Z., Zhao H., Wang D., Adv. Mater., 2014, 26, 905
[29]	Wang J., Wan J., Wang D., Acc. Chem. Res., 2019, 52, 2169
[30]	Xu S., Hessel C. M., Ren H., Yu R., Jin Q., Yang M., Zhao H., Wang D., Energy Environ. Sci., 2014, 7, 632
[31]	Salhabi E., Zhao L., Wang J., Yang M., Wang B., Wang D., 2019, 58, 9078
[32]	Lai X., Li J., Korgel B. A., Dong Z., Li Z., Su F., Du J., Wang D., Angew. Chem., Int. Ed., 2011, 123, 2790
[33]	Lou X., Deng D., Lee J., Feng J., Archer L., Adv. Mater., 2008, 20, 258
[34]	Kinsinger N. M., Dudchenko A., Wong A., Kisailus D., ACS Appl. Mater. Interfaces, 2013, 5, 6247
[35]	Xiong S., Yuan C., Zhang X., Xi B., Qian Y., Chem. Eur. J., 2009, 15, 5320
[36]	Deng S., Xiao X., Xing X., Wu J., Wen W., Wang Y., J. Mol. Catal. A:Chem., 2015, 398, 79
[37]	Xu J., Gao P., Zhao T., Energy Environ. Sci., 2012, 5, 5333
[38]	Wang L., Liu X., Wang X., Yang X., Lu L., Curr. Appl. Phys., 2010, 10, 1422
[39]	Zhang F., Yuan C., Lu X., Zhang L., Che Q., Zhang X., J. Power Sources, 2012, 203, 250
[40]	Pal M., Rakshit R., Singh A. K., Mandal K., Energy, 2016, 103, 481
[41]	Fan M., Ren B., Yu L., Song D., Liu Q., Liu J., Wang J., Jing X., Liu L., Electrochim. Acta, 2015, 166, 168
[42]	Liu X., Gao Y., Yang G., Nanoscale, 2016, 8, 4227
[43]	Wang Y., Pan A., Zhu Q., Nie Z., Zhang Y., Tang Y., Liang S., Cao G., J. Power Sources, 2014, 272, 107

Controllable Synthesis of Hollow Multishell Structured Co₃O₄ with Improved Rate Performance and Cyclic Stability for Supercapacitors

Controllable Synthesis of Hollow Multishell Structured Co₃O₄ with Improved Rate Performance and Cyclic Stability for Supercapacitors

可视化

摘要/Abstract

引用本文

使用本文

参考文献 43

相关文章 15

编辑推荐

Metrics

本文评价

[1]	YANG Zhichen, KANG Xiaoting, ZOU Bo, YUAN Xuna, LI Yajie, WU Qin, GUO Yupeng. Development of the Self-doping Porous Carbon and Its Application in Supercapacitor Electrode[J]. 高等学校化学研究, 2022, 38(4): 1065-1072.
[2]	GAO Wei, LI Yufeng, ZHAO Jitao, ZHANG Zhe, TANG Weiwei, WANG Jun, WU Zhenyu, LI Zhenyu. Design and Preparation of Graphene/Fe₂O₃ Nanocomposite as Negative Material for Supercapacitor[J]. 高等学校化学研究, 2022, 38(4): 1097-1104.
[3]	YANG Fan, CHU Jia, CHENG Yaping, GONG Jiafang, WANG Xiaoqin, XIONG Shanxin. Hydrothermal Synthesis of NiCo-layered Double Hydroxide Nanosheets Decorated on Biomass Carbon Skeleton for High Performance Supercapacitor[J]. 高等学校化学研究, 2021, 37(3): 772-777.
[4]	WANG Ruifang, LEI Weiwei, WANG Lei, LI Zhenyu, CHEN Jingyu, HU Zhenzhong. N-Doped Carbon Nanofibrous Film with Unique Wettability, Enhanced Supercapacitive Property, and Facile Capacity to Demulsify Surfactant Free Oil-in-water Emulsions[J]. 高等学校化学研究, 2021, 37(3): 436-442.
[5]	LI La, CHEN Di, SHEN Guozhen. All-Ti₃C₂T_xMXene Based Flexible On-chip Microsupercapacitor Array[J]. 高等学校化学研究, 2020, 36(4): 694-698.
[6]	CHEN Chaoxian, ZHAO Chenyang, LI Cuihua, LIU Jianhong, GUI Dayong. Porous NiCo₂O₄ Nanowire Arrays as Supercapacitor Electrode Materials with Extremely High Cycling Stability[J]. 高等学校化学研究, 2020, 36(4): 715-720.
[7]	GAO Yuan, ZHOU Ruitao, WANG Dongrui, HUANG Qiyao, CHENG Ching-Hsiang, ZHENG Zijian. Boosting the Energy Density of Flexible Asymmetric Supercapacitor with Three Dimensional Fe₂O₃ Composite Brush Anode[J]. 高等学校化学研究, 2020, 36(1): 97-104.
[8]	FU Xiuyan, XU Shuai, LUO Yang, LI Aiwu, YANG Han. Simultaneous Photoreduction and Nitrogen Doping of Graphene Oxide for Supercapacitors by Direct Laser Writing[J]. 高等学校化学研究, 2019, 35(5): 879-883.
[9]	WANG Chen, MENG Yanshuang, WANG Lei, ZHU Fuliang, ZHANG Yue. One Step Hydrothermal Synthesis of Flower-shaped Co₃O₄ Nanorods on Nickel Foam as Supercapacitor Materials and Their Excellent Electrochemical Performance[J]. 高等学校化学研究, 2018, 34(6): 882-886.
[10]	WANG Can, WANG Dianyu, ZHENG Shuang, FANG Xueqing, ZHANG Wenli, TIAN Ye, LIN Haibo, LU Haiyan, JIANG Lei. Facile Self-templating Melting Route Preparation of Biomass-derived Hierarchical Porous Carbon for Advanced Supercapacitors[J]. 高等学校化学研究, 2018, 34(6): 983-988.
[11]	SHI Xue, ZHOU Guowei. Preparation of Zinc-nickel-cobalt Ternary Oxide Nanosheets as Electrodes in Supercapacitors[J]. 高等学校化学研究, 2017, 33(6): 939-945.
[12]	ZHANG Lifeng, DU Suqing, SONG Qiaolan, LIU Yi, GUO Shouwu. Fluorine-free Ionic Liquid Based on Thiocyanate Anion with Propylene Carbonate as Electrolytes for Supercapacitors:Effects of Concentration and Temperature[J]. 高等学校化学研究, 2017, 33(5): 779-784.
[13]	ZHANG Botao, ZHANG Yang, XIANG Weixu, TENG Yanguo, WANG Ying. Comparison of the Catalytic Performances of Different Commercial Cobalt Oxides for Peroxymonosulfate Activation During Dye Degradation[J]. 高等学校化学研究, 2017, 33(5): 822-827.
[14]	WANG Hongzhi, SHI Xin, SHI Yulei, ZHANG Weiguo, YAO Suwei. One-pot Hydrothermal Synthesis of Novel NiCoO₂/Reduced Graphene Oxide Composites for Supercapacitors[J]. 高等学校化学研究, 2017, 33(4): 638-642.
[15]	WANG Hongzhi, SHI Yulei, LI Zixuan, ZHANG Weiguo, YAO Suwei. Synthesis and Electrochemical Performance of Co₃O₄/Graphene[J]. 高等学校化学研究, 2014, 30(4): 650-655.