Benzohydrazide Derivatives: Gelation and Application in Oil Spill Recovery

doi:10.1007/s40242-019-9089-2

高等学校化学研究 ›› 2019, Vol. 35 ›› Issue (5): 874-878.doi: 10.1007/s40242-019-9089-2

Benzohydrazide Derivatives: Gelation and Application in Oil Spill Recovery

ZHANG Tianren¹, ZHANG Chunxue¹, CHE Xiangyang¹, BAI Binglian², LI Min¹, WANG Haitao¹

1. Key Laboratory for Automobile Materials, Ministry of Education, College of Materials Science and Engineering, Jilin University, Changchun 130012, P. R. China;
2. College of Physics, Jilin University, Changchun 130012, P. R. China

收稿日期:2019-04-01 出版日期:2019-10-01 发布日期:2019-09-24
通讯作者: LI Min, WANG Haitao E-mail:minli@jlu.edu.cn;haitao_wang@jlu.edu.cn
基金资助:
Supported by the Science and Technology Development Programme of Jilin Province, China(No.20170520127JH), the Postdoctoral Science Foundation of China(No.2012T50294) and the Fundamental Research Funds for the Central Universities of China.

Benzohydrazide Derivatives: Gelation and Application in Oil Spill Recovery

ZHANG Tianren¹, ZHANG Chunxue¹, CHE Xiangyang¹, BAI Binglian², LI Min¹, WANG Haitao¹

1. Key Laboratory for Automobile Materials, Ministry of Education, College of Materials Science and Engineering, Jilin University, Changchun 130012, P. R. China;
2. College of Physics, Jilin University, Changchun 130012, P. R. China

Received:2019-04-01 Online:2019-10-01 Published:2019-09-24
Contact: LI Min, WANG Haitao E-mail:minli@jlu.edu.cn;haitao_wang@jlu.edu.cn
Supported by:
Supported by the Science and Technology Development Programme of Jilin Province, China(No.20170520127JH), the Postdoctoral Science Foundation of China(No.2012T50294) and the Fundamental Research Funds for the Central Universities of China.

摘要/Abstract

摘要： The synthesis and gelation properties of a series of organogelators containing a benzohydrazide unit and two alkoxy chains(oBn) were reported herein. oBn(n=8, 10, 12) could form stable gels in commercial fuels(e.g., diesel), which were characterized by low critical gelation concentrations(CGCs) and good mechanical properties (G'>10⁵ Pa). The gelation process was further studied by field-emission scanning electron microscopy(FE-SEM), Fourier transform infrared spectroscopy(FTIR) and X-ray diffraction(XRD), etc. It was demonstrated that in these organogels, molecules self-assembled into fibrils 3D-network, where hydrogen bonding, van der Waals force and π-π interaction were confirmed as the driving forces. As compounds oBn(n=8, 10, 12) show very good gelation properties in diesel, their applications in oil spill treatment have also been tested. It was found that oBn could achieve rapid (<30 s) and effective oil removal at room temperature, being good candidates for oil spill treatment in the future. Also, the removal efficiency could be as high as 95%.

关键词: Benzohydrazide derivative, Organogel, Self-assembly, Oil spill recovery

Abstract: The synthesis and gelation properties of a series of organogelators containing a benzohydrazide unit and two alkoxy chains(oBn) were reported herein. oBn(n=8, 10, 12) could form stable gels in commercial fuels(e.g., diesel), which were characterized by low critical gelation concentrations(CGCs) and good mechanical properties (G'>10⁵ Pa). The gelation process was further studied by field-emission scanning electron microscopy(FE-SEM), Fourier transform infrared spectroscopy(FTIR) and X-ray diffraction(XRD), etc. It was demonstrated that in these organogels, molecules self-assembled into fibrils 3D-network, where hydrogen bonding, van der Waals force and π-π interaction were confirmed as the driving forces. As compounds oBn(n=8, 10, 12) show very good gelation properties in diesel, their applications in oil spill treatment have also been tested. It was found that oBn could achieve rapid (<30 s) and effective oil removal at room temperature, being good candidates for oil spill treatment in the future. Also, the removal efficiency could be as high as 95%.

Key words: Benzohydrazide derivative, Organogel, Self-assembly, Oil spill recovery

ZHANG Tianren, ZHANG Chunxue, CHE Xiangyang, BAI Binglian, LI Min, WANG Haitao. Benzohydrazide Derivatives: Gelation and Application in Oil Spill Recovery[J]. 高等学校化学研究, 2019, 35(5): 874-878.

ZHANG Tianren, ZHANG Chunxue, CHE Xiangyang, BAI Binglian, LI Min, WANG Haitao. Benzohydrazide Derivatives: Gelation and Application in Oil Spill Recovery[J]. Chemical Research in Chinese Universities, 2019, 35(5): 874-878.

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Benzohydrazide Derivatives: Gelation and Application in Oil Spill Recovery

Benzohydrazide Derivatives: Gelation and Application in Oil Spill Recovery

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